Device for photocatalytic removal of volatile organic and inorganic contamination as well as microorganisms especially from automobile air conditioning systems
An air-conditioning system, photocatalytic technology, applied in irradiation, disinfection, etc., can solve the problem of reducing dust oxidation efficiency
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example I
[0045] Obtain a photocatalytic layer.
[0046] 350cm in cyclohexane 3 The 0,2MAOT (sodium diethylsuccinate) was added at a molar ratio of 0.5:0.1 with 1.44cm 3 An aqueous solution of silver nitrate and potassium chloroplatinate (IV). The whole mixture was mixed for 30 minutes under an inert gas atmosphere and then a precursor of titanium dioxide tetraisopropyl titanate (TIP) was introduced. The internal phase microemulsion containing metal ions was added with 150cm 3 A microemulsion prepared as a 0,2 MAOT (sodium diethylsuccinate) solution in cyclohexane containing dispersed phase sodium borohydride as reducing agent. A 3-fold excess of reducing agent was applied relative to the molar amount of metal. The obtained Pt / Ag nanocomposites were spaced apart, rinsed with acetone and water, dehydrated at a temperature of 80°C and calcined at a temperature of 350°C for 3 hours. The structure obtained is of the bimetallic alloy type provided on the surface of titanium dioxide.
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example II
[0050] Obtain a photocatalytic layer.
[0051] Based on TiO 2 The photocatalytic layer 4 is modified by platinum. relative to TiO 2 The mass platinum content is 0.1% by weight. The photocatalyst was obtained due to the addition of an aqueous solution of potassium(IV) chloroplatinate to isopropanol. Next, the material is added with a precursor of titanium dioxide tetraisopropyl titanate (TIP). The obtained sol was dehydrated at a temperature of 80°C and calcined at a temperature of 450°C for 3 hours. Next, the photocatalyst is cured using a method of immersion on the surface of the ceramic material and placed in the device as a plate-shaped member 1 . LEDs, ie LEDs emitting UV and Vis (intensity: 8mW / cm 2 ) is used as the light source 7. Such as Figure 9 As shown in , the spacer element 3 is arranged directly through the carrier element 2 and terminates on both sides with the plate element 1 . Light sources 7 are placed on both sides of the carrier element 2 .
[005...
example III
[0055] Obtain a photocatalytic layer.
[0056] 500cm in cyclohexane 3 0,2MAOT added with 0,5cm 3 Potassium chloroplatinate (IV) and hydrogen tetrachloroaurate (III) in water. The whole mixture was mixed under an inert gas atmosphere and then added with a second microemulsion containing the reducing agent-sodium borohydride dispersed in the aqueous phase of the water-AOT-cyclohexane microemulsion. A 3-fold excess of reducing agent was applied relative to the molar amount of metal. TiO 2 The nanocomposites were spaced apart, dehydrated at a temperature of 80°C and calcined at a temperature of 450°C. relative to TiO 2 The molar metal content is 0.1 mole % Pt and 0.5 mole % Au.
[0057] TiO modified by Au and Pt 2 The composed photocatalytic layer 4 was applied in suspension with a brush on the surface of a glass mat impregnated earlier by tetraethylorthosilicate (TEOS), and as Figure 11 is shown placed on a gasket 3 (shaped as part of the side wall of a concertina-folded...
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