Halogen-free and environment-friendly EPDM (Ethylene-Propylene-Diene Monomer) rubber/negative oxygen ion powder mixed closed-cell secondary foaming material and preparation method thereof
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A technology of EPDM rubber and negative oxygen ion powder, which is applied in the field of foaming materials, can solve the problems of poor dispersibility, failure to improve the air quality of the surrounding environment and benefit physical and mental health, and cannot reach per cubic centimeter. The effect of rate synchronization
Active Publication Date: 2016-08-24
YIBAO FUJIAN POLYMER MATERIALS
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Plastics, rubber, and rubber products containing tourmaline PHR and tender shale (negative oxygen ion powder) produced according to the aforementioned technology can be widely used in sporting goods, medical protective gear, dining utensils, office supplies, automotive interiors, decorations Materials and other products, when people use and touch such products, these products will exert the characteristics of tourmaline and tender shale (negative oxygen ion characteristics), can purify the surrounding environment and water quality, release negative oxygen ions, stimulate cell activity, and promote plant growth. Growth and development, prevention of electromagnetic radiation, etc., make people benefit from it. However, due to the material differences between rubber materials and tourmaline powder and tender shale, and tourmaline powder and tender shale also have high biological activity, for foaming materials It is difficult to say that the poor dispersion after processing and integration is difficult. If tourmaline powder and tender shale cannot be effectively and evenly dispersed in rubber molecules to form clusters, it will not only affect the quality of rubber products, but also cannot fully release a sufficient amount of negative energy. Oxygen ions cannot give full play to the effect of air energy negative oxygen ion powder, and the concentration of negative oxygen ions released by the product cannot reach 200-400 per cubic centimeter in static state and 400-1000 per cubic centimeter in dynamic state, and there is no improvement The air quality of the surrounding environment and the original intention of being beneficial to physical and mental health, therefore, how to improve the dispersion of negative oxygen ion powder in rubber, reduce costs, and improve the comprehensive physical properties of products, so as to enhance the application range of ecological health is an urgent need to solve in the field of foaming material technology important technical issues
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Embodiment 1
[0065] A preparation method of a halogen-free environment-friendly EPDM rubber / negative oxygen ion powder blended closed-cell secondary foaming material includes the following steps:
[0066] (1) Preparation of negative oxygen ion pre-mixed powder: 100PHR tourmaline powder, 100PHR Wizard R series plastic / rubber additive 1250 mesh, 5PHR chelating titanate coupling agent, 30PHR magnesium strong powder into Φ800 *1000mm high-speed stirring tank, stirring for 12 minutes, continuously controlling the temperature at 80°C±5°C during the stirring process, the negative oxygen ion premixed powder is obtained after the stirring is completed, and the negative oxygen ion premixed powder is weighed according to the formula weight PHR ratio Repackaging
[0086] The preparation method of the EPDM / PP / TPE / negative oxygen ion powder blended closed-cell secondary foaming material in Example 2 is completely the same as that of Example 1, except that the proportions of the components in Example 2 are as follows:
[0087] EPDM rubber 100PHR;
[0088] Negative oxygen ion premixed powder 45PHR;
[0089] Carbon black 25PHR;
[0090] Softener 28PHR;
[0091] Anti-fogging agent 1.5PHR;
[0092] Anti-aging agent 2PHR;
[0093] Antioxidant 1.5PHR;
[0094] Dispersant 2PHR;
[0095] Flow agent 1PHR;
[0096] Plasticizer 1.2PHR;
[0097] Curing agent 2PHR;
[0098] Accelerator 2.6PHR;
[0099] Foaming agent 4.6PHR;
[0100] Foaming aid 5PHR;
[0101] The physical properties of the halogen-free environmentally friendly EPDM rubber / negative oxygen ion powder blended closed-cell secondary foam material prepared in Example 2 are shown in Table 4 below:
[0102]
[0103] Table 4. Physical properties of Example 2
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Abstract
The invention relates to the technical field of foaming materials and provides a halogen-free and environment-friendly EPDM (Ethylene-Propylene-Diene Monomer) rubber / negative oxygen ion powder mixed closed-cell secondary foaming material and a preparation method thereof. Negative oxygen ion powder of the halogen-free and environment-friendly EPDM rubber / negative oxygen ion powder mixed closed-cell secondary foaming material can be effectively combined with halogen-free and environment-friendly EPDM rubber under the condition that high biological activity of the negative oxygen ion powder is maintained, the dispersity of the negative oxygen ion powder on rubber molecules is effectively improved, original excellent physical properties of the rubber can be effectively reserved, enough negative oxygen ions can be released effectively and sufficiently, a product prepared from the secondary foaming material can continuously release 1,500 negative oxygen ions in each cubic centimeter of space in a static state, can improve ambient air quality and benefits human health; the preparation method of the halogen-free and environment-friendly EPDM rubber / negative oxygen ion powder mixed closed-cell secondary foaming material is simple to operate, easy to implement and suitable for large-scale production.
Description
Technical field [0001] The invention relates to a foaming material, in particular to a halogen-free environment-friendly EPDM / negative oxygen ion powder blended closed-cell secondary foaming material and a preparation method thereof. Background technique [0002] In recent years, EPDM foam materials have been widely used in important industries of the national economy such as automobiles, electronics, electrical appliances, and construction. At the same time, due to the tensile strength of EPDM foam materials in many fields of industry now , Elongation at break, tear strength, high temperature resistance and other properties have higher requirements, and the odor of EPDM foam materials is heavier, most of them contain halogen (fluorine, chlorine, bromine, iodine), halogen in the material (Fluorine, chlorine, bromine, iodine) The foaming material made with the content exceeding a certain value will produce a kind of hydrogen halide gas when burned, which will suffocate the breathi...
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