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High-wear-resistance transparent TPU spherical film and preparation method thereof

A technology of spherical film and nano powder, which is applied in the field of TPU materials, can solve the problems that the ball cannot follow the flight path, restrict the wide application of TPU, and is prone to hydrolysis, etc., so as to facilitate the control of flight path, promote widespread use, and avoid local hardening Effect

Active Publication Date: 2014-12-03
DONGGUAN XIONGLIN NEW MATERIAL TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional football membranes are mostly made of leather and stitched with traditional needles, but because each seam usually forms localized hardening inside the shell, players cannot effectively control or kick the ball Can not follow the accurate flight path, in addition, the traditional leather has poor wear resistance and is prone to hydrolysis and other problems during use, so the traditional spherical film preparation leather has serious defects
Although TPU material is a material with broad market prospects, the existing TPU materials generally have defects such as insufficient hardness, poor wear resistance, insufficient elasticity and toughness when applied to spherical membranes, especially football membranes, which limit the use of TPU in football membranes. Wide application on the Internet, which in turn limits the development of high-quality ball sports equipment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] The preparation process of the TPU spherical film material as the first preferred embodiment of the present invention is as follows:

[0055] (1) Configure composite nanopowder, wherein nano-SiC of particle diameter 20-50nm accounts for 70% by weight, nano-TiO2 of particle diameter 30-40 accounts for 8% by weight, nano-ZnO of particle diameter 30-60nm accounts for 3% by weight, particle Nano-Cr with a diameter of 30-60nm 2 o 3 Accounting for 3% by weight, nano-Al with a particle size of 30-40nm 2 o 3 Accounting for 10% by weight, nano-SiO with a particle size of 30-50nm 2 Accounting for 6% by weight, the above-mentioned nanometer components are fully mixed and ground to an average particle size of 20-50nm to prepare a composite nanometer powder.

[0056] (2) Preparation of silane coupling agent, from triethyl vinyl silane, γ-aminopropyl triethoxy silane, γ-glycidyl ether oxypropyl trimethoxy silane, triphenoxy vinyl silane, benzene Any two of aminomethyltrimethoxys...

Embodiment 2

[0063] The preparation process of the TPU spherical film material as the second preferred embodiment of the present invention is as follows:

[0064] (1) Composite nano-powder is configured, wherein nano-SiC with a particle size of 20-50nm accounts for 80% by weight, and nano-TiO with a particle size of 30-40nm 2 Accounting for 5% by weight, nano-ZnO with a particle size of 30-60nm accounting for 3% by weight, nano-Cr with a particle size of 30-60nm 2 o 3 Accounting for 1% by weight, nano-Al with a particle size of 30-40nm 2 o 3 Accounting for 8% by weight, nano-SiO with a particle size of 30-50nm 2 Accounting for 3% by weight, the above-mentioned nanometer components are fully mixed and ground to an average particle size of 20-50nm to prepare a composite nanometer powder.

[0065] (2) To prepare silane coupling agent, first prepare the raw material components of silane coupling agent according to the following mass ratio: γ-aminopropyldimethoxymethylsilane with 18% by mas...

Embodiment 3

[0072] The preparation process of the TPU spherical film material as the third preferred embodiment of the present invention is as follows:

[0073] (1) Composite nanopowder is configured, wherein nano-SiC with a particle size of 20-50nm accounts for 75% by weight, and nano-TiO with a particle size of 30-40nm 2 Accounting for 6% by weight, nano-ZnO with a particle size of 30-60nm accounting for 4% by weight, nano-Cr with a particle size of 30-60nm 2 o 3 Accounting for 2% by weight, nano-Al with a particle size of 30-40nm 2 o 3 Accounting for 9% by weight, nano-SiO with a particle size of 30-50nm 2 Accounting for 4% by weight, the above-mentioned nanometer components are fully mixed and ground to an average particle size of 20-50nm to prepare a composite nanometer powder.

[0074] (2) prepare silane coupling agent, the raw material composition of described silane coupling agent (mass fraction in self composition) is: 25 parts of calcium terephthalates, 12 parts of sodium te...

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Abstract

The invention provides a high-wear-resistance transparent TPU spherical film and a preparation method thereof. The high-wear-resistance transparent TPU spherical film is prepared by mixing and tape-casting the following components in parts by weight: 60-90 parts of polyurethane-nanopowder complexing agent, 2-10 parts of chain extender, 0.3-2 parts of antioxidant, 1-4 parts of hydrolysis stabilizer, 0.8-3 parts of slipping agent, 0.8-3 parts of antiblocking agent, 1-10 parts of filling agent and 1-3 parts of flame retardant. The TPU spherical film material prepared by modifying and creating all components and preparation proportion of the TPU spherical film has unique technological advantages of being high in wear resistance, transparency and hydrolysis resistance properties, good in elasticity, cold-proof, durable, environment-friendly in materials, free from any hidden injury to a human body, printable, and capable of performing high-frequency welding and the like, the wide use of the TPU special film material in a plurality of fields can be promoted, and the TPU spherical film material has wide market prospects.

Description

technical field [0001] The invention relates to TPU material technology, and more specifically relates to a high wear-resistant transparent TPU spherical film and a preparation method thereof. Background technique [0002] TPU (Thermoplastic polyurethanes) material is a kind of thermoplastic polyurethane elastomer material, which has the advantages of wide hardness range, wear resistance and oil resistance, transparency and good elasticity, so it is widely used in daily necessities, sporting goods, toys, decorative materials and other fields, and has Gradually replace PVC to meet the trend of environmental protection requirements in more and more fields. Traditional football membranes are mostly made of leather and stitched with traditional needles, but because each seam usually forms localized hardening inside the shell, players cannot effectively control or kick the ball Can not follow the exact flight path, in addition, the traditional leather has poor wear resistance an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/08C08K13/06C08K9/06C08K9/04C08K9/02C08K3/34C08K3/22C08K3/36C08K3/26C08G18/66C08G18/48C08G18/10A63B41/08
Inventor 何建雄王一良
Owner DONGGUAN XIONGLIN NEW MATERIAL TECH
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