Oil displacing microemulsified acid system for acidizing plugging removal and preparation method of system

A micro-lactic acid and system technology, applied in chemical instruments and methods, drilling compositions and other directions, can solve the problems of affecting water injection pressure and injection volume, yet to find oil-displacing micro-lactic acid, prone to strong adsorption, etc., and reduce water injection. The effect of pressure, excellent oil displacement performance, and good dissolving performance

Active Publication Date: 2015-03-25
唐山冀油瑞丰化工有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The microlactic acid system of the prior art has the following problems: heat Poor stability, easy to demulsify above 70 °C; Strong adsorption is prone to occur in the layer, resulting in rapid destruction of the microemulsion system and premature release of acid; Acids, which are all strong acids, cannot complete deep or ultra-deep acidification plugging removal; There is still residual oil in the water flooding seepage channel, Affects water injection pressure and injection volume, requires residual acid to have oil displacement performance
[0004] No useful diesel oil, polyhydric acid or organic tartaric acid, alkyl sulfonate betaine, fatty amine polyoxyethylene ether phosphate, hydrochloric acid has been found A report on preparation of oil displacement microlactic acid by mixing

Method used

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  • Oil displacing microemulsified acid system for acidizing plugging removal and preparation method of system
  • Oil displacing microemulsified acid system for acidizing plugging removal and preparation method of system
  • Oil displacing microemulsified acid system for acidizing plugging removal and preparation method of system

Examples

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Effect test

Embodiment 1

[0030] Add 45g of polyhydric acid into a 400ml plastic beaker, heat it in a 60°C water bath to 50-60°C, add 12g of C16 / C18 fatty aminohydroxypropyl sulfonate and 4g of coconut amine polyoxyethylene ether phosphoric acid under stirring After fully dissolving the ester, add 19g of 10% hydrochloric acid, then add 20g of No. 0 diesel oil, and stir for 0.5h to obtain light yellow and transparent oil-displacing microlactic acid.

Embodiment 2

[0032] Add 45g of organic tartaric acid into a 400ml plastic beaker, heat it in a 60°C water bath to 50-60°C, add 12g of C16 / C18 fatty aminohydroxypropyl sulfonate and 4g of coconut amine polyoxyethylene ether under stirring Phosphate ester, after fully dissolved, add 19g of 10% hydrochloric acid, then add 20g of -10 diesel oil, stir for 0.5h, and obtain light yellow and transparent oil-displacing microlactic acid.

Embodiment 3

[0034] Add 65g of polyhydric acid into a 400ml plastic beaker, heat to 50-60°C in a 60°C water bath, add 10g of C16 / C18 fatty aminohydroxypropyl sulfonate and 5g of tallow amine polyoxyethylene ether under stirring After fully dissolving the phosphoric acid ester, add 5g of 10% hydrochloric acid, then add 15g of -20 diesel oil, stir for 0.5h, and obtain light yellow and transparent oil-displacing microlactic acid.

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Abstract

The invention provides an oil displacing microemulsified acid system for acidizing plugging removal and a preparation method of the system. The oil displacing microemulsified acid system is prepared from the following components in percentage by weight: 10-35% of diesel fuel, 40-75% of acid fluid, 10-30% of alkylsulfobetaine, 1-15% of fatty amine polyoxyethylene ether phosphate, and the balance of 10% hydrochloric acid. The preparation method of the system comprises the following steps: weighing the raw materials by weight; firstly, putting acid fluid into a vessel, heating and stirring in water bath at 60 DEG C, adding alkylsulfobetaine and fatty amine polyoxyethylene ether phosphate for dissolving thoroughly, and then adding 10% ydrochloric acid; and next, adding the diesel oil and stirring for 0.5 hour, thereby obtaining the finished product. The oil displacing microemulsified acid system is a thermodynamic stable system, has excellent dissolving property to inorganic matters and organic matters, and excellent oil displacing property, and can be widely applied to the measures of a water injection well and an oil well conversion well.

Description

technical field [0001] The invention relates to the field of oil field chemical agents for oil exploitation, in particular to an oil displacement microlactic acid for acidification and plugging removal and a preparation method thereof. Background technique [0002] Water flooding and chemical flooding are important oil recovery methods in the process of oil production, which are called "2+3" oil recovery by experts at home and abroad. For medium and low permeability reservoirs that are clogged by inorganic and organic substances during water injection, acidification is usually used to remove plugging measures. Because conventional acid systems, such as hydrochloric acid and soil acid, have too fast acid-rock reaction and cannot complete deep plugging removal, retarded acid systems are usually used. Microlactic acid systems are a new type of retarded acid systems developed on the basis of microemulsions. It is a microemulsion spontaneously formed mainly by acids, oils and sur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/52C09K8/58
CPCC09K8/524C09K8/528C09K8/58
Inventor 乔孟占赵英杰赵娜胡彬彬周光林于梦红张晓龙吴炜
Owner 唐山冀油瑞丰化工有限公司
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