Graphene conductive paste with surface adsorption dispersant, its preparation method and application
A surface adsorption, conductive paste technology, applied in the fields of nanotechnology and microelectronics, can solve the problems of easy and irreversible stacking, poor dispersion, etc., and achieve the effects of low cost, long life and good electrical conductivity
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Embodiment 1
[0035] Take 100g graphene powder (the average size is less than 20um, the thickness is 1-30 layers, and the conductivity is not less than 10 5 S / m) and 100g carbon black in ethanol ultrasonic 1h, dry after mixing uniformly to obtain the graphene powder (such as surface adsorption carbon black) figure 2 ). The powder was mixed with 300g ethyl cellulose, 3000g terpineol, and 1000g 10nm silver powder through a vacuum mixer for 3 hours until the slurry was uniform, and then ground for 5 hours by a three-roll machine to obtain a conductive paste with a maximum graphene size of 2 μm. The slurry has a viscosity of 500-3000mPas and a sheet resistance of 10Ω / sq after film formation, and can be used as a conductive ink for printing circuits.
Embodiment 2
[0037] Get 1g graphene powder (with embodiment 1) and 1g carbon black ultrasonic 1h in ethanol, dry after mixing uniformly and obtain the graphene powder of surface adsorption carbon black, this powder is mixed with 3g ethyl cellulose, 30g Terpineol, 30g 10nm silver powder, 2g glass powder, 0.5gTiO 2 , leveling agent BYK-161 0.1g, stirred by a vacuum mixer for 3 hours until the slurry is uniform, and ground by a three-roll machine for 5 hours to obtain a conductive paste, which can be used for the front electrode of a solar cell by screen printing. powerful. The viscosity of the slurry is 1000-3000mPas, and the sheet resistance after film formation is 0.5Ω / sq.
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