Lead plaster additive for lead-acid storage battery, and preparation method and application therefor
A lead-acid battery and additive technology, applied in the direction of lead-acid batteries, etc., can solve the problems of reduced battery life, poor high-current performance, battery self-discharge, etc., achieve strong operability, simple process steps, and improve battery charging acceptance The effect of capacity and service life
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Embodiment 1
[0022] A lead paste additive for lead-acid batteries, which is composed of the following components in mass percentage: 2% pretreated single-wall carbon nanotubes, 1% dispersant, the balance is deionized water, and the dispersant is polyacrylic acid.
[0023] This lead-acid storage battery lead paste additive is obtained by the following method:
[0024] (1) Preparation of pretreated single-walled carbon nanotubes: immerse the single-walled carbon nanotubes in 95% sulfuric acid, ultrasonically treat them at 40°C for 5 hours, filter them with deionized water, ammonium hydroxide solution, deionized Washing with ion water until the pH is neutral to obtain pretreated single-walled carbon nanotubes, which are ready for use.
[0025] (2) Mixing: After weighing each component according to the above mass percentage ratio, add the dispersant to deionized water and stir evenly, then add pretreated single-walled carbon nanotubes, and ultrasonically disperse to obtain lead-acid battery le...
Embodiment 2
[0030] A lead-acid battery lead paste additive, which is composed of the following components in mass percentage: 0.5% pretreated multi-walled carbon nanotubes, 0.5% dispersant, the balance is deionized water, and the dispersant is polyethylene pyrrolidone.
[0031] This lead-acid storage battery lead paste additive is obtained by the following method:
[0032] (1) Preparation of pretreated multi-walled carbon nanotubes: immerse the multi-walled carbon nanotubes in 95% sulfuric acid, ultrasonically treat them at 90°C for 1 h, filter them with deionized water, sodium hydroxide, deionized Washing with water until the pH is neutral to obtain pretreated multi-walled carbon nanotubes, which are ready for use.
[0033] (2) Mixing: After weighing each component according to the above mass percentage ratio, add the dispersant to deionized water and stir evenly, then add pretreated multi-walled carbon nanotubes, and ultrasonically disperse to obtain lead-acid battery lead paste addit...
Embodiment 3
[0035] A lead-acid storage battery lead paste additive, which is made up of the following components in mass percentage: 5% pretreated carbon nanofibers with a fiber diameter less than 100nm, 6% dispersant, and the balance is deionized water, and the dispersant is Sodium dodecyl sulfate.
[0036] This lead-acid storage battery lead paste additive is obtained by the following method:
[0037] (1) Preparation of pretreated carbon nanofibers with a fiber diameter of less than 100nm: immerse carbon nanofibers with a fiber diameter of less than 100nm in 70% nitric acid, ultrasonically treat them for 72 hours at 20°C, filter them with deionized water, Washing with sodium hydroxide solution and deionized water until the pH is neutral, and the pretreated carbon nanofibers with a fiber diameter of less than 100 nm are obtained, ready for use.
[0038] (2) Mixing: After weighing each component according to the above mass percentage ratio, add the dispersant to deionized water and stir ...
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