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Method for microwave-organic modification of attapulgite and method for using the attapulgite to treat polycyclic aromatic hydrocarbons in oil production wastewater

A technology for modifying attapulgite and polycyclic aromatic hydrocarbons, which is applied in separation methods, water/sewage treatment, chemical instruments and methods, etc., to achieve the effect of improving adsorption performance

Inactive Publication Date: 2017-05-31
XIAMEN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, at present, there are few reports on using attapulgite to treat polycyclic aromatic hydrocarbons in oil production wastewater. In view of this deficiency, the inventors deeply explored the use of attapulgite to remove polycyclic aromatic hydrocarbons in oil production wastewater. This case arose from this

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] 1) First put 20g of attapulgite in a 250ml Erlenmeyer flask, add 1g of cationic gemini surfactant 12-2-12, 20ml of 1mol / L hydrochloric acid, and 80ml of deionized water, seal the bottle, Put it into an incubator at 60° C., set the rotation speed at 200 rpm, and react for 3 hours.

[0028] 2) Take the mixture in step 1) out of the incubator, put it into a microwave oven, and set the microwave intensity to 400W for 3 minutes.

[0029] 3) Filter the mixture in step 2) through a Buchner funnel, and rinse repeatedly with deionized water until the eluent does not contain Br - So far, available AgNO 3 Solution titration test.

[0030] 4) Dry the filtered solid in step 3) in an oven at 80°C.

[0031] 5) Activate the dried solid in step 4) at 100°C for 1 hour.

[0032] 6) After the soil sample obtained in step 5) is subjected to mortar and sieve treatment, a microwave-organically modified attapulgite is obtained. The modified soil samples were analyzed by FTIR, XRD, TGA, et...

Embodiment 2

[0034] 1) First, put 30g of attapulgite in a 250ml Erlenmeyer flask, add 1.5g of cationic gemini surfactant 12-2-12, 30ml of 1mol / L hydrochloric acid, and 100ml of deionized water, and seal the bottle , put into an incubator at 60°C, set the rotation speed at 200rpm, and react for 5 hours.

[0035] 2) Take the mixture in step 1) out of the incubator, put it into a microwave oven, and set the microwave intensity to 500W for 4 minutes.

[0036] 3) Filter the mixture in step 2) through a Buchner funnel, and rinse repeatedly with deionized water until the eluent does not contain Br - So far, available AgNO 3 Solution titration test.

[0037] 4) Dry the filtered solid in step 3) in an oven at 75°C.

[0038] 5) Activate the dried solid in step 4) at 100°C for 2 hours.

[0039] 6) After the soil sample obtained in step 5) is subjected to mortar and sieve treatment, a microwave-organically modified attapulgite is obtained. The modified soil samples were analyzed by FTIR, XRD, TGA...

Embodiment 3

[0041] 1) First put 25g of attapulgite in a 250ml Erlenmeyer flask, add 1.2g of cationic gemini surfactant 12-2-12, 25ml of 1mol / L hydrochloric acid, and 90ml of deionized water, and seal the bottle , put into an incubator at 50°C, set the rotation speed at 200rpm, and react for 4 hours.

[0042] 2) Take the mixture in step 1) out of the incubator, put it into a microwave oven, and set the microwave intensity to 300W for 5 minutes.

[0043] 3) Filter the mixture in step 2) through a Buchner funnel, and rinse repeatedly with deionized water until the eluent does not contain Br - So far, available AgNO 3 Solution titration test.

[0044] 4) Dry the filtered solid in step 3) in an oven at 70°C.

[0045] 5) Activate the dried solid in step 4) at 100°C for 1.5 hours.

[0046] 6) After the soil sample obtained in step 5) is subjected to mortar and sieve treatment, a microwave-organically modified attapulgite is obtained. The modified soil samples were analyzed by FTIR, XRD, TGA...

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PUM

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Abstract

The invention discloses an attapulgite microwave-organic modification method and a method for treating polycyclic aromatic hydrocarbon in oil producing wastewater by utilizing attapulgite, and belongs to the technical field of waste reclamation and pollution control. According to the invention, attapulgite acts as a main material, and is subjected to microwave-organic modification, and the obtained adsorbent has relatively high adsorption capacity to polycyclic aromatic hydrocarbon in the oil producing wastewater. The amount of a surfactant, the use amount of attapulgite, the microwave time, the pH of a solution and the reaction temperature all affect the treatment effect. The reserve of attapulgite is very rich in China. Because the traditional adsorbent activated carbon is high in cost, is difficult to regenerate and the like, attapulgite is expected to replace the activated carbon to be an environment-friendly and cheap adsorbent.

Description

technical field [0001] The invention relates to the technical field of waste resource utilization and pollution control, in particular to a method for microwave-organic modification of attapulgite and a method for using the attapulgite to treat polycyclic aromatic hydrocarbons in oil extraction wastewater. Background technique [0002] In recent years, my country's water environment is suffering unprecedented serious pollution. Among all wastewaters, oily wastewater has become a non-negligible polluted water body. Oil enters the water body environment through different channels to form oily wastewater. Oily wastewater is a large-volume, wide-ranging and seriously harmful wastewater with many sources. Industrial oily wastewater has the largest amount and complex composition. In addition to natural impurities such as soluble salts and heavy metals, suspended emulsified oil, solid particles, hydrogen sulfide, etc., it also contains hydrophobic organic polycyclic aromatic hydro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/22B01J20/30C02F1/28C02F1/40
CPCB01J20/22B01J20/3085C02F1/285C02F1/40
Inventor 赵珊黄国和阳艾利魏佳安春江姚尧金磊忻夏莹陈秀娟周雄
Owner XIAMEN UNIV OF TECH