Novel multifunctional skin protection material and preparation method and application thereof

A multifunctional, fiber composite material technology, used in textiles and papermaking, bandages, animal fibers, etc., can solve the problems of difficult recycling, heavy load, inconvenience to carry, etc., achieve excellent catalytic digestion efficiency, good stability, and promote wound healing effect

Inactive Publication Date: 2016-08-24
INST OF PHARMACOLOGY & TOXICOLOGY ACAD OF MILITARY MEDICAL SCI P L A +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, Cu-BTC powder is usually prepared by solvothermal method experiments, which are difficult to put into practical applications due to problems such as heavy load, inconvenient portability, and difficult recycling and reuse in military equipment.

Method used

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  • Novel multifunctional skin protection material and preparation method and application thereof
  • Novel multifunctional skin protection material and preparation method and application thereof
  • Novel multifunctional skin protection material and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] 1) Dissolve 2.0g of sodium hydroxide in 38.0g of water to obtain a 5wt.% NaOH solution, then add 4.7g of sodium chloroacetate. After dissolving, immerse 0.12g of chitosan fibers in sodium chloroacetate solution for carboxylation treatment, take out the chitosan fibers after 1h, and wash off the unreacted residual liquid on the fiber surface with 40mL of distilled water;

[0016] 2) Dissolve 0.20g of copper acetate monohydrate and 0.11g of 1,3,5-benzenetricarboxylic acid in 100mL of absolute ethanol;

[0017] 3) the chitosan fibers after the treatment in step 1) are immersed alternately in the ethanol solution of copper acetate in step 2) and in the ethanol solution of 1,3,5-benzenetricarboxylic acid for each 20min, after each soaking, the shell The polysaccharide fibers were soaked and washed in absolute ethanol for 2 min. Four layers of Cu-BTC can be loaded on the surface of chitosan fibers after four alternate immersion cycles in the ethanol solution of copper acetat...

Embodiment 2

[0020] 1) Dissolve 2.0g of sodium hydroxide in 38.0g of water to obtain a 5wt.% NaOH solution, then add 4.7g of sodium chloroacetate. After dissolving, immerse 0.10g of chitosan fibers in sodium chloroacetate solution for carboxylation treatment, take out the chitosan fibers after 1h, and wash off the unreacted residual liquid on the fiber surface with 40mL of distilled water;

[0021] 2) Dissolve 0.40g of copper acetate monohydrate and 0.21g of 1,3,5-benzenetricarboxylic acid in 200mL of absolute ethanol;

[0022] 3) the chitosan fibers after the treatment in step 1) are immersed alternately in the ethanol solution of copper acetate in step 2) and in the ethanol solution of 1,3,5-benzenetricarboxylic acid for each 20min, after each soaking, the shell The polysaccharide fibers were soaked and washed in absolute ethanol for 2 min. After eight alternate immersion cycles in ethanol solutions of copper acetate and 1,3,5-benzenetricarboxylic acid, eight layers of Cu-BTC can be loa...

Embodiment 3

[0025] 1) Dissolve 2.0g of sodium hydroxide in 38.0g of water to obtain a 5wt.% NaOH solution, then add 4.7g of sodium chloroacetate. After dissolving, immerse 0.10 g of calcium and sodium alginate fiber in sodium chloroacetate solution for carboxylation treatment, take out the calcium and sodium alginate fiber after 1 hour, and wash off the unreacted residual liquid on the surface of the fiber with 40 mL of distilled water;

[0026] 2) Dissolve 0.20g of copper acetate monohydrate and 0.11g of 1,3,5-benzenetricarboxylic acid in 100mL of absolute ethanol;

[0027] 3) The calcium sodium alginate salt fibers treated in step 1) were alternately immersed in the ethanol solution of copper acetate in step 2) and the ethanol solution of 1,3,5-benzenetricarboxylic acid for 20 minutes each, after each soaking Soak and wash alginate calcium sodium salt fiber in absolute ethanol for 2 min. Four layers of Cu-BTC can be loaded on the surface of chitosan fibers after four alternate immersio...

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Abstract

The invention provides a Cu-BTC-based load type biological fiber multifunctional composite material which has excellent catalytic decomposition performance for a chemical toxic agent and a preparation method of the composite material and belongs to the technical field of functional materials. The material is formed in the mode that the biological fiber surface is loaded with a metal organic framework compound Cu-BTC through covalent bonds. The preparation method includes the steps that biological fibers are immersed in a biological fiber solution for carboxymethylated processing, and then residual liquid which does not react is flushed and removed with distilled water; the biological fibers which are subjected to carboxymethylated processing and washed to be clean are soaked in a Cu(OAc)2 absolute ethyl alcohol solution and a 1, 3, 5-benzene tricarbonic acid absolute ethyl alcohol solution, and the Cu-BTC-based load type biological fiber multifunctional composite material is obtained. The composite material is simple in preparation method and good in biocompatibility, has the functions of stopping bleeding and promoting healing of wounds, hygroscopicity and an antibacterial property and is high in digestion rate of chemical toxic agent and capable of being recycled. The novel multifunctional composite material can serve as medical sterile dressing for treating and curing wounded persons infected by the chemical toxic agent and a breathable multifunctional protection material which can discharge sweat and effectively discompose the chemical toxic agent and used for military equipment.

Description

technical field [0001] The invention belongs to the technical field of functional materials, and in particular relates to a Cu-BTC-based load type with excellent catalytic and digestion properties for chemical poisons at room temperature, hemostasis, wound healing promotion, good hygroscopicity and antibacterial properties, and biodegradability Multifunctional fiber composite material and its preparation method and use. Background technique [0002] With the growth of international terrorist activities and the proliferation of nuclear, biological and chemical weapons technology, the threat of nuclear, biological and chemical terrorist activities is on the rise worldwide. The severe situation of chemical weapons in neighboring countries makes our country still in the severe threat of chemical weapons. And with the development of modern chemical technology and the proliferation of chemical weapons production technology, chemical terror has intensified. Chemical weapons armam...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M13/21D06M13/503A61L15/28A61L15/18A61L15/44D06M101/10D06M101/06
Inventor 钟玉绪张立娟周云山孙俊梅应莺刘红岩
Owner INST OF PHARMACOLOGY & TOXICOLOGY ACAD OF MILITARY MEDICAL SCI P L A
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