Low-cost high-conductivity magnet based amorphous nanocrystalline magnetically soft alloy and preparation method thereof

A technology of amorphous nanocrystalline and soft magnetic alloys, which is applied in the field of high-permeability magnetic-based amorphous nanocrystalline soft magnetic alloys and its preparation, can solve the problems of unfavorable industrial production, high raw material costs, and high prices, and achieve energy saving in production The effect of modernization, simple production process and short production process

Active Publication Date: 2016-08-17
NEW MATERIALS TECH JIANGSU AMORPHD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the price of Nb is relatively expensive, and there is a problem of high raw material cost, which is not conducive to industrial production
CN103924169A reported reducing the content of Nb on the basis of Fe-Si-B-P-Cu-Nb alloy and modifying it by doping a small amount of rare eart

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Example 1Fe 82 Si 10 B 1.0 al 1.2 Cu 2.3 Nb 3.5 Y 0.01 preparation of

[0027] According to the molecular formula Fe of amorphous nanocrystalline soft magnetic alloy 82 Si 10 B 1.0 al 1.2 Cu 2.3 Nb 3.5 Y 0.01 The mass percentage of each element in the formula is compounded to obtain the master alloy raw material. Add a small amount of pure iron and ferro-niobium, a small amount of ferro-boron and a small amount of pure iron, copper and aluminum, Y, a small amount of ferro-boron and a small amount of pure iron, and polysilicon in the intermediate frequency melting furnace from the bottom to the top of the above-mentioned master alloy raw materials , and the balance of pure iron. The initial melting power of the intermediate frequency melting furnace is 35KW, and it is increased to 130-140KW at a rate of 0.5-2KW / min. When the master alloy raw material is completely melted, the heating is stopped, and the steelmaking slagging agent is covered on the molten al...

Embodiment 2

[0030] Example 2Fe 82 Si 10 B 1.0 Zn 1.2 Cu 2.3 Nb 3.5 Y 0.01 preparation of

[0031] According to the molecular formula Fe of amorphous nanocrystalline soft magnetic alloy 82 Si 10 B 1.0 Zn 1.2 Cu 2.3 Nb 3.5 Y 0.01 The mass percentage of each element in the formula is compounded to obtain the master alloy raw material. Add a small amount of pure iron and ferro-niobium, a small amount of ferro-boron and a small amount of pure iron, copper and zinc, Y, a small amount of ferro-boron and a small amount of pure iron, and polysilicon in the intermediate frequency smelting furnace from the bottom to the top of the above-mentioned master alloy raw materials , and the balance of pure iron. The initial smelting power of the intermediate frequency melting furnace is 30KW, and it is increased to 130-140KW at a rate of 0.5-2KW / min. When the master alloy raw material is completely melted, the heating is stopped, and the steelmaking slagging agent is covered on the molten alloy ...

Embodiment 3

[0034] Example 3 Fe 84 Si 9 B 1.0 Al 1.5 Cu 1.0 Nb 3.5 Y 0.01 preparation of

[0035] According to the molecular formula Fe of amorphous nanocrystalline soft magnetic alloy 84 Si 9 B 1.0 Al 1.5 Cu 1.0 Nb 3.5 Y 0.01 The mass percentage of each element in the formula is compounded to obtain the master alloy raw material. Add a small amount of pure iron and ferro-niobium, a small amount of ferro-boron and a small amount of pure iron, copper and aluminum, Y, a small amount of ferro-boron and a small amount of pure iron, and polysilicon in the intermediate frequency melting furnace from the bottom to the top of the above-mentioned master alloy raw materials , and the balance of pure iron. The initial smelting power of the intermediate frequency melting furnace is 40KW, and it is increased to 130-140KW at a rate of 0.5-2Kw / min. When the master alloy raw material is completely melted, the heating is stopped, and the steelmaking slagging agent is covered on the molten al...

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Abstract

The invention discloses low-cost high-conductivity magnet based amorphous nanocrystalline magnetically soft alloy and a preparation method thereof. The molecular formula of the magnetically soft alloy is FeaSibBcMdCueNbfM'g, wherein M is Al or Zn, and M' is selected from one or more of Y, Gd or Er; and a, b, c, d, e, f and g are the mass percent, the value ranges meet the conditions that a is larger than or equal to 79 and less than or equal to 88.5, b is larger than or equal to 8 and less than or equal to 11, c is larger than or equal to 0.05 and less than or equal to 2, d is larger than or equal to 0.8 and less than or equal to 1.5, e is larger than or equal to 0.7 and less than or equal to 2.5, f is larger than or equal to 2 and less than or equal to 4, and g is larger than or equal to 0.008 and less than or equal to 0.02. On the basis that the high magnetic conductivity, high Bs and low coercive force and consumption of the magnetically soft alloy are all achieved, the low-cost Al or the Zn is adopted to replace copper partially, the content of Nb is decreased, and trace rare-earth metal is mixed, so that the production cost is reduced. The low-cost high-conductivity magnet based amorphous nanocrystalline magnetically soft alloy is obtained through the preparation method which is simple in process and disclosed by the invention.

Description

technical field [0001] The invention belongs to the technical field of soft magnetic alloy materials, and in particular relates to a low-cost high-permeability amorphous nanocrystalline soft magnetic alloy and a preparation method thereof. Background technique [0002] Soft magnetic material is a commonly used functional material, which has been widely used in industrial fields such as electric power, motor and electronics. Since the 19th century, soft magnetic alloys have been greatly developed, and successively produced electrical pure iron, silicon steel, permalloy, iron-aluminum alloy, iron-silicon aluminum alloy, iron-cobalt alloy, soft magnetic ferrite and Fe-based amorphous nanocrystalline A series of soft magnetic alloys such as soft magnetic alloys. [0003] Iron-based amorphous nanocrystalline soft magnetic alloy has high resistance, high magnetic permeability, low iron loss and high saturation magnetic flux density. Since the discovery of Finemet soft magnetic al...

Claims

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Application Information

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IPC IPC(8): C22C45/02C21D1/26H01F1/153
CPCC21D1/26C21D2201/03C22C33/003C22C45/02H01F1/15308H01F1/15333H01F1/15341Y02P10/20
Inventor 陈雨峰朱昭峰
Owner NEW MATERIALS TECH JIANGSU AMORPHD
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