Flame retardation PTT polyester fiber and preparation method therefor

A technology of polyester fiber and flame retardant, which is applied in the field of flame-retardant PTT polyester fiber and its preparation, which can solve the problems of low dimensional stability, poor flame retardancy, and poor heat resistance, and achieve soft and excellent hand feeling. Flame retardant performance and heat resistance performance, and the effect of strong wearability

Inactive Publication Date: 2015-08-26
QINGDAO XINZHAN PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polytrimethylene terephthalate (PTT), as a new type of polyester polymer material with excellent comprehensive properties, has been widely used in the fields of fibers, films, engineering plastics, etc., but PTT alone has poor flame retardancy and heat resistance. The problems of poor quality and low dimensional stability limit its application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A kind of flame-retardant PTT polyester fiber, its components are proportioned by mass percentage: PTT 85%, flame retardant monomer 8%, polyethylene glycol 4%, phenylmethyl silicone 1.5%, perfluorobutyl Potassium sulfonate 0.1%, trimethyl phosphate 0.3%, antioxidant 0.3%, pentaerythritol stearate 0.8%, wherein, the PTT is made from terephthalic acid and 1,3-propanediol Polytrimethylene terephthalate with an intrinsic viscosity of 0.7-0.9dL / g, the flame retardant monomer is 2-hydroxyethyl (phenyl) phosphinic acid, and the antioxidant is tetrakis[β-(3 , 5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester.

[0019] Preparation method: (1) Preparation of flame retardant monomer pre-polymerization liquid: take flame retardant monomer and a certain mass of 1,3-propanediol and add it to esterification, so that 1,3-propanediol is used as solvent, flame retardant The mass percent concentration of the flame retardant monomer is 20-40wt% slurry, and then add the ca...

Embodiment 2

[0021] A kind of flame-retardant PTT polyester fiber, its components are proportioned by mass percentage: PTT 91%, flame retardant monomer 5%, polyethylene glycol 2.5%, phenylmethyl silicone 1%, perfluorobutyl Potassium sulfonate 0.1%, triphenyl phosphate 0.1%, antioxidant 0.1%, pentaerythritol stearate 0.2%, wherein, the PTT is prepared from terephthalic acid and 1,3-propanediol Polytrimethylene terephthalate with an intrinsic viscosity of 0.7-0.9dL / g, the flame retardant monomer is 2-hydroxyethyl (phenyl) phosphinic acid, and the antioxidant is tetrakis[β-(3 , 5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester.

[0022] Preparation method: (1) Preparation of flame retardant monomer pre-polymerization liquid: take flame retardant monomer and a certain mass of 1,3-propanediol and add it to esterification, so that 1,3-propanediol is used as solvent, flame retardant The mass percent concentration of the flame retardant monomer is 20-40wt% slurry, and then add th...

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Abstract

The invention discloses a flame retardation PTT polyester fiber and a preparation method therefor. The flame retardation PTT polyester fiber comprises the following ingredients, by weight, 80%-95% of PTT, 2%-8% of flame retardant monomers, 2%-6% of polyethylene glycol, 0.5%-2% of benzyl silicone, 0.1%-0.5% of potassium Perfluorobutanesulfonate, 0.1%-0.5% of stabilizing agents, 0.1%-0.5% of anti-oxidants and 0.1%-1% of lubricants. The PTT is polytrimethylene terephthalate prepared from terephthalic acid and 1,3-propylene glycol as raw materials and with an intrinsic viscosity of 0.7-0.9dL/g. The flame retardant monomers are 2-hydroxyethyl (phenyl) phosphinic acid. The beneficial effects are that the flame retardation PTT polyester fiber has excellent flame retardation performance and heat resistance, the limit oxygen index can reach more than 38%, the hand feeling is soft, the serviceability is strong, and the flame retardation PTT polyester fiber is suitable for the textile fabric field.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a flame-retardant PTT polyester fiber and a preparation method thereof. Background technique [0002] Polytrimethylene terephthalate (PTT), as a new type of polyester polymer material with excellent comprehensive properties, has been widely used in the fields of fibers, films, engineering plastics, etc., but PTT alone has poor flame retardancy and heat resistance. The problems of poor quality and low dimensional stability limit its application. Contents of the invention [0003] The object of the present invention is to provide a flame-retardant PTT polyester fiber and a preparation method thereof. [0004] The technical solution adopted by the present invention to solve the technical problem is: a kind of flame-retardant PTT polyester fiber, its components are proportioned by mass percentage: PTT 80%-95%, flame retardant monomer 2%-8%, Polyethylene glycol 2%~6%, ph...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/92D01F1/07C08G63/692
Inventor 不公告发明人
Owner QINGDAO XINZHAN PLASTIC
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