Preparation method of micro-electrolytic iron-carbon filler for degrading industrial wastewater

A technology of industrial wastewater degradation and micro-electrolysis of iron, which is applied in chemical instruments and methods, water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problems of affecting the use effect of fillers, easy decomposition in water, and reduced activity of fillers, etc. problems, to achieve the effect of simple and reasonable preparation method, not easy to hydrolyze, and mild conditions

Active Publication Date: 2017-07-11
WUHAN STEEL NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The problem with the above iron-carbon fillers is that the iron powder they use is uneven, the preparation conditions are harsh, and the sintering temperature is too high to cause the iron powder to oxidize and reduce the activity of the filler. In addition, the existing adhesives still have insufficient strength. , easy to decompose in water, affect the use of fillers and other shortcomings

Method used

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  • Preparation method of micro-electrolytic iron-carbon filler for degrading industrial wastewater

Examples

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preparation example Construction

[0025] A preparation method for degrading micro-electrolytic iron-carbon fillers from industrial wastewater, comprising the following steps:

[0026] (1) Prepare binder: mix sodium silicate, calcium chloride and hydroxypropyl cellulose uniformly by weight to obtain binder;

[0027] (2) Mixing: put iron powder, activated carbon and binding agent into the mixer by weight ratio and mix evenly;

[0028] (3) into a ball: put the raw material mixed in the step (2) into a ball into a ball;

[0029] (4) Drying and molding: heat the pellets obtained in step (3) to 250-300°C in a dryer to dry, and then they can be molded to obtain industrial wastewater degradable micro-electrolytic iron-carbon fillers.

[0030] The prepared industrial wastewater degradable micro-electrolytic iron-carbon filler consists of the following components: 55-70 parts by weight of iron powder, 30-40 parts by weight of activated carbon and 1-2 parts by weight of binder;

[0031] The iron powder is iron powder w...

Embodiment 1

[0037] The micro-electrolytic iron-carbon filler for degrading industrial wastewater consists of the following components: 65 parts by weight of iron powder, 35 parts by weight of activated carbon and 1.5 parts by weight of binder;

[0038] Iron powder is iron powder with 4% carbon content;

[0039] The binder consists of 6 parts by weight of sodium silicate, 2 parts by weight of calcium chloride and 2 parts by weight of hydroxypropyl cellulose.

[0040] The method for preparing the above-mentioned organic pollutant degradation micro-electrolytic iron-carbon filler comprises the following steps:

[0041] (1) Prepare binder: mix sodium silicate, calcium chloride and hydroxypropyl cellulose uniformly by weight to obtain binder;

[0042] (2) Mixing: put iron powder, activated carbon and binding agent into the mixer by weight ratio and mix evenly;

[0043] (3) into a ball: put the raw material mixed in the step (2) into a ball into a ball;

[0044] (4) Drying and forming: heat ...

Embodiment 2

[0046] The micro-electrolytic iron-carbon filler for degrading industrial wastewater consists of the following components: 55 parts by weight of iron powder, 30 parts by weight of activated carbon and 1 part by weight of binder;

[0047] Iron powder is iron powder with 4% carbon content;

[0048] The binder consists of 5 parts by weight of sodium silicate, 1 part by weight of calcium chloride and 1 part by weight of hydroxypropyl cellulose.

[0049] The preparation method is as in Example 1, wherein the drying temperature in step (4) is 300°C.

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Abstract

The invention discloses a method for preparing industrial waste water degraded micro-electrolytic iron-carbon filler, which comprises the following steps: (1) preparing a binder: mixing sodium silicate, calcium chloride and hydroxypropyl cellulose uniformly by weight, That is to get the binder; (2) mixing: put iron powder, activated carbon and binder into the mixer according to the weight ratio and mix evenly; (3) into balls: put the raw materials mixed in step (2) into the Form into balls in a ball machine; (4) Drying and molding: heat the balls obtained in step (3) to 250-300°C in a dryer to dry, and then they can be molded to obtain industrial wastewater degradable micro-electrolytic iron-carbon fillers . The preparation method is simple and reasonable, can be prepared in conventional equipment, and the conditions are mild; the micro-electrolytic iron-carbon filler for industrial pollutant wastewater degradation is spherical, has a large contact surface with sewage, and has good pollutant treatment effect. Industrial wastewater degrades micro-electrolytic iron-carbon fillers without hardening or passivation; the binder used is stable and not easy to hydrolyze.

Description

technical field [0001] The invention relates to a material for degrading industrial waste water pollutants, in particular to a preparation method for degrading micro-electrolytic iron-carbon fillers for industrial waste water. Background technique [0002] The iron-carbon filler is an iron-carbon primary battery composed of iron and carbon. In the absence of electricity, the metal iron forms the positive electrode, and the carbon forms the negative electrode to form the primary battery. A large number of positive electrodes and negative electrodes form a power grid according to a certain ratio. Filtration and electrolytic treatment of industrial wastewater to achieve the purpose of degrading organic pollutants. Further, iron and carbon can be slowly eliminated under the action of acid and alkali (and heavy metals), so as to achieve the purpose of sewage treatment. [0003] The invention patent with the publication number CN101486509 discloses a block micro-electrolytic fill...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/461
Inventor 沈远亮
Owner WUHAN STEEL NEW MATERIAL
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