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Magnetron sputtering cluster ion source used for flight time mass spectrum

A technology of time-of-flight mass spectrometry and magnetron sputtering, which is applied in the field of ion sources, can solve the problems that the same type of magnetron sputtering components cannot be accurately analyzed, and the size of metal clusters is small, so as to achieve accurate composition analysis and reduce loss.

Inactive Publication Date: 2015-01-14
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of the present invention is to provide a magnetron sputtering cluster ion source for time-of-flight mass spectrometry, which solves the problem of the small size of metal clusters in the past and the inability to accurately analyze the components of the same type of magnetron sputtering. The invention can be used for component analysis of various metal large-size cluster ions

Method used

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  • Magnetron sputtering cluster ion source used for flight time mass spectrum
  • Magnetron sputtering cluster ion source used for flight time mass spectrum
  • Magnetron sputtering cluster ion source used for flight time mass spectrum

Examples

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Embodiment 1

[0018] The target material is a silver target with a diameter of 50.8 mm and a thickness of 4 mm. The magnetron sputtering head is supplied with cooling water, 30 ml of argon gas per minute, and 120 ml of helium gas per minute. Turn on the DC power supply of magnetron sputtering, the voltage is 300V, the current is 0.2A, the generated ions directly enter the time-of-flight mass spectrometer, the acquisition frequency is 10000Hz, and the accumulation is 500 seconds to obtain Ag n + and Ag n o + (n=1-34) time-of-flight mass spectrometry (eg image 3 shown), indicating that time-of-flight mass spectrometry can be used to accurately analyze Ag 1 + and Ag 1 o + to Ag 12 + and Ag 12 o + Isotopic peaks with an accuracy of 1 Dalton (Da). Optimize the conditions of the magnetron sputtering ion source to produce large-sized silver clusters and silver oxide clusters. The acquisition conditions are the same as above, such as Figure 4 As shown, the measurement range of time-of...

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Abstract

The invention discloses a magnetron sputtering cluster ion source used for a flight time mass spectrum. The ion source comprises a cavity, an argon inlet pipe, a helium inlet pipe, a metal target material and a spraying opening. The metal target material is located on the side close to the flight time mass spectrum, and the argon inlet pipe and the helium inlet pipe are arranged at the two ends of the metal target material. The side, adjacent to the flight time mass spectrum, of the cavity is provided with the spraying opening protruding towards the cavity. According to the magnetron sputtering cluster ion source, the magnetron sputtering cluster ion source is combined with the flight time mass spectrum, when a sample is tested, argon enters the cavity through the argon inlet pipe and then is ionized, ionized argon ions rapidly bombard the surface of the metal target material to generate metal plasma which is carried by helium, the metal plasma is sprayed out from the spraying opening to form cluster ions which enter the high-resolution flight time mass spectrum, and finally a detector detects the ion cluster flight time mass spectrum with a quite wide size range.

Description

technical field [0001] The invention belongs to the field of ion sources, in particular to a magnetron sputtering cluster ion source for time-of-flight mass spectrometry. Background technique [0002] Atomic clusters or molecular clusters are material levels between single atoms or molecules and condensed states. It is of great theoretical and practical significance to study the physical and chemical properties of clusters of different sizes. Time-of-flight mass spectrometry has the advantages of fast analysis speed, wide analysis mass range, high resolution, and no mass upper limit. It is a powerful means to study clusters. Higher and higher, there is an urgent need for a stable and efficient ion source. [0003] The magnetron sputtering ion source can be used for the detection of metal cluster ions. The principle is to add an orthogonal magnetic field and electric field between the sputtered target (cathode) and the anode, and fill the high vacuum chamber with an inert ga...

Claims

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Application Information

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IPC IPC(8): H01J49/10H01J49/14
CPCH01J49/142
Inventor 唐紫超秦正波张世宇
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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