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Preparation method for composite group CEM-3 copper-clad laminate (CCL) with high comparative tracking index (CTI) and high thermal conductivity

A technology with high thermal conductivity and composite matrix, which is applied in chemical instruments and methods, paper/cardboard layered products, electronic equipment, etc., can solve the problems of low CTI, poor heat resistance and heat dissipation, and poor machinability of aluminum substrates. The effect of prolonging service life, improving thermal conductivity and reducing dosage

Active Publication Date: 2015-12-23
SHANDONG JINBAO ELECTRONICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, there are two types of thermally conductive copper clad laminates: aluminum substrate and composite base copper clad laminate. Made of heat-dissipating materials, with many fillers, poor heat resistance and heat dissipation, and low CTI

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A kind of preparation method of high CTI, high thermal conductivity composite matrix CEM-3 copper-clad laminate, the steps are as follows:

[0021] (1) Preparation of resin emulsion for glass cloth: 45 parts of bromine-free epoxy resin (epoxy equivalent of 400g / eq), 1 part of dicyandiamide, 25 parts of aluminum hydroxide, 8 parts of inorganic filler and 21 parts of dimethyl Formamide was added to the reaction kettle in turn, stirred at 20°C for 8 hours, then emulsified with a high-speed emulsifier for 1.5 hours, and finally placed in the reaction kettle for 12 hours of aging;

[0022] (2) Preparation of resin emulsion for cellophane: 45 parts of low-bromine epoxy resin (epoxy equivalent is 400g / eq), 0.5 parts of dicyandiamide, 20 parts of alumina, 15 parts of inorganic filler, 4.5 parts of silicon carbide and 15 parts Dimethylformamide was added to the reactor in turn, stirred at 20°C for 8 hours, then emulsified with a high-speed emulsifier for 1.5 hours, and finally p...

Embodiment 2

[0027] A kind of preparation method of high CTI, high thermal conductivity composite matrix CEM-3 copper-clad laminate, the steps are as follows:

[0028] (1) Preparation of resin emulsion for glass cloth: 55 parts of bromine-free epoxy resin (epoxy equivalent of 450g / eq), 2 parts of dicyandiamide, 22 parts of aluminum hydroxide, 5 parts of inorganic filler and 16 parts of dimethyl Formamide was added to the reaction kettle in turn, stirred at 40°C for 5 hours, then emulsified with a high-speed emulsifier for 2.5 hours, and finally placed in the reaction kettle for 16 hours of aging;

[0029] (2) Preparation of resin emulsion for glass mat: 50 parts of low bromine epoxy resin (epoxy equivalent is 450g / eq), 1 part of dicyandiamide, 14 parts of alumina, 10 parts of inorganic filler, 8 parts of silicon carbide and 17 parts Parts of dimethylformamide were added to the reactor one by one, stirred at 40°C for 5 hours, then emulsified by a high-speed emulsifier for 2.5 hours, and fin...

Embodiment 3

[0034] A kind of preparation method of high CTI, high thermal conductivity composite matrix CEM-3 copper-clad laminate, the steps are as follows:

[0035] (1) Preparation of resin emulsion for glass cloth: mix 65 parts of bromine-free epoxy resin (epoxy equivalent of 400g / eq), 1 part of dicyandiamide, 20 parts of aluminum hydroxide, 4 parts of inorganic filler and 10 parts of dimethyl Formamide was added to the reaction kettle in turn, stirred at 30°C for 6 hours, then emulsified by a high-speed emulsifier for 2.0 hours, and finally placed in the reaction kettle for 14 hours of aging;

[0036] (2) Preparation of resin emulsion for cellophane: 55 parts of low-bromine epoxy resin (epoxy equivalent is 450g / eq), 0.5 parts of dicyandiamide, 8 parts of alumina, 5 parts of inorganic fillers, 10 parts of silicon carbide and 21.5 parts Dimethylformamide was added to the reactor in turn, stirred at 30°C for 6 hours, then emulsified with a high-speed emulsifier for 2.0 hours, and finally...

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PUM

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Abstract

The invention belongs to the technical field of copper-clad laminate (CCL) production, and relates to a preparation method for a composite group CEM-3 CCL with a high comparative tracking index (CTI) and high thermal conductivity. The method can improve the CTI of the CEM-3 CCL through a non-brominated epoxy resin system, and is matched with graphene surface modified aluminum nitride, graphene surface modified boron nitride, silicon carbide and the like through low bromine epoxy resin to improve the thermal conductivity of the CEM-3 CCL. Inorganic fillers with different kinds and different types are compounded, so that the filler consumption is reduced; the prepared CCL can satisfy a normal operation in environments such as high heat, high pollution, high voltage, high current, high heat and the like, and the service life of the prepared CCL is prolonged.

Description

technical field [0001] The invention relates to a copper clad laminate, in particular to a method for preparing a high CTI and high thermal conductivity composite matrix CEM-3 copper clad laminate, belonging to the technical field of copper clad laminate production. Background technique [0002] Copper clad laminate is an important material in the printed circuit board industry. With the development of electrical appliances, in order to improve the use of copper clad laminate in high humidity, high pollution, high voltage, high current, high heat and other environments, improve the heat dissipation capacity of heating electronic components It is of great significance to prolong its service life and improve the CTI and thermal conductivity of composite-based copper clad laminates. [0003] At present, copper clad laminates mainly play an important role in LED lighting, automotive electronics, frequency converters, power supplies, etc. In the development process of LED, the p...

Claims

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Application Information

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IPC IPC(8): B32B15/14B32B29/02B32B37/06
CPCB32B15/14B32B29/02B32B37/06B32B2250/05B32B2255/02B32B2255/26B32B2457/08
Inventor 陈晓鹏陈长浩李宝东王天堂林洪会秦雪芹王卫兴姜晓亮朱义刚
Owner SHANDONG JINBAO ELECTRONICS