Catalytic cracking catalyst regeneration method and device

A regeneration equipment and catalytic cracking technology, which is applied in catalyst regeneration/reactivation, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc., can solve the problems of poor fluidization effect, high price of platinum, To solve problems such as limited resources, achieve the effect of improving product distribution, reducing carbon content, and improving regeneration effect

Active Publication Date: 2016-04-27
CHINA PETROLEUM & CHEM CORP +1
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Problems solved by technology

[0003] From the point of view of the existing technology, most of the traditional CO combustion aids use platinum as the active component. Platinum is expensive and has limited resources. Moreover, the other main disadvantage of the traditional noble metal-supported CO combustion aids is that the loaded noble metals are exposed to high temperature water vapor. It is easy to condense and deactivate, so it is necessary to continu...

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  • Catalytic cracking catalyst regeneration method and device
  • Catalytic cracking catalyst regeneration method and device
  • Catalytic cracking catalyst regeneration method and device

Examples

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Embodiment 1-3

[0054] This example is used to illustrate the effect of the catalytic cracking catalyst regeneration method and equipment provided by the present invention.

[0055] Using vacuum residue as raw material, the catalytic cracking catalyst is MLC-500, and the test is carried out on a medium-sized riser reactor. The structure of the regenerator is as figure 1 As shown, the spent catalyst from the inclined tube 3 of the spent catalyst enters the catalyst dense-phase area of ​​the first regenerator 1, and performs incomplete regeneration with the oxygen-containing gas from the first main air distributor 5, and the semi-regenerated catalyst passes through the conduit 10 Enter the middle and lower part of the catalyst dense phase area of ​​the second regenerator 2, contact with the oxygen-containing gas from the second main air distributor 11 for complete regeneration, the generated gas containing CO moves upward, and the methanol enters the second regenerator through the methanol dist...

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Abstract

The invention relates to a catalytic cracking catalyst regeneration method and a catalytic cracking catalyst regeneration device. The method comprises the following steps: (1) a spent catalyst is introduced into a first regenerator, such that the spent catalyst contacts a first oxygen-containing gas in the first regenerator; and coke-burning regeneration is carried out, such that semi-regenerated catalyst is obtained; and (2) the semi-regenerated catalyst is introduced into a second regenerator, such that the semi-regenerated catalyst contacts a second oxygen-containing gas in a catalyst dense phase zone in the second regenerator; and coke-burning regeneration is continued; gas produced after coke burning contacts methanol, and combustion is continued. The device comprises the first regenerator and the second regenerator. The first regenerator and the second regenerator have dense phase zones and dilute phase zones. The dense phase zone of the first regenerator communicates with the dense phase zone of the second regenerator through a conduit. A methanol distributor is arranged in the second regenerator. With the method provided by the invention, catalyst dilute phase bed layer temperature of the regenerators can be substantially reduced, such that regenerator stable operation can be realized, and catalytic cracking process production distribution can be improved.

Description

technical field [0001] The invention relates to a catalytic cracking catalyst regeneration method and catalytic cracking catalyst regeneration equipment. Background technique [0002] Catalytic cracking is the most important processing technology for lightening heavy oil in refineries. During the catalytic cracking process, heavy oil is cracked into gas and light hydrocarbons on the surface of the catalyst, and at the same time, carbon deposits appear on the surface of the catalyst, which leads to a significant decline in activity. In order to restore the cracking activity of the catalyst and provide the required heat, the coke-deposited catalyst is sent to the regenerator after the reaction to burn off the coke attached to the catalyst and restore the activity of the catalyst. Coke combustion will release a large amount of CO 2 and CO. A large number of industrial data show that the dilute phase space for regeneration is very large, and the residence time of the flue gas ...

Claims

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Application Information

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IPC IPC(8): B01J38/12B01J38/20B01J23/92
Inventor 魏晓丽袁起民陈学峰
Owner CHINA PETROLEUM & CHEM CORP
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