Copper foil with carrier, printed circuit board, copper clad laminated sheet, electronic device, and printed circuit board fabrication method
A technology with copper foil and carrier attached to the carrier, which is applied in the manufacture of printed circuits, electronic equipment, printed circuits, etc., can solve the problems of poor insulation and residue of circuit patterns, and achieve the effect of good laser opening
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Embodiment 1~9、11、12
[0244] Examples 1-9, 11, 12, Comparative Examples 1-5)
[0245]A titanium rotating cylinder was arranged in the electrolytic cell, and electrodes were arranged around the cylinder with an inter-electrode distance. Next, electrolysis was carried out in the electrolytic tank under the carrier foil production conditions described in Table 1, copper was deposited on the surface of the rotating drum, and the copper deposited on the surface of the rotating drum was peeled off to continuously produce an electrolytic copper foil with a thickness of 18 μm. It is set as a copper foil carrier. Furthermore, regarding Examples 1, 2, 6, 8, 9, and 12, the thicknesses of the surface-treated copper foil carriers were 12 μm, 5 μm, 70 μm, 12 μm, 35 μm, and 35 μm, respectively. Moreover, about the comparative example 3, it was set as the copper foil carrier of thickness 12 micrometers. About Examples 1, 2, 6, 8, 9, and 12, the conditions described in Table 1 were surface-treated to the copper f...
Embodiment 10
[0309] A rolled copper foil (refined copper, JISH3100C1100) was prepared, and the rolled copper foil was subjected to cold rolling for final processing using a rolling roll whose surface was roughened by sandblasting. At this time, the rolling roll roughness Ra=0.39-0.42 μm, and the oil film equivalent were 35,000. Thus, a copper foil carrier was obtained.
[0310] Next, copper foil with a carrier was produced by forming an intermediate layer and an ultra-thin copper layer on the surface (matte surface) of the electrodeposited copper foil in the same manner as in Example 1.
[0311] Each evaluation was implemented by the following method about the copper foil with a carrier of the Example and the comparative example obtained as mentioned above.
[0312]
[0313] The thickness of the ultra-thin copper layer of the produced copper foil with a carrier was observed using FIB-SIM (Focused Ion Beam-Scanning Ion Microscope, focused ion beam-scanning ion microscope) (magnification:...
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