Supercharge Your Innovation With Domain-Expert AI Agents!

Dimethylglyoxime magnesium and preparation method thereof

A technology of dimethylglyoxime and magnesium salt, applied in oxime preparation, organic chemistry, etc., can solve the problems of easy damage to turbofan, low melting point, failure, etc., and achieve the effect of improving catalytic effect and simple synthesis process

Inactive Publication Date: 2015-12-16
XIAN MODERN CHEM RES INST
View PDF4 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are some problems in the combustion catalysts commonly used in double-base gas generating agents, such as Al 2 o 3 The melting point is low, and it is easy to condense with other catalysts to form large particles during combustion, which will stick to the gas pipe or turbofan and cause failure; the compound containing Zr and Bi is too hard, and it is easy to damage the turbofan
The double base propellant containing magnesium oxide not only has the advantages of low combustion flame temperature, low solid particle content in the gas, no corrosive products such as chlorine or chlorine compounds, but also is insensitive to temperature and impact, and can be used in a wide temperature range It has good mechanical properties, and the addition of MgO can also inhibit the combustion of acoustic vibration instability, but the magnesium oxide used as a catalyst is unstable and easy to absorb moisture, and its performance is prone to change and failure during storage, which seriously limits the Propellant-like service life
In addition, the propellant formula contains water-soluble substances, which is not conducive to the preparation of solvent-free stretching process

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Dimethylglyoxime magnesium and preparation method thereof
  • Dimethylglyoxime magnesium and preparation method thereof
  • Dimethylglyoxime magnesium and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] Example 1 Preparation of Dimethylglyoxime Magnesium Compound

[0019] (1) Weigh 34.75g (0.3mol) of dimethylglyoxime, disperse it in 250mL deionized water, adjust the pH value of the solution to 9 with sodium hydroxide solution; weigh 76.8g (0.3mol) magnesium nitrate trihydrate Dissolve with 100mL deionized water to make a solution, add it to the above solution, stir and mix evenly;

[0020] (2) Stir and react for 2 hours at a constant temperature of 70°C, then cool and stand still;

[0021] (3) The precipitate was washed several times with deionized water, filtered, and dried to obtain 47.2 g of a white dimethylglyoxime magnesium compound with a yield of 90.4%.

[0022] Characterization of Dimethylglyoxime Magnesium Compound

[0023] 1. Infrared spectrum (KBr, cm -1 )υ: 3208, 2930, 1939, 1636, 1445, 1384, 1364, 1141, 981, 906.

[0024] 2. Analysis of organic elements

[0025] Molecular formula: C 4 h 6 N 2 o 2 Mg 2H 2 o

[0026] Theoretical value (%): C27.5...

Embodiment 2

[0032] Example 2 Preparation of Dimethylglyoxime Magnesium Compound

[0033] (1) Weigh 1.38g (0.012mol) of dimethylglyoxime, disperse it in 10mL of deionized water, adjust the pH of the solution to 9 with sodium hydroxide solution; weigh 3.07g (0.012mol) of magnesium nitrate trihydrate Dissolve with 10mL deionized water to form a solution, add it to the above solution, stir and mix evenly;

[0034] (2) Stir and react for 2 hours at a constant temperature of 70°C, then cool and stand still;

[0035] (3) The precipitate was washed several times with deionized water, filtered and dried to obtain 1.69 g of white dimethylglyoxime magnesium compound with a yield of 80.9%.

[0036] Analysis of the Solid Phase Decomposition Products of Dimethylglyoxime Magnesium Compound

[0037] Dimethylglyoxime magnesium dihydrate was calcined in a crucible at 500°C for 1 hour to obtain a white powder. X-ray diffraction showed that (as figure 1 shown), the five diffraction peaks 36.74, 42.82, ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a dimethylglyoxime magnesium compound with a structural formula represented in a formula (I). The dimethylglyoxime magnesium compound can be decomposed to produce uniformly distributed nascent magnesium oxide as a main catalytic active component when used as a combustion catalyst and can produce a carbon substance as an assisted catalytic component simultaneously, thereby having excellent catalytic effect on combustion of a slow-combustion solid propellant with a low combustion temperature and capable of greatly reducing combustion speed and pressure intensity indexes under the condition that the combustion speed of the propellant is not increased.

Description

technical field [0001] The invention relates to a magnesium dimethylglyoxime compound, which can be used as a combustion catalyst for solid propellants. technical background [0002] With the development of cutting-edge technology, the increase of the flight distance of missiles and rockets and the improvement of control precision, higher requirements are put forward for solid gas generators, which require light weight and longer working hours. This requires that the gas generator not only produces The gas volume is large, the gas cleanliness is high, and the burning rate and burning temperature are lower, but the performance of the propellant is related. Large, incomplete combustion and increased residue. [0003] In terms of double-based propellants with low combustion temperature and low burning rate, the decomposition rate is usually delayed by adding a catalyst with a higher melting point, adding a decomposition and endothermic catalyst to reduce the combustion tempera...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C07C249/12C07C251/70
Inventor 赵凤起安亭李辉仪建华姚二岗陈俊波曹鹏李猛
Owner XIAN MODERN CHEM RES INST
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More