Production method of metal deactivator

A technology of metal deactivator and production method, applied in the direction of chemical instruments and methods, catalyst protection, physical/chemical process catalysts, etc., can solve the problems of poor stability, large dosage, high toxicity, etc., and achieve the effect of optimizing the production process

Inactive Publication Date: 2015-09-23
江苏常州酞青新材料科技有限公司
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  • Summary
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  • Application Information

AI Technical Summary

Problems solved by technology

Most of the traditional bimetallic passivators are antimony-tin bimetallic passivators, which have high toxicity, poor stability and large dosage

Method used

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Experimental program
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Embodiment 1

[0016] A production method of a metal deactivator, comprising the following steps: A, its main components include 400-500kg of mother liquor A, 60-200kg of mother liquor B and 7-30kg of a pH regulator, after adding deionized water, stirring for 30- 60;

[0017] B. Preparation of mother liquor A: first, add 1-30kg of pH regulator, 20-40kg of organic acid, and 30-90kg of organic amine into a 630kg reaction flask, and stir for 20min; then add 90-230kg of antimony powder, and continue to increase the temperature by 50 Add 130-200 kg of oxidizing agent dropwise at ~100°C, condense and reflux for 1-2 hours; finally add 35-40 kg of stabilizer, stir and cool down to room temperature, and discharge to obtain mother liquor A; in the step B, the pH regulator is ethylenediamine. In the step B, the organic acid is benzoic acid. In the step B, the organic amine is monoethanolamine or diethanolamine. In the step B, the stabilizer is one or more of potassium carbonate, ammonium dihydrogen p...

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PUM

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Abstract

The invention provides a production method of a metal deactivator. The production method comprises the following steps that A, main components of the metal deactivator comprise 400 kg to 500 kg of mother liquor A, 60 kg to 200 kg of mother liquor B and 7 kg to 30 kg of PH conditioning agents, and after deionized water is added, stirring is carried out for 30-60 minutes. According to the rare earth element catalytic cracking double-metal deactivator, selection of system stabilizers is achieved in the process of improving system stability, selection of the pH conditioning agents is achieved in the process of improving product PH, and meanwhile selection of rare earth powder is achieved in the process of replacing a traditional antimony-tin double-metal deactivator. A midbody of the mother liquor A and the mother liquor B is prepared, a final product can be adjusted conveniently at any time, and the production process is optimized. According to the rare earth element catalytic cracking double-metal deactivator, selection of the system stabilizers is achieved in the process of improving system stability, and selection of the pH conditioning agents is achieved in the process of improving the product PH. The production process is optimized.

Description

technical field [0001] The invention relates to a catalytic cracking metal passivator, in particular to a production method of the metal passivator. Background technique [0002] In the process of catalytic cracking, especially in the process of catalytic cracking with heavy oil as raw material, the raw oil contains heavy metals, such as nickel, copper, iron and other heavy metal ash deposited on the surface of the catalyst, resulting in catalyst poisoning and deactivation and selectivity decline, thus The yield of light oil decreases, and the yield of hydrogen and coke increases. In view of the metal pollution of catalytic cracking catalysts, in addition to demetallization pretreatment of raw materials and selection of catalysts with strong metal resistance, the industry can also improve the properties of catalysts by increasing the replacement rate of catalysts, and use passivators to inhibit The poisonous effect of the metal in the raw material on the catalyst. Among th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J33/00
Inventor 陈晓洲蒋明
Owner 江苏常州酞青新材料科技有限公司
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