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Propylene polymer and preparation method thereof

A technology for propylene polymer and olefin polymerization, which is applied in the field of propylene polymer and its preparation, can solve the problems of products needing to be free of random substances, low polypropylene regularity, affecting downstream production processes, etc.

Active Publication Date: 2016-03-30
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

High ash content in polypropylene may cause the following defects: (1) easy fouling or even blockage in processing equipment, such as extrusion lines for film making and boards, production lines for fibers or non-woven fabrics; (2) affect the quality of products Strength, electrical properties, etc.: For example, fiber-grade polypropylene resin (PP resin) usually requires the mass fraction of ash to be below 0.0100%, and the ash mass fraction of PP resin for capacitors is usually required to be less than 0.0050%, preferably below 0.0030%; (3 ) affect the downstream production process
However, the effect of compounding is not a simple superposition of the properties of several electron donors.
For example, the isotacticity of polypropylene generally obtained from catalysts using monocarboxylic acid esters as internal electron donors is low, and the product needs to remove random substances.
And WO03002617 discloses a catalyst component and a catalyst for olefin polymerization obtained by using a monocarboxylic acid ester and a dicarboxylic acid ester in combination. The hydrogen adjustment sensitivity of the catalyst is good, but the stereospecificity and polymerization activity are still not very high

Method used

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  • Propylene polymer and preparation method thereof
  • Propylene polymer and preparation method thereof
  • Propylene polymer and preparation method thereof

Examples

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preparation example Construction

[0029]The invention provides a method for preparing a propylene polymer, the method comprising: under olefin polymerization conditions, in the presence of a catalyst, propylene or propylene and ethylene and / or selected from C 4 -C 8 A mixture of α-olefins is polymerized, the catalyst contains a solid component, an alkylaluminum compound and optionally an external electron donor compound, the solid component comprising the reaction product of the following components:

[0030] (i) magnesium-containing compounds;

[0031] (ii) titanium-containing compounds; and

[0032] (iii) internal electron donors;

[0033] Wherein, the internal electron donor is a combination of internal electron donor compound a, internal electron donor compound b and internal electron donor compound c.

[0034] According to the present invention, the internal electron donor compound a is a glycol ester compound represented by formula I,

[0035]

[0036] In formula Ⅰ, R 1 and R 2 the same or diffe...

Embodiment 1

[0114] This example is used to illustrate the propylene polymer provided by the present invention and its preparation method.

[0115] Preparation of the catalyst solid component: In a 300mL stirred glass reaction flask fully replaced by high-purity nitrogen, add 0.912mol of titanium tetrachloride and 10mL of hexane, cool to -20°C, add 8g (0.0372mol) Spherical magnesium chloride alcoholate (MgCl 2 2.6C 2 h 5 OH, synthesized with magnesium dichloride and ethanol according to the method disclosed in CN1330086A), under stirring, slowly heat up in stages, add 2,4-pentanediol dibenzoate (internal electron donor compound a) 5mmol , 2-isopropyl-2-isoamyl-1,3-dimethoxypropane (internal electron donor compound b) 5mmol and epichlorohydrin (internal electron donor compound c) 1.5mmol, continue to heat up to 110°C, after reaching the temperature and keeping the temperature for 0.5h, remove the liquid by suction filtration, and add titanium tetrachloride to the solid phase obtained by ...

Embodiment 2

[0119] This example is used to illustrate the propylene polymer provided by the present invention and its preparation method.

[0120] Preparation of catalyst solid component: prepare olefin polymerization catalyst solid component according to the method of Example 1, and prepare polypropylene according to the method of Example 1, the difference is that in the process of propylene polymerization, cyclohexylmethyl dimethyl Oxysilane. The isotactic index and ash content of the obtained polypropylene and the test results of the polymerization activity of the catalyst are shown in Table 1.

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Abstract

The present invention discloses a propylene polymer and a preparation method thereof. The method is as follows: under olefin polymerization conditions, in the presence of a catalyst, propylene or a mixture of propylene and ethylene and / or an alpha-olefin selected from C4-C8 are polymerized, the catalyst comprises a solid component, an alkyl aluminum compound and an optional external electron donor compound, the solid component comprises the following reaction product components: (i) a magnesium-containing compound; (ii) a titanium-containing compound; and (iii) an internal electron donor; wherein the internal electron donor is a combination of an internal electron donor compound a, an internal electron donor compound b and an internal electron donor compound c, the internal electron donor compound a is a diol ester compound of formula I, the internal electron donor compound b is a diether compound of formula II, and the internal electron donor compound c is an alkylene oxide compound of formula III. The propylene polymer prepared by the preparation method has high isotactic index and low ash content.

Description

technical field [0001] The invention relates to a propylene polymer and a preparation method thereof. Background technique [0002] It is well known that solid titanium-based catalyst components based on magnesium, titanium, halogen and electron donor compounds are used for olefin polymerization, especially for propylene polymerization, with high polymerization activity and stereospecificity. Among them, the electron donor compound is one of the essential components in the catalyst components, which plays a decisive role in important indicators such as polymerization activity, polymer isotactic index, molecular weight and molecular weight distribution. With the development of internal electron donor compounds, polyolefin catalysts are constantly updated. [0003] Catalysts with different internal electron donors have different characteristics, for example, some catalysts have higher polymerization activity, some catalysts have better hydrogen sensitivity, and some catalysts...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F10/06C08F4/654C08F4/651
Inventor 赵瑾夏先知刘月祥高平谭扬李威莅凌永泰高富堂张纪贵彭人琪
Owner CHINA PETROLEUM & CHEM CORP
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