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Double-ingredient chrome-free water-based metal anticorrosive paint and preparation method thereof

A metal anti-corrosion, chromium water-based technology, applied in anti-corrosion coatings, coatings, etc., can solve problems such as harmful hexavalent chromium, and achieve the effects of reducing the volatilization of harmful odors, improving long-term stability, and environmental protection in the process.

Inactive Publication Date: 2016-04-27
沈阳市航达科技有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because the traditional zinc-chromium coating contains hexavalent chromium, which is harmful to the human body, countries around the world, especially developed countries, have begun to take increasingly strict measures to limit its use.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] To prepare the chromium-free water-based metal anti-corrosion coating described in this scheme, proceed as follows:

[0043] First prepare the component A of the coating of this scheme:

[0044] (1) Select 70 kg of 500-mesh spherical zinc powder, 12 kg of FLT2 spherical aluminum powder, add 15 kg of ethylene carbonate and mix them, and at the same time add 1.0 kg of sodium molybdate and stir evenly; adopt the invention patent "A superfine flake metal Powder processing method and equipment" (authorized announcement number: CN101829787B) processing method, processing spherical zinc powder and spherical aluminum powder into flake zinc powder and flake aluminum powder, the diameter of the zinc and aluminum powder is controlled at no more than 20 μm , the thickness is not more than 0.3μm, and the passivation flake zinc-aluminum mixed slurry is made into 98 kg for standby after adjusting the viscosity.

[0045] The above-mentioned metal powder processing method: use a closed...

Embodiment 2

[0050] Embodiment 2: prepare the chromium-free waterborne metal anticorrosion coating described in this scheme, carry out as follows:

[0051] First prepare the component A of the coating of this scheme:

[0052](1) Select 65 kg of 500-mesh zinc powder, 7 kg of FLT2 aluminum powder, add 11 kg of ethylene carbonate and mix them, and at the same time add 0.9 kg of ammonium molybdate and stir evenly; adopt the invention patent "A superfine flake metal powder The processing method and equipment" (authorized announcement number: CN101829787B) process spherical zinc powder and spherical aluminum powder into flake zinc powder and flake aluminum powder. No more than 0.2 μm, 83.9 kg of passivated flaky zinc-aluminum mixed slurry is made after viscosity adjustment.

[0053] The above-mentioned metal powder processing method: use a closed cylindrical ball mill tank, first load rigid grinding spheres, and then add granular metal powder to be processed, the volume ratio of grinding sphere...

Embodiment 3

[0059] To prepare the chromium-free water-based metal anti-corrosion coating described in this scheme, proceed as follows:

[0060] First prepare the component A of the coating of this scheme:

[0061] (1) Select 72 kg of 500-mesh zinc powder, 8 kg of FLT2 aluminum powder, add 14 kg of ethylene carbonate and mix them, and at the same time add 1.0 kg of a mixture of sodium molybdate and ammonium molybdate and stir evenly. The weight ratio is 8:2; using the processing method of the invention patent "A Processing Method and Equipment for Ultrafine Flake Metal Powder" (authorized announcement number: CN101829787B), the spherical zinc powder and spherical aluminum powder are processed into flakes Zinc powder and flaky aluminum powder, the diameter of the zinc-aluminum powder is controlled at no more than 20 μm, and the thickness is not more than 0.2 μm. After adjusting the viscosity, 95 kg of passivated flaky zinc-aluminum mixed powder slurry is prepared for use.

[0062] The abov...

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Abstract

The invention relates to the field of environment-friendly paint, in particular to double-ingredient chrome-free water-based metal anticorrosive paint and a preparation method thereof. The anticorrosive paint comprises an ingredient A and an ingredient B, wherein the ingredient A is prepared from ingredients including zinc powder, aluminum power, passivants, dispersing agents and surfactants. The ingredient B is prepared from ingredients including silane coupling agents, boracic acid, passivant, natural zeolite and deionized water. The preparation method comprises the following steps that the ingredient A is stirred and mixed to prepare the ingredient A; firstly, the natural zeolite, the passivant and the deionized water are mixed, and are then mixed and stirred with the silane coupling agents and the boracic acid to prepare the ingredient B. Before use, the ingredient A and the ingredient B are mixed, stirred and uniformly prepared into finished product paint according to a weight proportion of 1:(1.3-1.4); the paint can be coated in a brush coating, spray coating or dip-coating mode; heating is used for sintering curing. The double-ingredient chrome-free water-based metal anticorrosive paint has the advantages that no heavy metal ionic compound such as hexavalent chromium, lead, mercury and cadmium compound exist; volatile noxious solvents such as benzene and xylene are not contained; the storage stability of the finished product paint is greatly improved; the anti-corrosion performance of a coating is also improved.

Description

technical field [0001] The invention relates to a preparation method of a metal anticorrosion coating, in particular to a two-component chromium-free water-based metal anticorrosion coating and a preparation method thereof. Background technique [0002] Zinc-chromium coating (also known as Dacromet coating) technology has developed rapidly since its appearance, and its application fields have been extended to industries such as medicine, electric power, petrochemical industry, and military industry. However, because the traditional zinc-chromium coating contains hexavalent chromium, which is harmful to human body, countries all over the world, especially developed countries, have begun to take increasingly strict measures to limit its use. Therefore, there is an urgent need to develop new chromium-free coatings to meet health and environmental requirements. At present, a variety of chromium-free zinc-aluminum coatings have been launched at home and abroad, and as an updated...

Claims

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Application Information

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IPC IPC(8): C09D5/10C09D183/04C09D7/12
CPCC09D5/106C09D4/00C09D5/103C09D7/61C09D7/63
Inventor 殷跃军李庆鹏张亮刘建国杨宏强严伟川
Owner 沈阳市航达科技有限责任公司
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