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Novel photocuring epoxy polyurethane resin coating for ceramic

A technology of epoxy polyurethane and resin coatings, which is applied in the field of coatings and can solve the problems of slow drying, poor water resistance, excellent and poor weather resistance, etc.

Inactive Publication Date: 2015-04-08
HUZHOU ZHONGCHEN CONSTR
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of the above technical problems, the present application provides a photocurable epoxy polyurethane resin coating for ceramics, which solves the technical problems of the existing ceramic photocurable epoxy polyurethane resin coatings such as slow drying, poor water resistance and poor weather resistance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] A novel photocurable epoxy polyurethane resin coating for ceramics, its raw materials are proportioned as follows in parts by weight: 100 parts of bisphenol A diglycidyl ether; 40 parts of triglycidyl isocyanurate; 80 parts of diglycidyl phthalate; 30 parts of β-lactam; 75 parts of acrylic acid; 25 parts of carbon black; 10 parts of benzoin ether; 35 parts of phosphoric acid; 1 part of methyl melamine; 15 parts of antimony trioxide; 0.1 part of hydroquinone; 20 parts of titanium dioxide; 60 parts of ditricoxypropyl isocyanurate diacrylate.

[0014] After heating the above-mentioned raw materials to 90°C in a reaction kettle, stir for 12 hours and mix evenly, then coat the ceramics, and irradiate the coating film with an ultraviolet lamp.

[0015] The surface drying time of the product is 5s, and the hard drying time is 15s; there is no foaming and shedding after soaking in water for 20 days; no foaming and wrinkling after soaking in saturated calcium hydroxide for 6 day...

Embodiment 2

[0017] A novel photocurable epoxy polyurethane resin coating for ceramics, its raw materials are proportioned as follows in parts by weight: 100 parts of bisphenol A diglycidyl ether; 50 parts of triglycidyl isocyanurate; 90 parts of diglycidyl phthalate; 40 parts of β-lactam; 85 parts of acrylic acid; 35 parts of carbon black; 20 parts of benzophenone; 45 parts of phosphoric acid; 10 parts of triethylamine; 15 parts of barium metaborate; 5 parts of styrene; 25 parts of antimony trioxide; 0.5 parts of hydroquinone; 30 parts of titanium dioxide; 70 parts of ditricoxypropyl isocyanurate diacrylate.

[0018] After heating the above raw materials to 100°C in a reaction kettle, stir for 15 hours and mix them evenly, then coat them on the ceramics, and irradiate the coating film with an ultraviolet lamp.

[0019] The surface drying time of the product is 3s, and the hard drying time is 10s; after soaking in water for 25 days, there is no foaming and shedding; after soaking in satura...

Embodiment 3

[0021] A kind of photocurable epoxy polyurethane resin coating for novel ceramics, its raw material ratio is as follows by weight: 100 parts of bisphenol A diglycidyl ether; 45 parts of triglycidyl isocyanurate; 85 parts of phthalic acid diglycidyl ether; 35 parts of β-lactam; 80 parts of acrylic acid; 30 parts of carbon black; 15 parts of benzophenone; 40 parts of phosphoric acid; 5 parts of triethylamine; 10 parts of barium metaborate; 3 parts of styrene; 20 parts of antimony trioxide; 0.3 parts of hydroquinone; 25 parts of titanium dioxide;

[0022] After heating the above-mentioned raw materials to 95°C in a reaction kettle, stir for 13 hours and mix them evenly, then coat them on the ceramics, and irradiate the coating film with an ultraviolet lamp.

[0023] The surface drying time of the product is 1s, and the hard drying time is 5s; after soaking in water for 30 days, there is no foaming or shedding; after soaking in saturated calcium hydroxide for 8 days, there is no b...

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Abstract

The invention discloses a novel photocuring epoxy polyurethane resin coating for ceramic. The novel photocuring epoxy polyurethane resin coating comprises the following raw materials: bisphenol A tirethylene acrylic acid glyceryl ether, triglycidyl isocyanurate, hexahydro-phthalic acid tirethylene acrylic acid glyceryl ether, beta-lactam, acrylic acid, carbon black, a photosensitizer, phosphoric acid, triethylamine, barium metaborate, a cross-linking agent, antimonous oxide, hydroquinone, titanium dioxide and 2-triglycidyl isocyanurate diacrylate; the surface drying time of the product is 1-5s; the hard drying time is 5-15s; and the novel photocuring epoxy polyurethane resin coating is free of a foaming or shedding phenomenon after being soaked in water for 20-30d, is free of a foaming or wrinkling phenomenon after being soaked in saturated calcium hydroxide for 6-8d, and is free of abnormality after being soaked in 5% hydrochloric acid solution for 5-7d, so that the novel photocuring epoxy polyurethane resin coating can be widely produced, and can continuously replace existing materials.

Description

technical field [0001] The application belongs to the field of coatings, in particular to a photocurable epoxy polyurethane resin coating for ceramics. Background technique [0002] Over the past 30 years of reform and opening up, China's ceramic industry has developed rapidly, and now it has become a veritable ceramic production and consumption country in the world. The output of daily-use ceramics produced in China accounts for about 70% of the world, the output of decorative art ceramics accounts for 65% of the world, and the output of architectural ceramics accounts for half of the world's total output. The ceramic industry occupies a pivotal position in the world's building materials industry. Ceramic coating is a novel ceramic coating that can react organic matter and inorganic matter, thus combining the advantages of both. The hardness of the new generation of ceramic coatings can reach above 6H. High temperature resistance 400 degrees, non-stick effect, a variety ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D163/00C09D7/12C04B41/83
CPCC09D175/14C04B41/4853C04B41/83C08L63/00
Inventor 陆志强
Owner HUZHOU ZHONGCHEN CONSTR