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Organosilicone defoamer and preparation method thereof

A technology of silicone defoamer and defoamer, which is applied in the direction of foam dispersion/prevention, can solve the problems of product quality and production capacity decline, affect the normal production, reduce the effective load of equipment, etc., and achieve a wide range of applications , easy operation, excellent stability and dispersibility

Active Publication Date: 2014-12-24
HUBEI XINGRUI SILICON MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the production process of many industries (such as printing and dyeing, fermentation, papermaking, paint, medicine, oil field exploitation, water treatment, etc.), a large amount of foam is often generated due to operations such as stirring, vibration, boiling or adding easy-to-foaming additives. Properly suppressed, foam will bring a lot of troubles to production, such as affecting the normal production, reducing the effective load of equipment, causing product quality and production capacity to decline, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] The raw material weight percent composition of described organosilicon defoamer: high boiling silicone oil 15%, dimethyl silicone oil (viscosity 600mPa·s) 14%, fumed white carbon black 3%, composite emulsifier (composite by Span80 and Tween80, m Span80 :m Tween80 =1:1.14) 20%, deionized water 46%, thickener (polyvinyl alcohol) 2%. The preparation process is:

[0014] (1) Put dimethyl silicone oil and fumed silica into the reaction kettle according to the above ratio, raise the temperature to 150°C, and stir for 5-8 hours to prepare silicone paste;

[0015] (2) Add high-boiling silicone oil into the silicone paste, then add emulsifier, mix evenly, heat up to 40°C and stir for 30 minutes, add deionized water and polyvinyl alcohol, mix and stir for 4 hours, then cool and pack.

Embodiment 2

[0017] The raw material weight percent composition of described organosilicon defoamer: high boiling silicone oil 20%, dimethyl silicone oil (viscosity 510mPa·s) 20%, fumed white carbon black 3%, composite emulsifier (compounded by Span80 and Tween80, m Span80 :m Tween80 =1:1) 15%, deionized water 40%, thickener (polyvinyl alcohol) 2%. The preparation process is:

[0018] (1) Put dimethyl silicone oil and fumed silica into the reaction kettle according to the above ratio, raise the temperature to 150°C, and stir for 5-8 hours to prepare silicone paste;

[0019] (2) Add high-boiling silicone oil to the silicone paste, then add emulsifier, mix well, heat up to 40°C and stir for 30 minutes, add deionized water and polyvinyl alcohol, mix and stir for 2 hours, then cool and pack.

Embodiment 3

[0021] The raw material weight percent composition of described organosilicon defoamer: high boiling silicone oil 15%, simethicone oil (viscosity 728mPa·s) 22%, fumed white carbon black 3%, composite emulsifier (composite by Span80 and Tween80, m Span80 :m Tween80 =1:1) 8%, deionized water 49%, thickener (polyvinyl alcohol) 3%. The preparation process is:

[0022] (1) Put dimethyl silicone oil and fumed silica into the reaction kettle according to the above ratio, raise the temperature to 150°C, and stir for 5-8 hours to prepare silicone paste;

[0023] (2) Add high-boiling silicone oil to the silicone paste, then add emulsifier, mix well, heat up to 40°C and stir for 30 minutes, add deionized water and polyvinyl alcohol, mix and stir for 3 hours, then cool and pack.

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Abstract

The invention discloses an organosilicone defoamer and a preparation method of the organosilicone deformer. The defoamer is prepared from the following raw materials in percentage by weight: 10-40% of simethicone (201), 10-25% of high-boiling silicone oil, 1-5% of a thickener, 40-60% of water, 5-25% of an emulgator, and 1-5% of fumed silica, wherein all of the raw materials account for 100%. The preparation process comprises the following steps: (a) weighing the simethicone (201) and the fumed silica in different weight ratios and adding into a reaction kettle, raising the temperature to about 150 DEG C, and stirring for 5-8 hours to prepare a silicon cream; (b) adding the high-boiling silicone oil and the emulgator into the prepared silicon cream, heating to about 40 DEG C, stirring for 30 minutes, then adding the thickener and the deionized water, continuing to stir for 2-4 hours, cooling, discharging, and packaging. The organosilicone defoamer provided by the invention provides a reasonable way to treat byproduct high-boiling residues of the organosilicone, improves the stability and the dispersity of the emulsion, guarantees the storage time, and greatly improves the defoaming capability, and the using temperature range of the materials is relatively wide.

Description

technical field [0001] The invention relates to a silicone defoamer and a preparation method thereof Background technique [0002] In the production process of many industries (such as printing and dyeing, fermentation, papermaking, paint, medicine, oil field exploitation, water treatment, etc.), a large amount of foam is often generated due to operations such as stirring, vibration, boiling or adding easy-to-foaming additives. Properly suppressed, foam will bring a lot of troubles to production, such as affecting the normal production, reducing the effective load of equipment, causing product quality and production capacity to decline, etc. In order to eliminate and suppress foam, the most effective and economical method is to add defoamer. Silicone defoamers are widely used because of their strong defoaming ability, good thermal stability, physiological and chemical inertness, non-toxic and harmless, and no secondary pollution. Using methyl silicone oil, high boiling sil...

Claims

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Application Information

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IPC IPC(8): B01D19/04
Inventor 苗刚黄潇王文金汪民康程微胡丹
Owner HUBEI XINGRUI SILICON MATERIAL CO LTD
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