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Hydrophobic full-degradable plastic film and making method of hydrophobic full-degradable plastic film

A technology of plastic film and production method, which is applied in the field of hydrophobic fully degradable plastic film and its production, can solve the problems of limited single modification method, high brittleness, water resistance, poor processing performance, etc., and achieve good mechanical properties and hydrophobic properties. Effect of increasing compatibility and improving water resistance

Inactive Publication Date: 2015-09-23
TONGLING FOUNDER PLASTICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the characteristics of natural polymers: poor processing performance, brittleness and water resistance, etc., their application range is limited.
To solve this problem, a single modification method such as plasticizing, acid adjustment, crosslinking, filling or blending is often used. However, this single modification method is limited, and the fully degradable plastic film prepared has a single function and high cost. Industrial production
Nano-silica materials have special functional effects of nanoparticles, which can be used to improve the mechanical properties and water resistance of natural polymer films and polyvinyl alcohol films. There are very few research reports on composite films with polyvinyl alcohol

Method used

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Embodiment Construction

[0013] The hydrophobic fully degradable plastic film is characterized in that it is made of the following raw materials in parts by weight: polyvinyl alcohol 112, potato starch 83, nano silicon dioxide 2, ethyl diazoacetate 2.9, sodium hypochlorite 0.04, Sodium periodate 0.3, antimony trioxide 0.5, lignin fiber 11, tall oil 8, appropriate amount of water.

[0014] The preparation method comprises the following steps:

[0015] (1) Add an appropriate amount of water to the potato starch and stir to form a paste, heat and pre-gelatinize for 10-20 minutes, add sodium periodate and ethyl diazoacetate, stir and mix at a constant temperature for 2-3 hours, suction filter and dry naturally to obtain modification potato starch;

[0016] (2) Vacuum dry the lignin fiber at 105°C for 2-4 hours, add tall oil and nano-silica, stir and grind for 2-3 hours, and dry;

[0017] (3) Put polyvinyl alcohol in a water bath at 80-90°C and keep it warm for 30-40 minutes, add the materials in steps (...

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Abstract

The invention discloses a hydrophobic full-degradable plastic film and a making method of the hydrophobic full-degradable plastic film. The making method of the hydrophobic full-degradable plastic film lies in that polyvinyl alcohol and potato starch are used as main film forming matters, and compared with the prior art, the making method is characterized in that with the adoption of a physical-chemical method, nanosilicon dioxide and potato starch are modified, and at the same time, through matching with other effective constituents, hydroxide radicals in potato starch and polyvinyl alcohol molecules are enabled to be preferably combined with an appropriate amount of nanosilicon dioxide surface hydroxyl groups to form hydrogen bonds, so that the compatibility degree of potato starch and polyvinyl alcohol is increased, part of hydroxide radicals in the potato starch and polyvinyl alcohol are blocked, the water resisting property of the plastic film is improved, and the prepared full-degradable plastic film has a good mechanical property and hydrophobic property, and further has no impacts on the biodegradation rate and can enable the biodegradable plastics to be extensively applied.

Description

technical field [0001] The invention relates to the technical field of natural polymer materials, in particular to a hydrophobic fully degradable plastic film and a manufacturing method thereof. Background technique [0002] Synthetic polymer materials bring great convenience to people's life, but also cause serious pollution to the environment. In addition, the oil reserves for making traditional plastics are constantly decreasing. Therefore, renewable and environmentally friendly natural polymer materials have become a research hotspot. , Cellulose, starch, protein, etc. are natural polymers that are actually studied and applied more at present, so natural polymer-type fully degradable materials have become one of the research hotspots of new environment-friendly materials. [0003] Natural polymers have attracted extensive attention in the fields of food packaging and plastic film applications due to their wide source of raw materials, strong biodegradability and excellen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L29/04C08L3/02C08K13/06C08K3/36C08K3/22
Inventor 陈可夏陈可亮潮建平
Owner TONGLING FOUNDER PLASTICS TECH
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