Sustained-release raw hide swelling agent as well as preparation method and application

A technology of bulking agent and rawhide, applied in the field of preparation of sustained-release rawhide bulking agent, can solve the problems of difficulty in controlling the degree of separation and loosening of collagen fibers, severe swelling effect, etc. mud effect

Active Publication Date: 2015-05-13
白银普瑞特化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because the hydrolyzate of sodium silicate is also sodium hydroxide, its swelling effect is also very severe, the fiber expansion is obviously fast, and the looseness of collagen fiber separation is difficult to control

Method used

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  • Sustained-release raw hide swelling agent as well as preparation method and application
  • Sustained-release raw hide swelling agent as well as preparation method and application
  • Sustained-release raw hide swelling agent as well as preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] A slow-release rawhide bulking agent, in the form of granules, has two layers from the inside to the outside, the inner layer is sodium silicate granules, and the sodium silicate granules are covered with polyvinyl alcohol coating.

[0045] The preparation method of this slow-release rawhide bulking agent mainly comprises the following steps:

[0046] (1) Preparation of coating agent

[0047] After dissolving 3 parts by weight of commercially available polyvinyl alcohol PVA-2488 in 50 parts by weight of water at 30 degrees Celsius for 2 hours, add 47 parts by weight of water, stir, heat up to 90 degrees Celsius, stir until the polyvinyl alcohol is fully dissolved, add a small amount of 2 % dilute hydrochloric acid to adjust the pH to 4.0, add 1 part by weight of formaldehyde solution (30%), keep warm at this temperature for 2 hours, adjust the pH of the system to 8.5 with 5% aqueous sodium hydroxide solution, and then cool down for later use;

[0048] (2) Coating agent...

Embodiment 2

[0057] A slow-release rawhide bulking agent, in the form of granules, has two layers from the inside to the outside, the inner layer is sodium silicate granules, and the sodium silicate granules are covered with polycaprolactam coating.

[0058] The preparation method of this slow-release rawhide bulking agent mainly comprises the following steps:

[0059] (1) Preparation of coating agent

[0060] After dissolving 10 parts by weight of commercially available polycaprolactam in 50 parts by weight of water at 30 degrees Celsius for 2 hours, add 40 parts by weight of water, stir, raise the temperature to 90 degrees Celsius, stir until the polycaprolactam is fully dissolved, add a small amount of 5% dilute sulfuric acid to adjust the pH 5.0, add 2 parts by weight of formaldehyde solution (30%), keep warm at this temperature for 2 hours, adjust the pH value of the system to 9.0 with 2% calcium hydroxide aqueous solution, and then cool down for later use.

[0061] (2) Envelope

[...

Embodiment 3

[0070] A slow-release rawhide swelling agent, in the form of granules, with two layers from the inside to the outside, the inner layer is a mixture of sodium silicate and calcium hydroxide particles, and the sodium silicate particles are covered with modified Polyvinyl alcohol coating.

[0071] The preparation method of this slow-release rawhide bulking agent mainly comprises the following steps:

[0072] (1) Preparation of coating agent

[0073] After dissolving 5 parts by weight of commercially available polyvinyl alcohol PVA-1799 in 50 parts by weight of water at 30 degrees Celsius for 2 hours, add 47-40 parts by weight of water, stir, heat up to 90 degrees Celsius, stir until the polyvinyl alcohol is fully dissolved, add A small amount of 3% dilute hydrochloric acid is used to adjust the pH to 4.5, add 1 part by weight of formaldehyde solution (30%), keep warm at this temperature for 2 hours, adjust the pH of the system to 9.0 with aqueous calcium hydroxide solution, and...

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Abstract

The invention discloses a sustained-release raw hide swelling agent. The swelling agent at least comprises two layers from inside to outside, wherein the innermost layer is a raw hide swelling agent particle body coated with at least one layer of polymer coating film. The invention further provides a preparation method of the swelling agent. The preparation method comprises steps as follows: (1) preparation of a coating agent; (2) coating; (3) mixing of products with different release curves. The invention further relates to an application of the sustained-release raw hide swelling agent to a leather alkaline swelling technology. The sustained-release raw hide swelling agent has the advantages as follows: (1) the sustained-release raw hide swelling agent is proper in dissolution speed, controllable in hydrolysis degree, slow and uniform in fiber swelling and suitable for a liming process of various leather, including upper leather; (2) the lime consumption in the liming process is very low, so that sludge during liming is effectively reduced, and the requirement for clean production of leather is met; (3) a hair saving and removing agent is combined for use, so that sodium sulfide or sodium hydrosulfide can be omitted during liming, the sulfide pollution is reduced, and liming waste liquids are easy to filter, recover and recycle.

Description

technical field [0001] The invention belongs to the field of leather processing, in particular to a slow-release raw hide swelling agent of Preparation method and application. Background technique [0002] The degree of separation and looseness of skin collagen fibers directly affects the softness, fullness, elasticity, grain state, physical and mechanical properties and area yield of finished leather. The separation process of skin collagen fibers, as the key to affect the loosening effect of skin collagen fibers, mainly occurs in the liming and hair removal process in the preparation section. Traditional soda sulfide and lime liming for hair removal has been widely used by tanneries because of its low cost, simple operation process, high hair removal efficiency, and moderate swelling effect. However, the low solubility of lime and excessive use lead to a large amount of lime sludge containing organic matter and sulfide in the process of lime-alkali depilation, causing se...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C14C1/06
CPCC14C1/06
Inventor 吴育彪关正祥党建荣邱庭彦高华林马会军张红力高传福李青松
Owner 白银普瑞特化工有限公司
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