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Modified perlite-rigid polyurethane foamed plastic composite thermal-insulation material

A composite thermal insulation material and rigid polyurethane technology, applied in the field of material science, can solve the problems of fire hazard, poor fire safety, easy aging, etc., and achieve the effects of simple preparation process, good thermal insulation effect, and good flame retardant performance.

Inactive Publication Date: 2016-12-07
NANJING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The biggest advantage of this type of organic thermal insulation material is light weight, heat insulation, and heat preservation, but the biggest defect is that it is easy to burn, easy to age, and has poor fire safety. Without flame retardant treatment, there are serious fire hazards, leading to building fire accidents.
Polyurethane rigid foam is a flammable organic thermal insulation material, which releases a large amount of toxic gas and smoke when burned, which poses a serious threat to people's life and property safety. Therefore, if its flammable fire prevention cannot be effectively and effectively solved safety issues, then rigid polyurethane foams cannot be widely promoted and applied in my country's building energy conservation

Method used

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  • Modified perlite-rigid polyurethane foamed plastic composite thermal-insulation material
  • Modified perlite-rigid polyurethane foamed plastic composite thermal-insulation material
  • Modified perlite-rigid polyurethane foamed plastic composite thermal-insulation material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The preparation of modified perlite adopts the following methods:

[0027] (1) Dissolving excess decanediamine in hydrochloric acid with a prepared substance concentration of 0.010mol / L, after partial protonation, decanediamine is partially protonated into one end that still has an active -NH2 group ammonia salt;

[0028] (2) Add perlite to partially protonated decanediamine solution, place it in an oil bath at 55°C, and stir with an electric mixer for 3 hours at a speed of 2000r / min; The dosage ratio is 10g: 100ml;

[0029] (3) Suction filtration, the filter cake is washed with distilled water for 3 to 4 times, dried, ground and sieved to obtain the modified perlite.

Embodiment 2

[0031] The preparation of modified perlite adopts the following methods:

[0032] (1) Dissolving excess decanediamine in hydrochloric acid with a prepared substance concentration of 0.008mol / L, after partial protonation, decanediamine is partially protonated into one end that still has an active -NH2 group ammonia salt;

[0033] (2) Add perlite to partially protonated decanediamine solution, place it in an oil bath at 50°C, and stir with an electric mixer for 4 hours at a speed of 1500r / min; The dosage ratio is 10g: 100ml;

[0034] (3) Suction filtration, the filter cake is washed with distilled water for 3 to 4 times, dried, ground and sieved to obtain the modified perlite.

Embodiment 3

[0036] The preparation of modified perlite adopts the following methods:

[0037] (1) Dissolving excess decanediamine in hydrochloric acid with a prepared substance concentration of 0.012mol / L, after partial protonation, decanediamine is partially protonated into one end that still has an active -NH2 group ammonia salt;

[0038] (2) Add perlite to partially protonated decanediamine solution, place it in an oil bath at 60°C, and stir for 2 hours with an electric mixer at a speed of 2500r / min; The dosage ratio is 10g: 100ml;

[0039] (3) Suction filtration, the filter cake is washed with distilled water for 3 to 4 times, dried, ground and sieved to obtain the modified perlite.

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Abstract

The invention provides a modified perlite-rigid polyurethane foamed plastic composite thermal-insulation material which is prepared from the following components in parts by weight: modified perlite, triglycidyl isocyanurate, polyester polyol, polyether glycol, hydroxy low-molecular-weight compounds, modified nano aluminum hydroxide, a foaming agent, an organosilicon foam stabilizer, microcrystalline cellulose, a composite catalyst, a foaming agent, a flame retardant and water. The composite thermal-insulation material provided by the invention has the advantages of simple preparation technique, low cost, favorable flame retardancy and favorable thermal-insulation effect.

Description

technical field [0001] The invention relates to a modified perlite-rigid polyurethane foam composite thermal insulation material, which belongs to the field of material science. Background technique [0002] In recent years, the use of wall insulation to achieve building energy conservation has been paid more and more attention. The country has also begun to enforce building energy conservation measures. Now the insulation materials used on a large scale in the market mainly include EPS (polystyrene foam), PS (extruded Plastic polystyrene foam) and PU (polyurethane foam). The biggest advantage of this type of organic thermal insulation material is light weight, heat insulation, and heat preservation, but the biggest defect is that it is easy to burn, easy to age, and has poor fire safety. Without flame retardant treatment, there are serious fire hazards, leading to building fire accidents. . Polyurethane rigid foam is a flammable organic thermal insulation material, which ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/42C08G18/44C08G18/48C08G18/50C08G18/32C08K13/06C08K9/04C08K3/36C08K9/06C08K3/22C08K5/5377C08J9/04C08G101/00
CPCC08G18/3206C08G18/42C08G18/44C08G18/48C08G18/5021C08G18/6607C08J9/04C08J2375/08C08K3/22C08K3/36C08K5/5377C08K9/04C08K9/06C08K13/06C08K2003/2224C08K2003/2227C08K2201/011C08L2201/02C08G2110/0025C08G2110/005
Inventor 唐洪刚左晓宝蒋慷邱林峰汤玉娟殷光吉马强王佳林丁冬楠何绍丽江恺邹帅
Owner NANJING UNIV OF SCI & TECH