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Yarn and fabric made of polyphenylene sulfide fibers and aromatic polymer fibers containing sulphone and production method of yarn and fabric

A technology of aromatic polymer and polyphenylene sulfide fiber, which can be used in the field of flame-retardant yarn and fabrics and clothing made from it, and can solve the problems of poor thermal hydrolysis performance and the like

Active Publication Date: 2015-05-20
中芳新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, although PPS fiber has excellent chemical resistance, its heat resistance temperature does not exceed 180°C, and its thermal hydrolysis resistance is also poor.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Yarn and fabric made of polyphenylene sulfide fibers and aromatic polymer fibers containing sulphone and production method of yarn and fabric
  • Yarn and fabric made of polyphenylene sulfide fibers and aromatic polymer fibers containing sulphone and production method of yarn and fabric

Examples

Experimental program
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preparation example Construction

[0087] In another embodiment, the present invention relates to a method for the preparation of the above-mentioned yarn, said method comprising:

[0088] (i) forming a fiber mixture, said fiber mixture comprising 30-70 parts by weight of aromatic polymer fibers (A) containing sulfone groups and 30-70 parts by weight of polyphenylene sulfide fibers (B), said sulfone-containing The aromatic polymer fiber (A) based on the sulfone group is made from an aromatic polymer containing a sulfone group, and the aromatic polymer containing a sulfone group is polymerized from the following three monomers:

[0089] meta-position aromatic monomer (a) containing diamine group;

[0090] A monomer (b) containing a sulfone group and an amino group;

[0091]Para-position aromatic monomers containing dicarboxylic acid groups or their halides (c);

[0092] In the aromatic polymer containing sulfone groups, the mass percent content of sulfone groups in the polymer is 4-10%; and

[0093] (ii) spin...

Embodiment 1

[0126] Aromatic polymer fiber containing sulfone group / PPS fiber 50 / 50 blend, spinning count 16s / 2, fabric weight 450gsm, plain weave

[0127] 1. Spinning: put 50% aromatic polymer fibers containing sulfone groups and 50% PPS fibers in the bale grabbing area and send them to A035 cotton feeding machine through A2001D bale grabbing machine → FA106 opening machine → A092 cotton box → cotton feeding machine →FA231A Carding Machine→FA302 Drawing Frame→FA481 Roving Frame→FA506 Spinning Frame to make industrial protective clothing yarn.

[0128] 2. Weaving: The finished yarn is made into a bobbin by the GS669 winding machine, and then sent to the GA747 rapier loom to make plain weave fabric.

Embodiment 2

[0130] Aromatic polymer fiber containing sulfone group / PPS fiber 70 / 30 blend, spinning count 30s / 2, fabric weight 250gsm, twill weave

[0131] 1. Spinning: Place 70% aromatic polymer fibers containing sulfone groups and 30% PPS in the bale grabbing area and send them to the A035 cotton feeding machine through the A2001D bale grabbing machine → FA106 opening machine → A092 cotton box → cotton feeding machine → FA231A carding machine→FA302 drawing frame→FA481 roving frame→FA506 spinning frame to make industrial protective clothing yarn.

[0132] 2. Weaving: The finished yarn is made into a bobbin by the GS669 winder, and sent to the GA747 rapier loom to make a twill fabric.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention relates to flame-retardant yarn made of polyphenylene sulfide fibers and aromatic polymer fibers containing sulphone, fabric and garments made of the yarn, and a production method of the yarn, the fabric and the garments. The yarn comprises the polyphenylene sulfide fibers (B) and the aromatic polymer fibers (A) containing sulphone. The aromatic polymer fibers (A) containing sulphone is made of aromatic polymer containing sulphone. The aromatic polymer containing sulphone is polymerized by meta-position aromatic monomer (a) containing diamino, monomer (b) containing sulphone and amino and para-position aromatic monomer (c) containing dicarboxylic acid groups or yl halide (c) of the para-position aromatic monomer. The sulphone accounts for 4-10% in the aromatic polymer. The yarn is good in high temperature resistance and chemical resistance and widely applicable to high-temperature work environments with chemical corrosion.

Description

technical field [0001] The invention relates to a flame-retardant yarn made of sulfone group-containing aromatic polymer fibers and polyphenylene sulfide fibers, fabrics and clothes made therefrom, and their preparation methods. The yarn has good high temperature resistance and chemical resistance at the same time, and can be widely used in high temperature and chemical corrosion working environments. Background technique [0002] In some chemically corrosive working environments, such as chemical wastewater treatment plants, it is necessary to use chemically better materials for chemical liquid filtration. With the improvement of industrial efficiency and the increase of working temperature, the temperature of the processed chemical aqueous solution is getting higher and higher. Accordingly, there is a need for fabrics that are both heat and chemical resistant. [0003] Polyphenylene sulfide (hereinafter referred to as PPS) resin has excellent heat resistance, shielding p...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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IPC IPC(8): D02G3/04C08G69/42D01F6/80B32B27/02B32B27/30B32B27/28A41D31/00
Inventor 汪晓峰钱春芳吴佳陈晟晖张光旭
Owner 中芳新材料有限公司
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