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Process of mechanical copper plating and mechanical copper alloy plating

A copper alloy and mechanical plating technology, applied in the electrolysis process, electrolysis components and other directions, can solve the problems of easy oxidation and unsuitability of metal copper, and achieve the effects of stable deposition speed, convenient operation and simple process flow

Active Publication Date: 2015-12-02
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The main layered material used in mechanical copper plating and copper alloy is copper powder or copper alloy powder. Compared with zinc and zinc alloy powder, metallic copper is easy to oxidize, and the standard electrode potential of metallic copper is much more positive than metallic zinc. The surface state of zinc powder and zinc powder in the acidic solution is also different, so the conventional mechanical galvanizing process is not suitable for mechanical copper and copper alloy plating from the perspective of mechanism.

Method used

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Examples

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Comparison scheme
Effect test

Embodiment 1

[0023] In the mechanical copper plating and copper alloy process described in this embodiment, the workpiece to be plated is a 100kg steel flat gasket with a thickness of Ф20 and a thickness of 3mm, the surface area to be plated is 9.5 square meters, and the thickness of the coating to be plated is 10 microns, which specifically includes the following steps:

[0024] (1) Pre-treatment: The steel gaskets are sequentially subjected to degreasing, rinsing, rust removal, and rinsing to obtain steel parts with clean surfaces; The rust product on the surface of the gasket is removed by the hydrochloric acid pickling method, and rinsed with running water;

[0025] (2) Put the steel gasket, medium (Ф2~3), water, into the plating cylinder of the general mechanical plating equipment, add 400ml phosphoric acid to the plating cylinder to adjust the pH value of the plating solution to 3, and then add 807.5g copper powder , then add 465ml of deposition accelerator aqueous solution to the pl...

Embodiment 2

[0030] In the mechanical copper plating and copper alloy process described in this embodiment, the workpiece to be plated is 100kg of steel flat gasket with a thickness of Ф16 and 2mm, the surface area to be plated is 14 square meters, and the thickness of the layer to be plated is 10 microns, which specifically includes the following steps:

[0031] (1) Pre-treatment: Steel flat gaskets are sequentially subjected to degreasing, rinsing, rust removal, and rinsing to obtain steel parts with clean surfaces; in this embodiment, the oxidation method is adopted to remove various types of grease dirt on the surface of steel flat gaskets , use hydrochloric acid pickling method to remove the rust products on the surface of the gasket, and use running water for rinsing;

[0032] (2) Put the steel parts, medium (Ф2~3), water, into the plating cylinder of the general mechanical plating equipment, add 450ml citric acid to adjust the pH value of the plating solution to 5, then add 1190g bra...

Embodiment 3

[0037] In the mechanical copper plating and copper alloy process described in this embodiment, the workpiece to be plated is 100kg of steel nails with a length of Ф2.5mm and a length of 50mm, the surface area to be plated is 22.5 square meters, and the thickness of the layer to be plated is 20 microns, which specifically includes the following steps:

[0038] (1) Pretreatment: The steel nails are sequentially subjected to degreasing, rinsing, rust removal, and rinsing to obtain steel nails with clean surfaces; in this embodiment, ultrasonic cleaning is used to remove various types of grease and dirt on the surface of the steel nails, and hydrochloric acid is used for pickling. The rust product on the surface of the gasket is removed by the method, and the running water is used for rinsing;

[0039](2) Put steel nails, medium (Ф0.5~1), water, into the plating cylinder of general mechanical plating equipment, add 600ml phosphoric acid to adjust the pH value of the plating solutio...

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Abstract

The invention discloses a process of mechanical copper plating and mechanical copper alloy plating and belongs to the technical field of surface plating of a steel product. The process of mechanical copper plating and mechanical copper alloy plating comprises the steps of adjusting the pH value of a plating solution by means of universal mechanical plating equipment, then adding copper powder or copper alloy powder and a sedimentation accelerating agent into the plating solution, and finally a cooper coating or a copper alloy coating is prepared on the surface of the steel product along with the rotation of a plating cylinder of the mechanical plating equipment. The sedimentation accelerating agent adopted by the process is composed of diatomite, sodium gluconate, triethanolamine, stannous salt, ammonium dihydrogen phosphate, polyethylene glycol, OP-10, inorganic acid and a defined amount of water. By adopting the process of mechanical copper plating and mechanical copper alloy plating, the copper powder or the copper alloy powder can subside on the surface of the steel product rapidly, the process is simple, the operation is convenient, and the dual-effect of corrosion prevention and decoration of the steel product can be achieved.

Description

technical field [0001] The invention relates to a mechanical copper plating and copper alloy process, which belongs to the technical field of surface plating of iron and steel materials, and is used for preparing copper and copper alloy plating layers on the surface of iron and steel parts. Background technique [0002] In recent years, with the continuous increase of environmental protection pressure, the traditional copper electroplating process has been closed, stopped, and reorganized. However, the demand for copper electroplating process in the fields of electronics, electrical appliances, and decorative-protective hardware has increased unabated. The development of copper plating provides a good opportunity. However, in the field of mechanical plating, there is no mature mechanical copper plating process for production practice. Literature search shows that there is little research on mechanical copper plating in the field of surface protection. Yu Ping used to add co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D17/16C25D3/38
Inventor 王胜民赵晓军李继锋谭蓉王玉光申国成
Owner KUNMING UNIV OF SCI & TECH
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