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A micro-scale dynamic dispersion glue

A dispersant and micro-scale technology, which is applied in the field of nano-micro materials and oilfield chemistry, can solve the problems that polymers cannot form colloidal dispersants, difficult gelation, poor adaptability, etc., and achieve excellent long-term stability and extended water flooding Excellent effect on sweep coefficient and erosion resistance

Active Publication Date: 2016-08-31
SOUTHWEST PETROLEUM UNIV
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  • Claims
  • Application Information

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Problems solved by technology

However, the CDG based on the linear polymer of partially hydrolyzed polyacrylamide (HPAM) has the following obvious deficiencies: ① The linear molecule cannot be coiled enough under solution conditions, so it is necessary to add inorganic salts to make the molecular coils coil enough to form intramolecular crosslinks ;②Gel forming conditions are harsh and poor adaptability. CDG is mainly intramolecular crosslinking, requiring low concentration of polymer and crosslinking agent system. Polymers with lower concentrations cannot form colloidal dispersion gels; ③ It is difficult to form gels in the formation, affected by diffusion, dispersion, retention (adsorption, mechanical trapping), shear degradation, etc., the polymer seepage process in the formation Medium concentration and viscosity loss are serious. In order to solve the above unfavorable factors, the concentration of the polymer is usually increased, which causes the polymer to form a weak gel mainly due to intermolecular crosslinking during the initial injection process, increasing the injection pressure and failing to reach the reservoir. deep regulation
The above unfavorable factors have hindered the popularization and application of CDG in my country's oilfields

Method used

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  • A micro-scale dynamic dispersion glue
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  • A micro-scale dynamic dispersion glue

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Embodiment 1

[0030] Embodiment 1 each component weight ratio is:

[0031] 1. Main agent hyperbranched polymer: 0.075% to 0.175%,

[0032] 2. Cross-linking agent citrate: 0.005% to 0.0125%,

[0033] 3. Cross-linking agent aluminum trichloride: 0.0075% to 0.0175%,

[0034] 4. Stabilizer sulfite: 0.005% to 0.01%,

[0035] 5. The rest is water.

[0036] The hyperbranched polymer mother liquor with a mass concentration of 0.5% was prepared with suction-filtered oilfield injection water (see Table 1 for the ion composition), and was left to stand for 24 hours before use. Distilled water was used to prepare 1.0% lemon salt solution, 1.0% aluminum chloride solution and 1.0% sulfite solution respectively. Add a certain amount of 0.5% hyperbranched polymer mother liquor, 1.0% lemon salt solution, 1.0% aluminum chloride solution, and 1.0% sulfite to a 120ml jar according to the set system concentration solution, add quantitative oil field injection water, and prepare 100ml of micro-scale dynamic...

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Abstract

The invention discloses a micro-scale dynamic dispersion agent and a preparation method thereof. The micro-scale dynamic dispersion agent comprises, in weight percent, 0.075%-0.15% of hyper-branched polymer, 0.005%-0.0125% of citrate, 0.0075%-0.015% of aluminum trichloride, 0.005%-0.01% of sulfite and the rest water, wherein the hyper-branched polymer is polyamide-amine hybrid nano-silica hyper-branched polymer. The preparation method includes the steps: sequentially adding hyper-branched polymer solution, citrate solution, aluminum trichloride solution and sulfite solution; adding oilfield injection water to prepare micro-scale dynamic dispersion agent base solution; placing the micro-scale dynamic dispersion agent base solution in a constant temperature oven and aging the micro-scale dynamic dispersion agent base solution into the agent. The dynamic dispersion agent can automatically change micro-scale under the condition of different mineralization degrees and is applicable to deep profile control of an oil reservoir with medium-high temperature and a wide mineralization degree, adaptivity of the oil reservoir is realized, and injection water development effects are improved.

Description

technical field [0001] The invention relates to a micro-scale dynamic dispersant, which belongs to the field of nano-micro materials and oil field chemistry. Background technique [0002] After a short period of elastic energy extraction, the oil field enters the stage of supplementary energy development. Water flooding is still the preferred technology for oilfield development. The water flooding stage endows other functions besides replenishing formation energy and has become a hot topic in the world's oil industry. After years of water injection development, the oilfield has entered the "double high stage" of high water cut and high water production. At the same time, the contradiction between the profile and the plane is prominent, water channeling is serious, and it is difficult to stabilize production. Laboratory research and field tests have proved that chemical flooding is an important strategic technology to improve the recovery rate and injection development effec...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/588
CPCC09K8/588
Inventor 蒲万芬刘锐赵磊石国新孙琳毛天聪
Owner SOUTHWEST PETROLEUM UNIV
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