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Electroplating liquid for cylinder outside-tank electroplating

An electroplating solution and cylinder technology, applied in electrolytic coatings, coatings, etc., can solve the problems of large changes in coating thickness, unpredictable service life, low product qualification rate, etc., to improve coating stress, hardness and coating thickness changes. Controllable and avoid loosely bound effects

Inactive Publication Date: 2016-09-28
LONCIN MOTOR
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the usual electroplating process, the electroplating solution is in a basically static environment, and the cations are passively moved to the inner surface of the cylinder as the cathode, and the resulting concentration difference makes the coating not tight, so it is easy to fall off, and the electroplating time is longer; and because The problem of concentration difference makes the coating thickness of the final product vary greatly and is difficult to control, which makes it difficult to control some key dimensions of the inner surface of the cylinder. Therefore, it is difficult to guarantee the quality of the finished product after electroplating
In the prior art, there is a technical scheme of circulating electroplating solution to electroplate nickel-silicon carbide composite layer on the inner circular surface of the cylinder, but because the electroplating process cannot guarantee the quality of the composite coating, the final cylinder product obtained cannot meet the needs of use; especially It is the traditional electroplating solution formula itself, which cannot be matched with the traditional electroplating process and the new process, resulting in the low pass rate of the final product and the expected service life.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030]Include the following steps:

[0031] a. Preprocessing:

[0032] a1. Etching, through NaOH 25g / L lye alkali etching, the time is 175s, and the temperature of the alkali etching solution is 40°C; it is carried out by the way of lye flowing through the inner surface of the cylinder;

[0033] a2. Passivation, passivation is carried out by acid solution, which includes 50g / L of potassium hydrogen persulfate and 6g / L of sulfuric acid; the time is 175s, and the temperature of the acid etching solution is 35°C; the acid solution is used to flow through the cylinder superficially;

[0034] a3. Activation, further corroding the inner surface of the cylinder with hydrofluoric acid 13g / L acid solution; the time is 30s, and the temperature is room temperature; the acid solution flows through the inner surface of the cylinder;

[0035] a4. Zinc conversion, using chemical zinc conversion to form a zinc layer on the inner surface of the cylinder; the zinc conversion solution used inc...

Embodiment 2

[0042] Include the following steps:

[0043] a. Preprocessing:

[0044] a1. Etching, through NaOH 5g / L lye alkali etching, the time is 180s, and the temperature of the alkali etching solution is 60°C; it is carried out by the way of lye flowing through the inner surface of the cylinder;

[0045] a2. Passivation, passivation is carried out by acid solution, which includes 12g / L of potassium hydrogen persulfate and 15g / L of sulfuric acid; the time is 180s, and the temperature of the acid etching solution is 45°C; the acid solution is used to flow through the cylinder superficially;

[0046] a3. Activation, further corroding the inner surface of the cylinder with hydrofluoric acid 4g / L acid solution; the time is 90s, and the temperature is room temperature; the acid solution flows through the inner surface of the cylinder;

[0047] a4. Zinc conversion, using chemical zinc conversion to form a zinc layer on the inner surface of the cylinder; the zinc conversion solution used inc...

Embodiment 3

[0054] Include the following steps:

[0055] a. Preprocessing:

[0056] a1. Etching, through NaOH 18g / L lye alkali etching, the time is 178s, and the temperature of the alkali etching solution is 50°C; it is carried out by the way of lye flowing through the inner surface of the cylinder;

[0057] a2. Passivation, passivation is carried out by acid solution, which includes 35g / L of potassium hydrogen persulfate and 9g / L of sulfuric acid; the time is 178s, and the temperature of the acid etching solution is 40°C; the acid solution is used to flow through the cylinder superficially;

[0058] a3. Activation, further corroding the inner surface of the cylinder with hydrofluoric acid 8g / L acid solution; the time is 60s, and the temperature is room temperature; the acid solution flows through the inner surface of the cylinder;

[0059] a4. Zinc conversion, using chemical zinc conversion to form a zinc layer on the inner surface of the cylinder; the zinc conversion solution used inc...

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PUM

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Abstract

The invention discloses an electroplating solution for electroplating outside a tank of a cylinder body, which comprises an electroplating solution A for pre-electroplating nickel and an electroplating solution B for electroplating a nickel-silicon carbide composite coating; the electroplating solution A contains nickel sulfate 246‑626g / L and boric acid 35‑45g / L; in electroplating solution B, nickel sulfate 246‑626g / L, boric acid 35‑45g / L, silicon carbide 10‑45g / L and electroplating additive 0.5‑2.5g / L ;The electroplating solution adopts the electroplating solution formula of pre-plating nickel and post-plating composite nickel layer, which is suitable for the electroplating process outside the tank, combined with the flowing electroplating solution to ensure the real-time replacement of cations on the coating, so that the concentration difference of cations on the surface of the cathode coating is basically zero Changes, avoiding the formation of a large concentration difference, and the change of the thickness of the coating is controllable; at the same time, the undifferentiated concentration combined with the special ratio of the plating solution ensures the compactness of the coating, avoids the appearance of loose bonding, and ensures the quality of the plating.

Description

technical field [0001] The invention relates to an electroplating solution for cylinder workpieces, in particular to an electroplating solution for flowing electroplating outside a tank. Background technique [0002] As the main part of the engine, the cylinder block is used to form the combustion chamber together with the piston and the cylinder head, and provide the movement track for the piston assembly, thereby forming a power conversion environment. When the cylinder guides the piston to reciprocate continuously, the inner wall of the cylinder and the piston rub against each other for a long time and at high frequency, which reduces the useful power of the cylinder and consumes part of the energy. Therefore, there is electroplating on the inner wall in the prior art, and the electroplating coating is used to replace the cylinder liner to solve the above problems. In the usual electroplating process, the electroplating solution is in a basically static environment, and ...

Claims

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Application Information

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IPC IPC(8): C25D7/04C25D5/08C25D3/12C25D5/14C25D15/00
CPCC25D7/04C25D3/12C25D5/08C25D5/14C25D15/00
Inventor 刘智勇聂进
Owner LONCIN MOTOR