Modified perlite-rigid polyurethane foamed plastic composite thermal-insulation material
A composite thermal insulation material and rigid polyurethane technology, applied in the field of material science, can solve the problems of fire hazard, poor fire safety, easy aging, etc., and achieve the effects of simple preparation process, good thermal insulation effect, and good flame retardant performance.
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Embodiment 1
[0026] The preparation of modified perlite adopts the following methods:
[0027] (1) Dissolving excess decanediamine in hydrochloric acid with a prepared substance concentration of 0.010mol / L, after partial protonation, decanediamine is partially protonated into one end that still has an active -NH2 group ammonia salt;
[0028] (2) Add perlite to partially protonated decanediamine solution, place it in an oil bath at 55°C, and stir with an electric mixer for 3 hours at a speed of 2000r / min; The dosage ratio is 10g: 100ml;
[0029] (3) Suction filtration, the filter cake is washed with distilled water for 3 to 4 times, dried, ground and sieved to obtain the modified perlite.
Embodiment 2
[0031] The preparation of modified perlite adopts the following methods:
[0032] (1) Dissolving excess decanediamine in hydrochloric acid with a prepared substance concentration of 0.008mol / L, after partial protonation, decanediamine is partially protonated into one end that still has an active -NH2 group ammonia salt;
[0033] (2) Add perlite to partially protonated decanediamine solution, place it in an oil bath at 50°C, and stir with an electric mixer for 4 hours at a speed of 1500r / min; The dosage ratio is 10g: 100ml;
[0034] (3) Suction filtration, the filter cake is washed with distilled water for 3 to 4 times, dried, ground and sieved to obtain the modified perlite.
Embodiment 3
[0036] The preparation of modified perlite adopts the following methods:
[0037] (1) Dissolving excess decanediamine in hydrochloric acid with a prepared substance concentration of 0.012mol / L, after partial protonation, decanediamine is partially protonated into one end that still has an active -NH2 group ammonia salt;
[0038] (2) Add perlite to partially protonated decanediamine solution, place it in an oil bath at 60°C, and stir for 2 hours with an electric mixer at a speed of 2500r / min; The dosage ratio is 10g: 100ml;
[0039] (3) Suction filtration, the filter cake is washed with distilled water for 3 to 4 times, dried, ground and sieved to obtain the modified perlite.
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