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A kind of preparation method of anti-aging wood-plastic composite material and light stabilizer

A technology of wood-plastic composite materials and light stabilizers, which is applied in textiles and papermaking, fiber treatment, plant fibers, etc., can solve the problems of complex aging mechanism of wood-plastic composite materials, low molecular weight of light stabilizers, and easy decomposition, etc. Anti-ultraviolet aging performance, good physical and mechanical properties and processability, and the effect of improving processability

Inactive Publication Date: 2017-04-19
GUANGXI TEACHERS EDUCATION UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The solution is to coat a layer of protective film on the surface of the wood-plastic composite material, but for the unavoidable problems such as peeling of the coating on the surface coating, it is necessary to choose a suitable stabilizer, modifier, UV absorber, etc. Can better inhibit the aging of wood-plastic composite materials
[0004] Because wood-plastic composite materials contain plant fibers and plastic matrix at the same time, the aging mechanism of wood-plastic composite materials is very complicated. At present, there are patents on the aging performance of wood-plastic composite materials, such as Chinese patent CN101708617A, which uses wood powder, plastic particles, maleic anhydride, hard Aging-resistant wood-plastic composite boards are prepared by combining fatty acid salts, antioxidants, and ultraviolet absorbers. The ultraviolet absorber used in the patent is 2-hydroxy-4-n-octyloxybenzophenone, which is a traditionally commonly used one. Benzophenone-like UV absorber, the excellent anti-aging performance of general materials comes from the effects of added additives, light stabilizers and antioxidants, etc. This patent does not highlight the anti-aging effect
Chinese patent CN103483846A discloses a kind of anti-aging anti-brittle cold polypropylene-based wood-plastic composite material composed of wood powder, polypropylene, maleic anhydride grafted polypropylene, anti-aging agent, toughening agent, filler, lubricant, but The anti-aging agent used is composed of antioxidant and UV-531, so the light stabilizer has the disadvantages of low molecular weight and easy decomposition during processing.
Chinese patent CN104031399 discloses a composition of wheat straw, polypropylene, mold release agent and anti-aging agent. The anti-aging agent used is UV327, which is also a commonly used light stabilizer in materials. It also has the disadvantages of low molecular weight and easy decomposition; Chinese patent CN104231430A discloses a preparation method and products of anti-fouling and aging-resistant wood-plastic materials, which are composed of PP, wood powder matrix raw materials, nano-carbon black light stabilizers and other auxiliary agents, and the nano-carbon black used has the disadvantages of being difficult to disperse.
Chinese patent CN104356545A discloses a high weather resistance PVC wood-plastic composite material and its preparation method. It uses PVC and sawdust powder as the main raw materials, and then composes with compounding additives and benzotriazole light stabilizer, which has long-term light stability. Insufficient effect is not good

Method used

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  • A kind of preparation method of anti-aging wood-plastic composite material and light stabilizer
  • A kind of preparation method of anti-aging wood-plastic composite material and light stabilizer
  • A kind of preparation method of anti-aging wood-plastic composite material and light stabilizer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] This embodiment adopts existing ultraviolet absorber UV-P as light stabilizer, calcium-zinc composite stabilizer as thermal stabilizer, stearic acid as lubricant, dioctyl phthalate as plasticizer, used for Prepare wood-plastic composite material, the raw material component that it comprises is:

[0057] PVC: 100 parts,

[0058] Modified sisal fiber: 40 parts,

[0059] Heat stabilizer: 2.5 parts,

[0060] Lubricant: 1 part,

[0061] Antioxidant: 0.5 part,

[0062] Plasticizer: 10 parts,

[0063] Light stabilizer: 2 parts;

[0064] Its preparation methods include:

[0065] Step 1. Put the above-mentioned raw material components into a high-speed mixer together, and mix at high speed for 60s to obtain pre-mixed raw materials;

[0066] Step 2. Use an open plastic mixer to plasticize the mixed premixed raw materials. The temperature of the front roller is 175°C, the temperature of the rear roller is 180°C, and the mixing time is 5min-10min;

[0067] Step 3. Place the...

