Novel superimposed perovskite solar cell preparation method

A solar cell and perovskite technology, applied in circuits, photovoltaic power generation, electrical components, etc., can solve the problems of high process cost, expensive price, and inability to meet large-scale large-scale production

Active Publication Date: 2015-10-21
无锡暄时光电科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the metal electrode gold and silver evaporation process is complicated, the energy consumption is high, and the preparation process needs to be completed within 10 -4 Completed in a vacuum of Pa, this condition can be achieved in the laboratory, but it is difficult to achieve in large-scale production
At the same time, precious metals such as gold and silver are expensive, and the process cost is high, which cannot meet the large-scale large-scale production, and at the same time faces the risk of metal electrodes being corroded by other functional layers.

Method used

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  • Novel superimposed perovskite solar cell preparation method
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  • Novel superimposed perovskite solar cell preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] Weigh 40 mg of PEDOT:PSS granules, add 5 ml of isopropanol, and then add some zirconium beads and put them together in a desktop disperser for ball milling at a frequency of 35 Hz for 4 hours. After ball milling, pipette 250uL of the mixture of PEDOT:PSS and isopropanol with a pipette gun, and spray the mixture evenly onto the prepared Spiro-MeOTAD film with a spray gun in a thermal spraying method at a spraying temperature of 95°C. Then pipette 500uL of the mixture of PEDOT:PSS and isopropanol with a pipette gun, and spray the mixture evenly on the FTO glass substrate with a spray gun in a thermal spraying method, and the spraying temperature is 95°C. The surface morphology of PEDOT:PSS film obtained by ball milling method, such as figure 1 shown. Then assemble the device and test the photoelectric performance, at AM1.5, 100mW / cm 2 Use KEITHLEY 4200 to test the I-V performance curve of the battery under light, and the short-circuit current density of the battery is 1...

Embodiment 2

[0048] Weigh 40 mg of PEDOT:PSS granules, add 5 ml of isopropanol, and carry out mixing and dispersion under the condition of ultrasonic vibration, the frequency of ultrasonic vibration is 35 Hz, and the time is 2 h. After oscillating, pipette 250uL of the mixture of PEDOT:PSS and isopropanol with a pipette gun, and spray the mixture evenly onto the prepared Spiro-MeOTAD membrane with a spray gun in a thermal spraying method at a spraying temperature of 95°C. Then pipette 500uL of the mixture of PEDOT:PSS and isopropanol with a pipette gun, and spray the mixture evenly on the FTO glass substrate with a spray gun in a thermal spraying method, and the spraying temperature is 95°C. The surface morphology of PEDOT:PSS film obtained by ultrasonic oscillation method, such as figure 2 shown. Then assemble the device and test the photoelectric performance, at AM1.5, 100mW / cm 2 Use KEITHLEY 4200 to test the I-V performance curve of the battery under light, and the short-circuit curr...

Embodiment 3

[0050] Weigh 40 mg of PEDOT:PSS granules, add 5 ml of isopropanol, and then add some zirconium beads and place them together in a desktop disperser for ball milling at a frequency of 45 Hz for 3 hours. After ball milling, use a pipette gun to pipette different amounts of mixtures of PEDOT:PSS and isopropanol, and spray the mixture evenly onto the prepared Spiro-MeOTAD film by thermal spraying with a spray gun at a spraying temperature of 65°C . Then pipette 500uL of the mixture of PEDOT:PSS and isopropanol with a pipette gun, and spray the mixture evenly on the FTO glass substrate with a spray gun in a thermal spraying method, and the spraying temperature is 65°C. Then assemble the device and test the photoelectric performance, at AM1.5, 100mW / cm 2 Use KEITHLEY 4200 to test the I-V performance curve of the battery under light, such as Figure 5 As shown, when the layer I spraying amount is 125uL, the short-circuit current density of the battery is 17.88mA / cm 2 , the open ci...

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Abstract

The invention provides a novel superimposed perovskite solar cell preparation method. A first block electrode is composed of a substrate and PEDOT:PSS. A second block electrode is composed of FTO, TiO2, perovskite, Spiro-MeOTAD, and PEDOT:PSS. The two block electrodes are superimposed so as to form the superimposed perovskite solar cell. A Layer I comprises thermally spraying PEDOT:PSS spraying liquid with different amount on a Spiro-MeOTAD film. A Layer II comprises thermally spraying PEDOT:PSS spraying liquid with different amount on a back electrode substrate. According to the superimposed perovskite solar cell, holes generated by the perovskite can be successfully extracted. The superimposed perovskite solar cell is simple in making technology and low in cost. Vacuum is prevented and the substrate can be flexibly transformed. The method is beneficial to flexible design of the nanometer structure of the electrodes and large-scale manufacture of the perovskite solar cells.

Description

technical field [0001] The invention relates to a preparation method of a novel laminated perovskite solar cell. Background technique [0002] At present, 80-85% of human energy supply comes from traditional fossil fuels, such as coal, oil and natural gas, etc. These fossil fuels are unevenly distributed below the surface and have limited reserves. , produces a large amount of greenhouse gases, which is one of the factors that accelerate global warming, and is also accompanied by the production of a large number of environmental pollutants, resulting in serious environmental pollution and threatening human health. Renewable energy is the development direction of future energy because of its sustainability, cleanliness and environmental protection. Among renewable energy sources, solar energy, as a new type of energy source, is considered to be one of the most important new energy sources in the 21st century. [0003] Solar energy is an inexhaustible and huge clean energy. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/42H01L51/44H01L51/48
CPCH10K30/151H10K30/81Y02E10/549
Inventor 史彦涛侯凯莉邢玉瑾
Owner 无锡暄时光电科技有限公司
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