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Preparing method of hexagonal boron nitride/polystyrene composite

A hexagonal boron nitride and polystyrene technology, applied in chemical instruments and methods, heat exchange materials, etc., can solve the problems of complex processing technology, low thermal conductivity, and difficult to process and shape, and achieve strong controllability and high Effects of mechanical properties and thermal conductivity

Active Publication Date: 2016-08-17
LIAONING UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, its low thermal conductivity and poor mechanical properties cannot meet the industrial needs of heat dissipation and high strength.
At present, the common way to improve the thermal conductivity and mechanical properties of polystyrene is to add fillers with high thermal conductivity and high mechanical properties. Adding some fillers can improve the mechanical properties and thermal conductivity, but it will bring other defects, such as adding metal The corrosion resistance of the material is poor, the price is high, and it is not easy to process and shape; the addition of metal oxide materials will lead to high production costs and complicated processing technology; the addition of graphite materials will cause its insulation performance to deteriorate

Method used

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  • Preparing method of hexagonal boron nitride/polystyrene composite
  • Preparing method of hexagonal boron nitride/polystyrene composite
  • Preparing method of hexagonal boron nitride/polystyrene composite

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] 1) Hexagonal boron nitride pretreatment: KH-570 (the amount of coupling agent added is 2% of the total mass of hexagonal boron nitride and styrene) and 200ml deionized water, magnetically stirred for about 20min, and hexagonal boron nitride Add in the solution and continue magnetic stirring for 40min, then continue stirring for 30min in a 70°C water bath, filter, and obtain boron nitride powder ( figure 1 ), figure 1 The peak positions shown are consistent with those reported for boron nitride in the literature. Located at 783cm -1 and 1383cm -1 The absorption band is the characteristic absorption peak of hexagonal boron nitride, of which 783cm -1 The absorption peak corresponding to the out-of-plane bending vibration of the B-N-B bond, while 1383cm -1 The in-plane stretching vibration absorption peak corresponding to the B-N bond. Dry at 110°C for 12 hours, and grind the dried boron nitride powder with a mortar for use.

[0029] 2) Preparation of h-BN@PS masterba...

Embodiment 2

[0033] The preparation method is the same as that in Example 1, except that, according to the mass ratio, hexagonal boron nitride:styrene=1:16.7, and the mass ratio of hexagonal boron nitride and polystyrene polymer is 1:61.

[0034] The mechanical properties of the obtained hexagonal boron nitride / polystyrene polymer composite were tested, and the test results are shown in Table 1.

Embodiment 3

[0036] The preparation method is the same as in Example 1, except that, according to the mass ratio, hexagonal boron nitride: styrene = 1:11.1, and the mass ratio of hexagonal boron nitride and polystyrene polymer is 1:40.7.

[0037] The mechanical properties of the obtained hexagonal boron nitride / polystyrene polymer composite were tested, and the test results are shown in Table 1.

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Abstract

The invention discloses a preparing method for a hexagonal boron nitride / polystyrene composite and belongs to the technical field of high polymer material modification and the technical field of processing. The preparing method comprises the steps that firstly, a suspension polymerization method is adopted, and h-BN@PS masterbatch is prepared from boron nitride, styrene, a coupling agent, an initiator and a dispersing agent, wherein the mass ratio of the h-BN@PS masterbatch to polystyrene is 1:(3-5); the h-BN@PS masterbatch and a polystyrene base material are mixed, and the hexagonal boron nitride / polystyrene composite is prepared, wherein the mechanical performance of polystyrene is enhanced, and the heat conductivity coefficient can be increased. The preparing process of the composite is advanced, the compatibility of hexagonal boron nitride and polystyrene can be improved, and operation is simple and environmentally friendly; the composite can obtain high mechanical performance and a high heat conductivity coefficient under a low filler doping amount, and significant application value is achieved.

Description

technical field [0001] The invention relates to a method for preparing a hexagonal boron nitride / polystyrene polymer composite material with high mechanical and thermal conductivity properties, and belongs to the technical field of polymer material modification and processing. Background technique [0002] In recent years, in the field of polymer composite materials, polymer composite materials with high mechanical and high thermal conductivity have gradually become a research hotspot and focus, and have attracted great attention from researchers. Various fields in the national economy have increasingly stringent performance requirements for high-mechanical and high-thermal-conductivity materials. Traditional high-mechanical and high-thermal-conductivity materials have different insurmountable defects, and it is difficult to meet the requirements of modern industries for the diverse functions of thermally conductive materials. sexual demands. Therefore, the development of n...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L25/06C08K9/06C08K3/38C08F112/08C08F2/20C08J3/22C09K5/14
CPCC08F2/20C08F112/08C08J3/226C08J2325/06C08J2425/06C08L25/06C08L2205/025C09K5/14C08K9/06C08K2003/385
Inventor 张向东刘世财韩维坊韩伟葛春华关宏宇
Owner LIAONING UNIVERSITY
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