Embodiment 2

[0069] In this embodiment, a comb-shaped composite benzotriazole polymer is used as a light stabilizer, a calcium-zinc composite stabilizer is used as a heat stabilizer, stearic acid is used as a lubricant, and dioctyl phthalate is used as a plasticizer. agent, used to prepare wood-plastic composite materials, the raw material components included are:

[0070] PVC: 100 parts,

[0071] Sisal fiber: 40 parts,

[0072] Heat stabilizer: 2.5 parts,

[0073] Lubricant: 1 part,

[0074] Antioxidant: 0.5 parts,

[0075] Plasticizer: 10 parts,

[0076] Light stabilizer: 3 parts;

[0077] Its preparation methods include:

[0078] Step 1. Put the above-mentioned raw material components into a high-speed mixer together, and mix at high speed for 60s to obtain pre-mixed raw materials;

[0079] Step 2. Use an open plastic mixer to plasticize the mixed premixed raw materials. The temperature of the front roller is 175°C, the temperature of the rear roller is 180°C, and the mixing time...

Embodiment 3

[0082] In this example, a wood-plastic composite material is prepared by using a comb-shaped composite benzotriazole polymer as a light stabilizer, and the raw material components included are:

[0083] PVC: 100 parts,

[0084] Modified sisal fiber: 40 parts,

[0085] Heat stabilizer: 2.5 parts,

[0086] Lubricant: 1 part,

[0087] Antioxidant: 0.5 parts,

[0088] Plasticizer: 10 parts,

[0089] Light stabilizer: 3 parts;

[0090] Its preparation methods include:

[0091] Step 1. Put the above-mentioned raw material components into a high-speed mixer together, and mix at high speed for 60s to obtain pre-mixed raw materials;

[0092] Step 2. Use an open plastic mixer to plasticize the mixed premixed raw materials. The temperature of the front roller is 175°C, the temperature of the rear roller is 180°C, and the mixing time is 5min-10min;

[0093] Step 3. Place the compound obtained in step 2 into a plate vulcanizer and mold it into a plate with a thickness of 4mm. The mo...

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Abstract

The invention discloses a preparation method of an anti-aging wood-plastic composite material and a light stabilizer. The wood-plastic composite material is prepared from the following raw material weight components: 100 parts of polyvinyl chloride, 20-40 parts of sisal fiber, 1-5 parts of heat stabilizer, 1-8 parts of lubricant, and 0.5-2 parts of antioxidant , 6-10 parts of plasticizer, 0.5-5 parts of light stabilizer represented by chemical formula P (HAPBT-co-MTMP-co-AEG-cp-OA). The wood-plastic composite material has a good aging resistance effect due to the addition of a special light stabilizer, and the material has good physical and mechanical properties and processability, which further broadens the application field of the wood-plastic composite material. In terms of some indoor wood materials, it is also suitable for the application of outdoor materials such as architectural decoration, transportation, municipal administration, and gardens.

Description

technical field [0001] The invention relates to a composite material, more specifically, the invention relates to an anti-aging wood-plastic composite material and a preparation method of a light stabilizer. Background technique [0002] Wood-plastic composite materials have been widely used because of their durability, long life, appearance similar to wood materials, low density, better dimensional stability than wood, no cracks, warping, no wood knots, twill, and easy molding. It is applied to various aspects such as construction, various indoor and outdoor planks, various pallets in logistics, some tables and chairs in the garden, and decorative products. In recent years, with the aggravation of air pollution and the increasing scarcity of petroleum resources, the use of natural plant fibers, plastic substrates and waste plastics to make wood-plastic composite materials with excellent performance has become a common concern in the industry and science circles, which has f...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08L97/02C08L33/14C08K13/02C08K5/12C08K5/134C08K5/09C08F220/34C08F220/18C08F220/28C08L23/12D06M13/513D06M101/06
CPCD06M13/513C08F220/18C08F220/28C08F220/34C08L23/12C08L27/06C08L2205/03C08L2201/08D06M2101/06C08F220/346C08L97/02C08L33/14C08K5/12C08K5/1345C08K5/09
Inventor 于淑娟韦德麟陆树文陈宽
Owner GUANGXI TEACHERS EDUCATION UNIV
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