Metal organic complex containing thiophene functional group and preparing method and application of metal organic complex
A functional group, metal-organic technology, which is applied in the field of porous metal-organic complexes and their preparation, can solve problems such as poisoning, impaired liver and kidney functions and immunity, and anemia, and achieves the effect of a simple synthesis method.
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[0028] Example 1 Organometallic complexes containing thiophene functional groups
[0029] Will H 2 btdc(0.005g, 0.02mmol) and Cd(NO 3 ) 2 ·6H 2 O (0.015g, 0.05mmol) was added to a high temperature resistant screw-top glass bottle with a volume of 5mL, added 0.75mL DMF, stirred with a magnetic stirrer to dissolve it, and then added 0.75ml C 2 H 5 OH, stir for 15 minutes until the metal salt is completely dissolved and the ligand is evenly mixed. The glass bottle is sealed and placed in an oven at 75°C, heated at this temperature for 2 days, and heated at 5°C·h -1 The cooling rate is slowly cooled to room temperature, and yellow lumpy crystals are formed. They are washed with N,N-dimethylformamide, filtered, and dried to obtain the target product, which is a metal organic complex containing thiophene functional groups. The yield is 58%.
[0030] Elemental analysis calculated value (%): C30.64, H1.97; measured value (%): C30.70, H2.01.
[0031] Infrared spectrum (KBr, cm -1 ): 3437m, ...
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[0034] Example 2 Fluorescence properties of a metal organic complex containing thiophene functional groups and the function of selectively recognizing metal ions
[0035] Method: A metal-organic complex containing thiophene functional groups prepared in Example 1 was used as a fluorescence sensor to selectively identify metal ions.
[0036] 1) Carry out the fluorescence luminescence test of solid and liquid at room temperature on the metal organic complex containing thiophene functional group of the present invention.
[0037] Liquid sample configuration: Take a certain amount of metal organic complex crystals containing thiophene functional groups, grind it to a uniform powder, and then dissolve it in methanol solution to a concentration of 1×10 -4 M methanol suspension.
[0038] The results of solid-state fluorescence analysis showed that the metal-organic complex containing thiophene functional groups exhibited a strong emission band around 468nm under excitation at a wavelength of ...
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