The invention relates to a preparation method of a Ziegler-
Natta catalyst for efficiently preparing low entanglement
polyethylene and an application. The preparation method comprises the following steps that a prepared
alcohol absorbing porous carrier and a prepared polyhedral oligomeric
silsesquioxane molecule / Mg mixture are stirred in
tetrahydrofuran and filtered,
solid powder is dried until the
solid powder flows freely, and a carrier used for preparing the low entanglement
polyethylene catalyst is obtained; then, a carrier of an
aluminium alkyl modified catalyst is prepared through the
aluminium alkyl; and finally, a TiC14
tetrahydrofuran solution is added into the carrier of the
aluminium alkyl modified catalyst, after stirring, the
solid powder is washed by means of the
tetrahydrofuran solution and dried until the solid powder flows freely, and the Ziegler-
Natta catalyst for efficiently preparing the low entanglement
polyethylene is obtained. POSS can be assembled into a
microsphere with particle
diameter being 20-100 nm in a pore passage of the porous carrier. The active points are divided effectively. The intervals between active centers are increased. The occurrence of chain overlapping in the
polymerization process is restrained. The low entanglement polyethylene Ziegler-
Natta can be prepared efficiently with the polymerizing temperature being higher than or equal to 60 DEG C.