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Carbon-nanotube-based transparent antistatic pressure-sensitive adhesive structure and application thereof

A carbon nanotube, anti-static technology, applied in the direction of adhesives, film/flake adhesives, etc., can solve problems such as unfavorable product detection, waste of conductive materials, disadvantages, etc., to achieve excellent anti-static ability, protection, safety and cleanliness , the effect of large application market

Inactive Publication Date: 2015-09-30
SUZHOU HANANO MATERIALS TECH LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The former needs to add conductive materials to the pressure-sensitive adhesive, which will not only affect the adhesive performance of the pressure-sensitive adhesive, but also cause conductive substances to remain on the surface of the product, which greatly limits the selectivity of the pressure-sensitive adhesive.
Although the latter will not have such problems, because the conductive substances used are often in the form of particles, and to ensure that these particles form a continuous conductive network, it is necessary to use a considerable amount of conductive substances, which will affect both the pressure-sensitive adhesive and the substrate. The bonding strength of the material will also cause waste of conductive materials, which is not conducive to reducing costs; at the same time, too much conductive material will also affect the transparency of the protective film, which is not conducive to testing the product without tearing off the protective film

Method used

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  • Carbon-nanotube-based transparent antistatic pressure-sensitive adhesive structure and application thereof
  • Carbon-nanotube-based transparent antistatic pressure-sensitive adhesive structure and application thereof
  • Carbon-nanotube-based transparent antistatic pressure-sensitive adhesive structure and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] 1. Preparation of carbon nanotube dispersion: Weigh 1g of multi-walled carbon nanotubes and 2g of SDBS (sodium dodecyl benzene sulfonate, CAS No. 25155-30-0) into 1L of water, and ultrasonicate the system for 30min with a cell pulverizer , and then transferred to a satellite ball mill at a speed of 600 rpm for high energy ball milling for 2 hours. The viscous liquid obtained was filtered through a coarse sieve to remove the zirconium beads, and then centrifuged at 10,000 rpm for 10 minutes in a high-speed centrifuge to remove the precipitate to obtain a carbon nanotube dispersion.

[0046] 2. Preparation of carbon nanotube coating solution: add 20g of SDS (sodium dodecyl sulfate) to the carbon nanotube dispersion solution, and stir with a magnetic stirrer to dissolve the SDS quickly to obtain a viscous dispersion system.

[0047] 3. After the 50μm thick PET substrate is glued to the surface dust by double-sided sticky rollers, it enters the dimple coating unit. The temp...

Embodiment 2

[0051] 1. Preparation of carbon nanotube dispersion: Weigh 1g of double-walled carbon nanotubes and place them in 1L of DMF (dimethylformamide). Ultrasonicize the system for 100min with a cell pulverizer, then transfer it to a satellite ball mill for High energy ball milling at 600rpm for 5h. The viscous liquid obtained was filtered through a coarse sieve to remove the zirconium beads, and then centrifuged at 10,000 rpm for 10 minutes in a high-speed centrifuge to remove the precipitate to obtain a carbon nanotube dispersion.

[0052] 2. After the 50μm thick PET substrate is glued to its surface by double-sided dust-adhesive rollers, it enters the slit coating unit. The temperature of the oven is set at 160°C, and the machine speed is adjusted to 30m / min, and carbon nanometers are coated on the PET surface. tube conductive layer. A transparent carbon nanotube conductive coating is obtained by drying at a high temperature, and tests show that its structure is similar to Embodi...

Embodiment 3

[0056] 1. Preparation of carbon nanotube dispersion: Weigh 1g of single-walled carbon nanotubes and place them in 1L of deionized water. Ultrasonicize the system for 30min with a cell pulverizer, and then transfer it to a satellite ball mill for high-energy ball milling at 600rpm for 1h. . The viscous liquid obtained was filtered through a coarse sieve to remove the zirconium beads, and then centrifuged at 10,000 rpm for 10 minutes in a high-speed centrifuge to remove the precipitate to obtain a carbon nanotube dispersion.

[0057] 2. Preparation of carbon nanotube coating solution: add 20g of SDS (sodium dodecyl sulfate) to the carbon nanotube dispersion solution, and stir with a magnetic stirrer to dissolve the SDS quickly to obtain a viscous dispersion system.

[0058] 3. After the 30μm thick PET substrate is glued to the surface dust by the double-sided dust-adhesive roller, it enters the dimple coating unit. The oven temperature is set to 120°C, and the machine speed is a...

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Abstract

The utility model discloses a transparent anti-electrostatic pressure-sensitive adhesive structure based on carbon nanotubes and an anti-electrostatic protecting membrane. The pressure-sensitive adhesive structure comprises a carbon nanotube transparent conductive network and a pressure-sensitive adhesive layer which is overlapped with the carbon nanotube transparent conductive network. The anti-electrostatic protecting membrane comprises a base material, the carbon nanotube transparent conductive network covering one side of the base material, and the pressure-sensitive adhesive layer covering the carbon nanotube transparent conductive network, has excellent anti-electrostatic property, has electrostatic voltage less than 100V when being rapidly peeled off from a base body such as glass and plastic, and can effectively protect the security and the cleanness of electronic equipment; meanwhile the carbon nanotube transparent conductive network has great porosity, does not affect the combination of the base material with the pressure-sensitive adhesive, is applicable to various normal pressure-sensitive adhesives, is easy to prepare and low in cost, and has a great application market.

Description

technical field [0001] The invention relates to a pressure-sensitive adhesive layer of a protective film, in particular to a transparent antistatic pressure-sensitive adhesive layer based on a carbon nanotube conductive network and a preparation method thereof, which can be applied to the protection of electronic products. Background technique [0002] At present, in the process of production, storage and transportation of electronic products, the surface protection of products is indispensable. On the one hand, this protection can prevent the surface of the product from being worn, and on the other hand, it can prevent dust from adhering to the surface of the product. As a protective film used for electronic products, in addition to requiring it to be easily attached to the surface of the product, in order to prevent excessive electrostatic voltage that may even endanger the safety of electronic products during the process of tearing off the protective film, the protective ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J7/02
Inventor 陈新江
Owner SUZHOU HANANO MATERIALS TECH LTD
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