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A kind of glass cleaner composition adding cationic polymer

A cationic polymer, composition technology, applied in detergent compositions, nonionic surface active compounds, surface active detergent compositions, etc. Translucency and other issues, to achieve the effect of long-lasting detergent product demand, good water droplet spreading performance, time-saving and labor-saving cleaning effect

Active Publication Date: 2018-10-23
广州超威生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the hydrophilic modification effect of the cationic polysaccharide polymer on the glass surface is not ideal, and the washing resistance effect is limited
Chinese patent CN 101821371 discloses a hard surface cleaning composition adding nonionic surfactants, acids and hydrophilic polymers. Although the composition has achieved a good hydrophilic modification effect on the surface of ceramic tiles, the described Hard surface cleaning compositions are free of anionic and amphoteric surfactants
In addition, the pH value of the composition is below 3. Although this has good detergency for soap scum and scale, it will weaken the removal power for grease dirt under low pH value conditions, which may affect the transparency of the glass. At the same time, it may irritate the eyes and skin of consumers and affect the safety of consumers during use.
[0006] In summary, it can be seen that hydrophilic polymers do help to improve the washing effect of glass cleaning products and give the glass surface a good hydrophilic effect, but the maintenance time and washing resistance of this hydrophilic effect still cannot meet the current requirements. consumer needs

Method used

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  • A kind of glass cleaner composition adding cationic polymer
  • A kind of glass cleaner composition adding cationic polymer
  • A kind of glass cleaner composition adding cationic polymer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-6

[0121] The formula components and contents of the cationic polymer-added glass cleaner compositions 1-6 of the present invention are shown in Table 1 below. Table 1 below tested the effect on the hydrophilic modification of cationic polymer-added glass cleaner compositions 1-6 of the present invention by changing the pH value of the solution.

[0122] The influence of table 1 composition pH value on cationic polymer hydrophilic modification

[0123]

[0124] The preparation method of the glass cleaner composition 1-6 of the present invention adding cationic polymer is:

[0125] 1) Add the cationic polymer Noverite 311 (or Noverite 301) into water and stir to dissolve;

[0126] 2) Add NaOH aqueous solution to adjust the pH value of the solution, and add water to keep the weight constant.

[0127] Can be found by the test result of table 1, by soaking in the glass sheet of solution (composition 1 and composition 4) under acidic condition, after three times of rinsing, its c...

Embodiment 7-11

[0129] In glass cleaner compositions 7-11 of the present invention, the surfactant system includes one or more mixtures of anionic surfactants, zwitterionic surfactants, cationic surfactants, and nonionic surfactants. This is because the cationic polymer provided by the invention can be well compatible with various surfactants, and is also suitable under neutral and alkaline conditions.

[0130] Table 2 The formulation components and content of glass cleaner compositions 7-11 of the present invention

[0131]

Composition 7

Composition 8

Composition 9

Composition 10

Composition 11

components

content(%)

content(%)

content(%)

content(%)

content(%)

XP 80

0.3

-

-

0.3

AES270

-

0.43

-

0.43

BS-12

-

-

0.86

0.86

1227

-

-

-

0.76

Noverite 311

0.68

0.68

0.68

0.68

Ethylene glycol

0.5

0.5

0.5

0.5

0.5

...

Embodiment 12-15

[0143] Table 5 Formula components and contents of glass cleaner compositions 12-15 of the present invention

[0144]

[0145]

[0146] The preparation method of the glass cleaner composition 12-15 of the present invention adding cationic polymer is:

[0147] 1) Add cationic polymer Noverite 311 (or Noverite 301) and ammonia water (or NaOH solution) into water respectively, and stir to dissolve;

[0148] 2) Add short carbon chain fatty alcohol and surfactant respectively, stir and mix;

[0149] 3) Add detergent additives, adjust the pH value of the solution, and add water to keep the weight constant.

[0150] The data in Table 5 fully prove that the glass cleaner composition containing the cationic polymer can make the surface of the glass sheet have better hydrophilicity, and the hydrophilicity has better washing resistance.

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Abstract

The invention relates to a glass cleaner composition added with cationic polymers. The glass cleaner composition comprises the following materials: (a) cationic polymers which account for 0.01-3.0 percent of the total weight of the composition, have the general formula shown in the description and have the number-average molecular weight of 40,000-1,000,000, wherein R1 and R3 are one or more of ingredients shown in the description, and R2 is one or more of diallyl-dialkyl-ammonium chloride and N-(quaternary ammonium alkyl)acrylamide; (b) short-carbon-chain fatty alcohol which accounts for 4-40 percent of the total weight of the composition and has 1-4 carbon atoms; (c) a surfactant system which accounts for 0.1-5 percent of the total weight of the composition and at least comprises an ampholytic surfactant or an anionic surfactant; (d) at least one alkali of which the amount is enough to enable the pH value of the composition to range from 5 to 11; (e) one or more washing assistants; (f) the balance of water. The glass cleaner composition added with the cationic polymers can effectively improve the surface hydrophilicity of glass and has relatively good washability.

Description

technical field [0001] The invention relates to a glass cleaner composition, in particular to a liquid detergent composition for cleaning the surfaces of glass doors and windows, automobile glass and other glass products. Background technique [0002] Because of its smooth, transparent, crystal clear, good light transmittance and cost performance, glass is a widely used building material and decorative material. However, glass is easily contaminated by dust, oil stains and other dirt during use, and after the glass is contaminated, it will seriously affect the line of sight and the appearance of finishing. At present, the glass cleaners on the market are usually composed of surfactants, alcohol ether organic additives, chelating agents and other components, which are easily washed away by rainwater and sewage, so they only have a single decontamination ability and do not have a long-term effect. The ability to maintain the cleaning effect and the wash-resistant effect, so t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C11D1/29C11D1/90C11D1/68C11D1/94C11D1/40C11D1/72C11D1/831C11D1/835C11D3/37C11D3/20C11D3/04C11D3/30C11D3/60
CPCC11D1/29C11D1/40C11D1/66C11D1/72C11D1/831C11D1/835C11D1/90C11D1/94C11D3/04C11D3/044C11D3/2006C11D3/2041C11D3/30C11D3/3769
Inventor 石磊张利萍李东华黄亮
Owner 广州超威生物科技有限公司
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