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Method of removing micro organic pollutants in water

A technology for removing organic pollutants and water, applied in the field of water treatment, can solve the problems to be investigated, high cost of catalysis, inability to realize recovery and utilization of catalysts, etc. Effect

Active Publication Date: 2015-03-04
江苏中鹏环保集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The application number is CN200910071693.2, and the Chinese patent application titled "Method for Removing Trace Organic Pollutants in Water by Catalytic Oxidation of Potassium Manganate" discloses a method for removing trace organic pollutants in water. The catalyst used contains Fe( II), Fe(III), iron oxyhydroxide, iron oxide, among which Fe(II) and Fe(III) catalysts form a uniform solution with water after being added into the water body, so that the used catalyst cannot be recovered and Utilization, at present, there is no research or invention related to the application of activated carbon-supported iron-based agents to enhance the oxidation of potassium permanganate in neutral or near-neutral water environments
[0006] The application number is CN201110150251.4, and the Chinese patent application titled "A method for removing micro-pollutants in water by oxidizing potassium permanganate catalyzed by ruthenium" discloses a method for removing trace organic pollutants in water. By adding ruthenium catalyst, It can increase the reaction rate and strengthen the treatment effect; although the catalytic process has achieved a good catalytic effect, because ruthenium is a noble metal, the catalytic cost is very high, and there are still few studies on the toxicity of ruthenium, so it is applied to water The security of the processing field is still to be investigated

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0039] Take 200mL of river water (taken from the Yangtze River) containing trace organic pollutants, and control FeO / AC+Fe 2 o 3 The dosage of AC / AC (mass ratio 1:4) is 15mg / L. After stirring vigorously with a magnetic stirrer for 10 minutes, potassium permanganate is added. The dosage of potassium permanganate is 5mg / L. After 1 hour of treatment, the removal rate of trace organic pollutants can reach 35%-90%. Compared with the single use of potassium permanganate, the removal rate of trace organic pollutants in this embodiment is increased by 35%-600%, and the reaction rate is increased by 3-10 times.

[0040] figure 1 It is the effect diagram of this embodiment on the removal of trace organic pollutants, and the trace organic pollutants are taken by non-steroidal anti-inflammatory drugdiclofenac, in the figure Represents the removal rate curve of activated carbon-loaded iron-based reagents fortified with potassium permanganate to remove diclofenac, Represents the remo...

Embodiment 2

[0042] Take 200mL of domestic sewage containing trace organic pollutants (taken from the effluent of Nanjing Jiangning Sewage Plant), and control Fe(OH) 3 The dosage of / AC is 7mg / L. After stirring vigorously with a magnetic stirrer for 10 minutes, potassium permanganate is added. The dosage of potassium permanganate is 10mg / L, and the water sample is treated for 45 minutes. The removal rate can reach 45%-95%. Compared with the single use of potassium permanganate, the removal rate of trace organic pollutants in this embodiment is increased by 50%-700%, and the reaction rate is increased by 5-14 times.

[0043] figure 2 It is the effect diagram of this embodiment on the removal of trace organic pollutants, and the trace organic pollutants are taken by non-steroidal anti-inflammatory drugdiclofenac, in the figure Represents the removal rate curve of activated carbon-loaded iron-based reagents fortified with potassium permanganate to remove diclofenac, Represents the remo...

Embodiment 3

[0045] Take 200mL of industrial wastewater containing trace organic pollutants (taken from Nanjing Pharmaceutical Factory), and add Fe 3 o 4 / AC and potassium permanganate reagents, control the dosage of activated carbon-loaded iron-based reagents to 15mg / L, and the dosage of potassium permanganate to 10mg / L, stir vigorously with a magnetic stirrer, and treat the water samples for 1.8h , The removal rate of trace organic pollutants can reach more than 90%.

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Abstract

The invention discloses a method of removing micro organic pollutants in water. The method comprises the following steps: adding potassium permanganate and activated-carbon-loaded iron-based medicaments into the water containing micro organic pollutants to treat for 20 minutes to 2 hours, wherein the adding amount of the potassium permanganate is 0.5-10mg / L, the adding amount of the activated-carbon-loaded iron-based medicaments is 5-30mg / L. The method of removing micro organic pollutants in water disclosed by the invention is high in removal rate of micro organic pollutants, and capable of increasing the removal rate of the micro organic pollutants by 40%-800% in comparison with an independent potassium permanganate oxidizing process. Moreover, disinfection by-products are not produced in a reaction process, the catalyst is safe and harmless. The method is simple to operate, small in investment and low in operation cost.

Description

technical field [0001] The invention belongs to the technical field of water treatment, and in particular relates to a method for removing trace organic pollutants in water. Background technique [0002] Water sources continue to be polluted, and drinking water standards are becoming more and more stringent, making the problem of drinking water decontamination more and more arousing people's attention. Conventional drinking water treatment processes have been difficult to meet people's water quality requirements. Domestic and foreign experimental research and actual production results have shown that conventional coagulation, sedimentation, filtration, and disinfection processes for polluted source water can only remove trace organic pollution in water. 20%-30% of the substance, and the presence of soluble trace organic pollutants is not conducive to destroying the stability of the colloid, so that the removal effect of the conventional treatment process on the turbidity of ...

Claims

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Application Information

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IPC IPC(8): C02F1/72
CPCC02F1/725C02F2101/30
Inventor 张静金梦婷朱亮高莹张瑞甲
Owner 江苏中鹏环保集团有限公司
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