A kind of antibacterial medical material and its preparation method and antibacterial medical device
A technology of polymer materials and antibacterial nanoparticles, applied in the field of medical devices, can solve the problems of limitation, unsatisfactory antibacterial effect, poor antibacterial durability of medical devices, etc., and achieve the effect of good antibacterial effect and good antibacterial durability.
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[0041] The invention provides a kind of preparation method of antibacterial medical material, comprises the following steps:
[0042] Under ultrasonic conditions, the medical polymer material is impregnated in the antibacterial nano particle solution to obtain the antibacterial medical material.
[0043] In the preparation method provided by the invention, firstly, the medical polymer material is immersed in the antibacterial nano particle solution under ultrasonic conditions. Wherein, the medical polymer material is preferably one or more of fibers, resins and rubbers. The antibacterial nanoparticle solution is prepared by mixing the antibacterial nanoparticles and a solvent, and the antibacterial nanoparticles are preferably one of silver nanoparticles, zinc oxide nanoparticles, copper oxide nanoparticles, titanium dioxide nanoparticles and magnesium oxide nanoparticles. one or more species. The particle size of the antibacterial nanoparticles is preferably 50-200 nm, more...
Embodiment 1
[0066] (1) Soak medical gauze (Xianning Lifa Degreasing Gauze Products Factory) in 0.5wt% benzophenone ethanol solution, soak for 5 minutes, take it out, and air-dry naturally to obtain medical gauze coated with benzophenone. The medical gauze that the surface is coated with benzophenone is immersed in 8wt% polyethylene glycol acrylate (the number average molecular weight is 350) aqueous solution, under UV (365nm) photoinitiation, grafting reaction occurs on the surface of medical gauze, grafting 6min Finally, take it out, wash it with water, wash it with alcohol, and dry it successively to obtain a medical gauze modified by surface grafting.
[0067] (2) preparation of antibacterial silver nanoparticles (particle diameter is 80nm) ethanol solution, the concentration of antibacterial silver nanoparticles in the solution is 1mg / mL, the ultrasonic probe is placed in the antibacterial silver nanoparticles solution, ultrasonic (power is 288W) 1h in advance, The nanoparticles are d...
Embodiment 2
[0070] (1) Immerse the surgical gown (Shenzhen Duoai Textile Technology Co., Ltd.) in 0.5wt% benzophenone ethanol solution for 5 minutes, take it out, and dry it naturally to obtain a surgical gown coated with benzophenone. Immerse the surgical gown coated with benzophenone in a 6wt% hydroxyethyl acrylate aqueous solution, and under UV (365nm) photoinitiation, a grafting reaction occurs on the surface of the surgical gown. After 6 minutes of grafting, take it out, and then wash it with water and alcohol. After washing and drying, a surgical gown modified by surface grafting is obtained.
[0071] (2) preparation of antibacterial zinc oxide nanoparticles (particle diameter is 120nm) ethanol solution, the concentration of antibacterial zinc oxide nanoparticles in the solution is 1mg / mL, the ultrasonic probe is placed in the antibacterial zinc oxide nanoparticle solution, ultrasonic in advance (ultrasonic power is 300W) for 1h, so that the nanoparticles are dispersed in the soluti...
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