Heavy oil contact cracking method

A contact cracking, heavy oil technology, applied in cracking, non-catalytic thermal cracking, petroleum industry and other directions, can solve the problems of increased coke yield, difficult to control the temperature in the bed, flying temperature, etc., achieve uniform radial distribution, improve oil Agent contact effect, stable operation effect

Active Publication Date: 2016-04-20
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the fixed bed has the following disadvantages: the heat transfer efficiency of the fixed bed is low, the heat of reaction cannot be fully removed (or replenished), the temperature distribution in the catalyst layer is uneven, and the temperature in the bed is not easy to control for the forced exothermic heat-limited reaction, which is easy to cause overheating Wait
If the feed is all low-quality heavy oil, it is easy to cause the catalyst to block the pores of the particles due to heavy oil covering the surface of the particles, affecting the activity of the molecular sieve, resulting in rapid deactivation of the catalyst, resulting in an increase in the coke yield, and affecting the stable operation of the device.
It can be seen that the catalytic cracking process is no longer suitable for the cracking of inferior heavy oil, so the researchers developed heavy oil contact cracking, the contact agent used has a certain activity, but the traditional riser device is not suitable for the processing requirements of inferior heavy oil, Need to develop a new reactor structure to adapt to it

Method used

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Effect test

Embodiment 1

[0059] use figure 1 In the cracking reactor shown, the total height of the pre-lift section A, the oil agent contact reaction zone B, and the outlet zone C of the cracking reactor is 12m, the diameter of the lower part of the pre-lift section A is 0.15m, and the height is 0.5m. The height of the middle part 4 of A is 0.5m, the diameter of the upper part of the pre-lifting section A is 0.5m, and the height is 2m, the height of the oil contact reaction zone B is 5m, and the diameter is 0.5m, and the height of the exit zone C is 4m, and the diameter is 0.1m. The middle and upper part of the pre-lifting section A is provided with a casing 5, the casing 5 is thin in the middle, and the diameter of both ends is enlarged, and the height ratio of the three parts of the casing 5 from top to bottom is 1:3:0.2, and the middle The diameter ratio of the section to the upper part of the pre-lift section A is 0.4:1, the acute angle at the top of the longitudinal section of the casing 5 is 40...

Embodiment 2

[0063] use figure 1 In the cracking reactor shown, the total height of the pre-lift section A, the oil agent contact reaction zone B, and the outlet zone C of the cracking reactor is 30m, the diameter of the lower part of the pre-lift section A is 0.3m, and the height is 1m, and the pre-lift section A The height of the middle part 4 is 1.2m, the upper part of the pre-lifting section A has a diameter of 1m and a height of 4m, the height of the oil agent contact reaction zone B is 10m, and the diameter is 1m, and the height of the exit zone C is 13.8m, and the diameter is 0.5m. The middle and upper part of the section A is provided with a casing 5, the casing 5 is thin in the middle, and has a shape of enlarged diameter at both ends, and the height ratio of the three parts of the casing 5 from top to bottom is 1:2:1, and the middle section and The diameter ratio of the upper part of the pre-lift section A is 0.8:1, the top acute angle of the longitudinal section of the casing 5 ...

Embodiment 3

[0066] use figure 1 In the cracking reactor shown, the total height of the pre-lift section A, the oil agent contact reaction zone B, and the outlet zone C of the cracking reactor is 10m, the diameter of the lower part of the pre-lift section A is 0.1m, and the height is 0.4m, and the pre-lift section A middle part 4 has a height of 0.5m, the upper part of the pre-lift section A has a diameter of 0.4m and a height of 1.1m, the oil agent contact reaction zone B has a height of 4m and a diameter of 0.4m, and the outlet zone C has a height of 4m and a diameter of 0.1m , the middle and upper part of the pre-lifting section A is provided with a casing 5, the casing 5 is thin in the middle, and has a shape of enlarged diameter at both ends, and the height ratio of the three parts of the casing 5 from top to bottom is 1:3:1, The diameter ratio of the middle section to the upper part of the pre-lift section A is 0.2:1, the acute angle of the top of the longitudinal section of the casi...

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Abstract

A heavy oil contact cracking method is performed in a cracking reactor. The cracking reactor comprises a pre-lifting section, an oil agent contact reaction area, and an outlet area from bottom to top. The diameter of the outlet area is smaller than the diameter of the oil agent contact reaction area. A sleeve pipe is arranged in the pre-lifting section, the diameter of the center of the sleeve pipe is the smallest, and the diameter of the sleeve pipe increases from the center to two ends. The method comprises the following steps: adding a contact agent into the pre-lifting section, making the contact agent enter the oil agent contact reaction area through the pre-lifting section, making heavy oil and the contact agent carry out contact cracking reactions in the oil agent contact reaction area; and discharging the products obtained in contact reactions out of the cracking reactor from the outlet area. The provided method can carry out a cracking treatment on heavy oil, and has the advantages that the coking on the wall of the reactor is reduced, the generation of coke is reduced, and the yield of light oil products is increased.

Description

technical field [0001] The invention relates to a heavy oil contact cracking method. Background technique [0002] With the development of the world economy, the demand for light and clean fuel oil is also growing rapidly, and the degree of heavy and inferior crude oil worldwide is intensified, mainly manifested in high density, high viscosity, high carbon residue, and high heavy metal content , sulfur, nitrogen content, etc., and the increasingly stringent environmental protection requirements have brought many new problems to the oil refining industry. [0003] At present, the processing mechanism of heavy oil is mainly divided into two types: decarburization and hydrogenation. Hydrogenation mainly includes hydrofining, hydrocracking and so on. The hydrogenation process of oil refining is of great significance to increase the depth of crude oil processing, improve product quality, and increase the yield of light oil. However, the operating temperature and pressure of the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G9/42
Inventor 李延军王子军申海平张书红李子锋任磊
Owner CHINA PETROLEUM & CHEM CORP
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