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Active openings agent, reticulated urethane foam material and preparation methods for active openings agent and reticulated urethane foam material

A polyurethane foam and cell opener technology, applied in the chemical industry, can solve the problems of poor product quality, potential safety hazards, uneven cells, etc., and achieve improved operating latitude, no potential safety hazards, and uniform cells. Effect

Active Publication Date: 2015-10-21
SHANGHAI MAIPU NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The object of the present invention is to provide a kind of active cell-opening agent, described this active cell-opening agent will solve the inhomogeneous cell of reticulated polyurethane foam in the prior art, poor product quality, high reject rate during preparation, Dangerous operation and technical problems of potential safety hazards during blasting

Method used

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  • Active openings agent, reticulated urethane foam material and preparation methods for active openings agent and reticulated urethane foam material
  • Active openings agent, reticulated urethane foam material and preparation methods for active openings agent and reticulated urethane foam material
  • Active openings agent, reticulated urethane foam material and preparation methods for active openings agent and reticulated urethane foam material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The first step: the active cell opener component (1) - the preparation of the diol or polyol of the oxyalkylene ether with 2 or more primary hydroxyl structures reacted with the first acid anhydride

[0044] In a 500ml four-necked flask with a fixed device, a constant temperature function, a mechanical stirrer, a thermocouple, a vacuum device and nitrogen gas, add 250g of n-butanol starting weight average molecular weight of 1500 oxirane groups and The weight percentage of propylene oxide group is 1 / 1 polyoxyalkylene ether alcohol, then add 50 grams of acetic anhydride, use nitrogen protection, start stirring, use a heating mantle to heat to 120 ° C, stir for 8 hours, add 200 ppm of polyether Refining the adsorbent, reacting for 1 hour, cooling to 35-50 degrees and filtering to obtain a clear and transparent light yellow liquid. This product is referred to herein as active cell opener component (1).

[0045] The second step: compounding of active cell opening agent

...

Embodiment 2

[0048] The first step: the active cell opener component (1) - the preparation of the diol or polyol of the oxyalkylene ether with 2 or more primary hydroxyl structures reacted with the first acid anhydride

[0049] In a 500ml four-necked flask with a fixed device, a constant temperature function, a mechanical stirrer, a thermocouple, a vacuum device and nitrogen gas, add 250g of allyl alcohol starting weight average molecular weight of 3000 oxirane groups and The weight percentage of propylene oxide group is 1 / 1 polyoxyalkylene ether alcohol, then add 30 grams of acetic anhydride, use nitrogen protection, start stirring, use a heating mantle to heat to 120 ° C, stir for 8 hours, add 200 ppm of polyether Refining the adsorbent, reacting for 1 hour, cooling to 35-50 degrees and filtering to obtain a clear and transparent light yellow liquid. This product is referred to herein as active cell opener component (1).

[0050] The second step: compounding of active cell opening agent...

Embodiment 3

[0052] Embodiment 3 prepares reticulated polyurethane flexible foam:

[0053] Adopt above-mentioned embodiment 1, embodiment 2, select for use to add the prescription of activating agent cell opener as comparative example 1, implement the reticular polyurethane flexible foam that 2 prepares, select foam density as 24kg / m 3 The formula, the result is as following table 1:

[0054] According to the formula in Table 1, weigh the required polyether polyol V-3010, deionized water, amine catalyst Dabco*33LV, silicone surfactant BL-580NA, and dichloromethane. Then the mixture was stirred at 1500 revolutions per minute for 2 hours, and then the mixture was stored in a storage tank with a temperature-controlled water bath, and slowly stirred until the temperature of the polyether composite material was controlled at 21 degrees.

[0055] According to the formula in Table 1, in a container with a capacity of about 100L, the polyether combination material, activator cell opener, and stan...

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Abstract

The invention provides an active openings agent. The active openings agent is composed of a compound generated through reaction of dihydric alcohol of oxyalkylene ether with two or more primary hydroxyl group structures or polyhydric alcohols and first acid anhydride, at least one amine compounds, at least one acid or second acid anhydride, a compound containing phosphorus and simethicone. The invention further provides a preparation method for the active openings agent. The invention provides an areticulated urethane foam material which is composed of polyether polyol, deionized water, dichloromethane, stannous octoate, amine catalyst, TDI80 / 20, organosilicon surfactant and an openings agent. The further provides a preparation method for the reticulated urethane foam material. The novel active openings agent is used for preparing the reticulated urethane flexible foam material, the opening performance of the foam material can be improved, the operation tolerance level of the technology is improved, the foam material is prevented from contracting, and safety is high.

Description

technical field [0001] The invention belongs to the field of chemical industry and relates to an active cell opener, a reticular polyurethane foam and a preparation method thereof. Background technique [0002] Flexible polyurethane foam (commonly known as polyurethane foam) is usually made of polyether polyol or polyester polyol, water, amine catalyst, silicone surfactant, tin catalyst, physical blowing agent, other additives and isocyanate Mixing under high-speed stirring, the polyol, water and isocyanate react quickly under the action of the catalyst to form a foam with a network structure. Stop expanding, and finally the gas inside the foam volatilizes from the foam, and the foam reaches the maximum volume. After the gas volatilizes, the foam slightly falls back, and it is basically formed after five minutes. [0003] Reticulated polyurethane flexible foam belongs to a new type of functional foam in flexible polyurethane foam, also known as filter cotton, mesh sponge, b...

Claims

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Application Information

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IPC IPC(8): C08J9/00C08G65/336C08G65/335C08G65/333C08G65/332C08G18/76C08G18/48C08J9/14C08L75/04C08G101/00
Inventor 张文凯龚国安谢海波
Owner SHANGHAI MAIPU NEW MATERIAL TECH CO LTD
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