An Adaptive Hydrogen Production System

A hydrogen production system and self-adaptive technology, applied in the field of hydrogen production, can solve the problems of consumption of hydrogen, fast aging of gas permeable membrane, and failure to solve the source of hydrogen, and achieve automatic recovery and discharge, fuel feeding process and waste liquid discharge process. easy effect

Inactive Publication Date: 2016-11-23
XI AN JIAOTONG UNIV +1
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Problems solved by technology

As a clean power generation technology, fuel cells can be used as portable power generation equipment, but the fuel cell power generation process needs to consume hydrogen continuously. The common method is to carry hydrogen bottles or physical and chemical adsorption hydrogen storage equipment, but there are many methods for the above methods. Disadvantages: firstly, the safety is not high; secondly, the source of hydrogen is not solved, that is, the problem of hydrogen production
For the metal hydride hydrogen production system for portable power supply, the technical problems that need to be solved include: (1) The flow rate of the alkali metal borohydride solution supplied to the catalytic reactor needs to be adaptively and automatically controlled according to the change of the hydrogen consumption of the fuel cell (2) Direction independence, that is, the flow of the fluid in the system has nothing to do with the direction of the container; (3) The reaction waste is automatically recovered; (4) The fuel solution is fed and the reaction waste is discharged easily; (5) When the system is closed, the fuel The alkali metal borohydride solution in the container will slowly hydrolyze and release hydrogen, so the pressure in the container or system will continue to increase and cause safety problems, requiring an effective solution
[0005] The core of the technical solution of US Patent Publication No. US 2006 / 0236606 A1 is the use of gas permeable membrane technology. This solution proposes a conceptual design that requires the gas permeable membrane to be elastic and able to withstand pressure. The membrane needs to be sealed with a solid container Connection, the above requirements are extremely difficult to achieve technically, even if the design concept can be realized, the cost of its realization is very high, and the elastic gas permeable membrane ages quickly, so the service life is short

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  • An Adaptive Hydrogen Production System
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Embodiment Construction

[0027] The invention provides an adaptive hydrogen production system related to alkali metal borohydrides. The alkali metals in compounds such as alkali metal borohydrides are metal elements represented by Group 1 or Group 2 in the periodic table of elements, such as lithium and sodium , potassium, calcium and magnesium, etc., the corresponding borohydride is LiBH 4 , NaBH 4 、KBH 4 , Ca(BH 4 ) 2 and Mg(BH 4 ) 2 . The above-mentioned basic metal borohydride can be dissolved in water, and under the action of a catalyst, the basic metal borohydride will undergo a hydrolysis reaction. Taking sodium borohydride as an example, its hydrolysis chemical reaction formula is:

[0028]

[0029] The alkaline metal borohydride solution will undergo self-hydrolysis reaction. In order to reduce the rate of self-hydrolysis, when configuring the alkaline metal borohydride aqueous solution, add a certain amount of alkali solution corresponding to the basic metal element, such as for NaB...

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Abstract

The invention discloses an adaptive hydrogen production system. The adaptive hydrogen production system comprises a telescopic alkali metal hydroboron solution storage device, a telescopic waste liquid storage device, a reactor, a gas-liquid separator and a piston plate, wherein one end of the telescopic alkali metal hydroboron solution storage device is fixed, and the other end of the telescopic alkali metal hydroboron solution storage device is connected with one end of the piston plate; one end of the telescopic waste liquid storage device is fixed, and the other end of the telescopic waste liquid storage device is connected with the other end of the piston plate; the telescopic alkali metal hydroboron solution storage device is sequentially connected with the reactor and the gas-liquid separator by pipelines, and a liquid outlet of the gas-liquid separator is connected with the telescopic waste liquid storage device. According to the adaptive hydrogen production system, the whole system does not utilize a permeable membrane material; all the adopted components are mechanical components; the hydrogen production reaction speed adapts to automatic control according to the change of hydrogen consumption; the operation of the system has a direction independence characteristic; furthermore, reaction wastes can be automatically recovered, a fuel adding process and a waste liquid discharging process are simple and convenient, and the pressure safety of the system at any state can be ensured.

Description

【Technical field】 [0001] The invention relates to the technical field of hydrogen production, in particular to a hydrogen production system. 【Background technique】 [0002] With the continuous development and progress of economy and technology, more and more electronic devices are carried by individuals, so there is a great market demand for portable power supplies. As a clean power generation technology, fuel cells can be used as portable power generation equipment, but the fuel cell power generation process needs to consume hydrogen continuously. The common method is to carry hydrogen bottles or physical and chemical adsorption hydrogen storage equipment, but there are many methods for the above methods. Disadvantages: firstly, the safety is not high; secondly, the source of hydrogen is not solved, that is, the problem of hydrogen production. [0003] Alkali metal borohydride contains hydrogen atoms, and its solution undergoes a hydrolysis reaction under the action of a c...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B3/06
CPCY02E60/36
Inventor 张兄文曾少华
Owner XI AN JIAOTONG UNIV
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