This invention relates to a PEDOT solution, an electrochemical sensing
electrode, and a preparation method thereof, comprising 75-200 parts of a PEDOT:PSS
aqueous dispersion, 3-10 parts of an
organic solvent, and 0.3-2 parts of a crosslinking agent, wherein the crosslinking agent is a
silane coupling agent. Through the synergistic ratio of these components, a composite functional layer is formed on the
electrode surface, solving the problems of insufficient interfacial
wetting and electro-drift caused by the hydrophobicity of traditional
electrode substrates, ensuring stable
solid-liquid interfacial contact between the electrode and detection media such as aqueous solutions and sweat. Simultaneously, the three-dimensional
network structure constructed by the crosslinking reaction allows the composite functional layer to form a strong
chemical bond with the electrode substrate, effectively avoiding problems such as modification layer detachment and swelling. This application replaces traditional
electroplating processes, is suitable for integrated products such as wearable sweat patches, avoids problems such as
electrolyte corrosion of the substrate and short circuits, and is suitable for the modification needs of embedded, irregularly shaped, and array electrodes.