Method for preparing gallium nitride light emitting diode on patterned gallium nitride single crystal substrate
A gallium nitride single crystal and light-emitting diode technology, which is applied in the manufacture of semiconductor/solid-state devices, electrical components, circuits, etc., can solve the problems of poor thermal conductivity of sapphire substrates, and achieve the effect of good heat dissipation performance.
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Embodiment 1
[0030] A method for preparing a gallium nitride light-emitting diode on a patterned gallium nitride single crystal substrate, comprising the following steps:
[0031] Step 1. Deposit SiO with a thickness of 100nm on a gallium nitride single crystal substrate by chemical vapor deposition (PECVD) 2 Or SiN is used as the mask pattern layer, and the mask pattern layer is prepared as a circular hole-shaped mask pattern layer with a periodic structure. The circular hole diameter of the circular hole-shaped mask pattern layer is 0.9 microns. The pattern period of the circular hole mask pattern layer is 1.5 microns.
[0032] Step 2, clean the gallium nitride single crystal substrate 101 prepared with a circular hole-shaped mask pattern layer and put it into an MOCVD reaction chamber for secondary growth. 2 Atmosphere and 1000°C, the pressure of the MOCVD reaction chamber is 250 torr, the V / III molar ratio is 1200, and the growth rate of 1 micron / hour is used to three-dimensionally gr...
Embodiment 2
[0041] Step 1. Deposit SiO with a thickness of 98nm on a gallium nitride single crystal substrate by chemical vapor deposition (PECVD) 2 Or SiN is used as the mask pattern layer, and the mask pattern layer is prepared as a circular hole-shaped mask pattern layer with a periodic structure. The circular hole diameter of the circular hole-shaped mask pattern layer is 0.8 microns. The pattern period of the circular hole mask pattern layer is 1.4 microns.
[0042] Step 2, clean the gallium nitride single crystal substrate 101 prepared with a circular hole-shaped mask pattern layer and put it into an MOCVD reaction chamber for secondary growth. 2 Atmosphere and 950°C, the pressure of the MOCVD reaction chamber is 200 torr, the V / III molar ratio is 1000, and the three-dimensionally grown n-type GaN three-dimensional growth layer 102 with a thickness of 150 nanometers is adopted at a growth rate of 2 microns / hour, wherein the n-type GaN The Si doping concentration of the three-dimens...
Embodiment 3
[0051] Step 1. Deposit SiO with a thickness of 102nm on a gallium nitride single crystal substrate by chemical vapor deposition (PECVD) 2 Or SiN is used as the mask pattern layer, and the mask pattern layer is prepared as a circular hole-shaped mask pattern layer with a periodic structure, and the circular hole diameter of the circular hole-shaped mask pattern layer is 1.0 microns. The pattern period of the circular hole mask pattern layer is 1.6 microns.
[0052] Step 2, clean the gallium nitride single crystal substrate 101 prepared with a circular hole-shaped mask pattern layer and put it into an MOCVD reaction chamber for secondary growth. 2 Atmosphere and 1050°C, the pressure of the MOCVD reaction chamber is 300torr, the V / III molar ratio is 1300, and the growth rate of 3 microns / hour is used to three-dimensionally grow the n-type GaN three-dimensional growth layer 102 with a thickness of 200 nanometers, wherein the n-type GaN The Si doping concentration of the three-dim...
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