High-wear-resistance transparent TPU spherical film and preparation method thereof
A technology of spherical film and nano powder, which is applied in the field of TPU materials, can solve the problems that the ball cannot follow the flight path, restrict the wide application of TPU, and is prone to hydrolysis, etc., so as to facilitate the control of flight path, promote widespread use, and avoid local hardening Effect
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Embodiment 1
[0054] The preparation process of the TPU spherical film material as the first preferred embodiment of the present invention is as follows:
[0055] (1) Configure composite nanopowder, wherein nano-SiC of particle diameter 20-50nm accounts for 70% by weight, nano-TiO2 of particle diameter 30-40 accounts for 8% by weight, nano-ZnO of particle diameter 30-60nm accounts for 3% by weight, particle Nano-Cr with a diameter of 30-60nm 2 o 3 Accounting for 3% by weight, nano-Al with a particle size of 30-40nm 2 o 3 Accounting for 10% by weight, nano-SiO with a particle size of 30-50nm 2 Accounting for 6% by weight, the above-mentioned nanometer components are fully mixed and ground to an average particle size of 20-50nm to prepare a composite nanometer powder.
[0056] (2) Preparation of silane coupling agent, from triethyl vinyl silane, γ-aminopropyl triethoxy silane, γ-glycidyl ether oxypropyl trimethoxy silane, triphenoxy vinyl silane, benzene Any two of aminomethyltrimethoxys...
Embodiment 2
[0063] The preparation process of the TPU spherical film material as the second preferred embodiment of the present invention is as follows:
[0064] (1) Composite nano-powder is configured, wherein nano-SiC with a particle size of 20-50nm accounts for 80% by weight, and nano-TiO with a particle size of 30-40nm 2 Accounting for 5% by weight, nano-ZnO with a particle size of 30-60nm accounting for 3% by weight, nano-Cr with a particle size of 30-60nm 2 o 3 Accounting for 1% by weight, nano-Al with a particle size of 30-40nm 2 o 3 Accounting for 8% by weight, nano-SiO with a particle size of 30-50nm 2 Accounting for 3% by weight, the above-mentioned nanometer components are fully mixed and ground to an average particle size of 20-50nm to prepare a composite nanometer powder.
[0065] (2) To prepare silane coupling agent, first prepare the raw material components of silane coupling agent according to the following mass ratio: γ-aminopropyldimethoxymethylsilane with 18% by mas...
Embodiment 3
[0072] The preparation process of the TPU spherical film material as the third preferred embodiment of the present invention is as follows:
[0073] (1) Composite nanopowder is configured, wherein nano-SiC with a particle size of 20-50nm accounts for 75% by weight, and nano-TiO with a particle size of 30-40nm 2 Accounting for 6% by weight, nano-ZnO with a particle size of 30-60nm accounting for 4% by weight, nano-Cr with a particle size of 30-60nm 2 o 3 Accounting for 2% by weight, nano-Al with a particle size of 30-40nm 2 o 3 Accounting for 9% by weight, nano-SiO with a particle size of 30-50nm 2 Accounting for 4% by weight, the above-mentioned nanometer components are fully mixed and ground to an average particle size of 20-50nm to prepare a composite nanometer powder.
[0074] (2) prepare silane coupling agent, the raw material composition of described silane coupling agent (mass fraction in self composition) is: 25 parts of calcium terephthalates, 12 parts of sodium te...
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