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Metal organic complex containing thiophene functional group and preparing method and application of metal organic complex

A functional group, metal-organic technology, which is applied in the field of porous metal-organic complexes and their preparation, can solve problems such as poisoning, impaired liver and kidney functions and immunity, and anemia, and achieves the effect of a simple synthesis method.

Inactive Publication Date: 2016-05-04
LIAONING UNIVERSITY
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Zinc is one of the essential trace elements for the human body. It plays an extremely important role in important physiological processes such as human growth and development, reproductive genetics, immunity, and endocrine. However, excessive zinc intake can cause poisoning, such as eating too much zinc Acute zinc poisoning can cause gastrointestinal symptoms such as vomiting and diarrhea; chronic zinc poisoning can cause anemia and other symptoms; animal experiments can cause damage to liver, kidney function and immunity

Method used

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  • Metal organic complex containing thiophene functional group and preparing method and application of metal organic complex
  • Metal organic complex containing thiophene functional group and preparing method and application of metal organic complex
  • Metal organic complex containing thiophene functional group and preparing method and application of metal organic complex

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Experimental program
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Effect test

Embodiment 1

[0028] Embodiment 1 contains the organometallic complex of thiophene functional group

[0029] H 2 btdc (0.005g, 0.02mmol) and Cd(NO 3 ) 2 ·6H 2 O (0.015g, 0.05mmol) was added into a high-temperature-resistant screw-top glass bottle with a volume of 5mL, 0.75mL of DMF was added, stirred with a magnetic stirrer to dissolve it, and then 0.75ml of C 2 h 5 OH, stir for 15 minutes until the metal salt is completely dissolved and mixed evenly with the ligand, seal the glass bottle and put it in an oven at 75°C, heat at this temperature for 2 days, at 5°C·h -1 The cooling rate was slowly cooled to room temperature, and yellow blocky crystals were generated. They were washed with N,N-dimethylformamide, filtered, and dried to obtain the target product, which was a metal-organic complex containing thiophene functional groups. The yield was 58%.

[0030] Elemental analysis calculated value (%): C30.64, H1.97; measured value (%): C30.70, H2.01.

[0031] Infrared spectrum (KBr, cm ...

Embodiment 2

[0034] Example 2 Fluorescence properties and selective recognition of metal ions of a metal-organic complex containing thiophene functional groups

[0035] Method: A metal-organic complex containing thiophene functional group prepared in Example 1 was used as a fluorescent sensor to selectively recognize metal ions.

[0036] 1) The metal-organic complexes containing thiophene functional groups of the present invention are subjected to solid and liquid fluorescence luminescence tests at room temperature.

[0037] Liquid sample configuration: Take a certain amount of metal-organic complex crystals containing thiophene functional groups, grind to uniform powder, then dissolve in methanol solution, and configure to a concentration of 1×10 -4 Methanol suspension of M.

[0038] The results of solid-state fluorescence analysis show that the metal-organic complex containing thiophene functional groups exhibits a strong emission band at about 468 nm under excitation at a wavelength of...

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Abstract

The invention relates to a metal organic complex containing a thiophene functional group and a preparing method and application of the metal organic complex. According to the technical scheme, Cd(NO3)2.6H2O, a ligand 2,2'-bithiophene-5,5'-dicarboxylic acid(H2btdc), a solvent N,N-dimethyl formamide and ethyl alcohol are added into a high-temperature-resistant spiral opening glass bottle, and stirring is carried out at the room temperature; the container is sealed and then put into an oven, and heating is carried out for 1-2 days at the temperature of 75 DEG C; the container is slowly cooled to the room temperature, and yellow transparent bulk crystals are obtained; the mixture is washed with N,N-dimethyl formamide, filtered and dried, and the target product is obtained. The prepared metal organic complex containing the thiophene functional group shows a good fluorescence characteristic and can be used for efficiently and selectively recognizing heavy metal zinc ions.

Description

technical field [0001] The invention relates to a porous metal-organic complex containing thiophene functional sites and its preparation method and application, in particular to the preparation and application of a porous metal-organic complex with zinc ion selective recognition function. Background technique [0002] In recent years, functional metal-organic framework materials have received considerable attention as a rapidly developing field, not least because of their great potential for practical applications. In photochemical reactions, the absorption and release of light energy is achieved through the transfer of energy from the reaction center to the electron-driving center in the light-harvesting compound. To maximize the efficiency of the energy transfer process, the relative orientation of the components in the light-harvesting compound is crucial. In order to simulate the process of photosynthesis, the synthesis of molecules also relies on the effective control ...

Claims

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Application Information

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IPC IPC(8): C07F3/08C09K11/06G01N21/64
CPCC07F3/003C07B2200/13C09K11/06C09K2211/188G01N21/643
Inventor 韩正波魏娜
Owner LIAONING UNIVERSITY
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