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Coating rubber material for high-polymer printing rubber rollers and preparation method thereof

A technology of printing rubber rollers and polymers, which is applied in the field of printing rubber rollers, can solve problems such as uneven dispersion, easy agglomeration of graphene oxide, and restrictions on industrial applications, so as to improve stability, improve dispersion, and good mechanics performance effect

Inactive Publication Date: 2016-12-07
TONGLING HONGZHENG NETWORK SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it has been found that the main problem in the process of preparing graphene oxide / polymer composites is that graphene oxide is easy to agglomerate, and the dispersion in the polymer is not uniform, and the state of the interface between graphene oxide and polymer Poor, ultimately leading to low comprehensive performance of graphene oxide / polymer composites, which limits its further industrial application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0023] A kind of covering glue compound of polymer printing rubber roller, it is made up of the raw material of following weight part:

[0024] Polytetrahydrofuran ether glycol 2, antioxidant SP0.6, accelerator TTTE1, saturated octadecylamide 1, graphene oxide 10, N hydroxysuccinimide 6, 1 ethyl (3 dimethylaminopropyl) carbon Diimine hydrochloride 10, p-aminobenzenesulfonic acid 7, styrene 30, potassium persulfate 0.1, lanthanum chloride 0.3, ethylenediaminetetraacetic acid 2, carbon fiber 1.7, 20% ammonia water 50, natural rubber 100, N , N diethylaniline 0.3, calcium zeolite 10, polycarbodiimide 1, polyacrylamide 2, phthalate 2, sulfur 0.8.

[0025] A kind of preparation method of the covering rubber compound of described polymer printing rubber roller, comprises the following steps:

[0026] (1) Add the above graphene oxide to 50 times its weight of N, N dimethylformamide, sonicate for 20 minutes, add 1 ethyl (3 dimethylaminopropyl) carbodiimide hydrochloride , N-hydroxys...

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PUM

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Abstract

The invention discloses a coating rubber material for high-polymer printing rubber rollers. The coating rubber material is prepared from the following raw materials in parts by weight: 2-3 parts of polyoxytetramethylene glycol, 0.6-1 part of anti-aging agent SP, 1-2 parts of accelerator TTTE, 1-2 parts of saturated octadecacarbamide, 10-14 parts of graphene oxide, 6-7 parts of N-hydroxy succinimide, 10-12 parts of 1-ethyl-(3-dimethylaminopropyl)carbodiimide hydrochloride, 7-9 parts of sulfanilic acid, 30-40 parts of styrene, 0.1-0.2 part of potassium persulfate, 0.3-0.4 part of lanthanum chloride, 2-3 parts of ethylenediamine tetraacetic acid, 1.7-2 parts of carbon fiber, 50-67 parts of 20-25% ammonia water, 100-130 parts of natural rubber, 0.3-0.4 part of N,N-diethylaniline, 10-13 parts of scolecite, 1-2 parts of polycarbodiimide, 2-4 parts of polyacrylamide, 2-3 parts of phthalate and 0.8-1 part of sulfur. The polyoxytetramethylene glycol, polyacrylamide and other high-polymer raw materials are added to effectively enhance the dispersity of the raw materials in the rubber and enhance the stability of the finished product.

Description

technical field [0001] The invention relates to the technical field of printing rubber rollers, in particular to a coating rubber material for polymer printing rubber rollers and a preparation method thereof. Background technique [0002] Printing rubber roller is a composite of elastic rubber and metal roller core processed by a certain process. It is widely used in various printing industries. At present, there are many problems in the quality of printing rubber rollers, such as poor wear resistance. Abrasion and holes often appear, seriously affecting the printing quality, so how to improve the abrasion resistance and mechanical properties of printing rubber rollers is very necessary; [0003] The raw material of graphene oxide is easy to get and the price is low. It is an ideal filler for polymer nanocomposites. After the discovery of unsupported graphene oxide paper and graphene / polymer conductive nanocomposites, an upsurge in the application of graphene oxide has been...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L7/00C08L25/06C08L71/02C08L33/26C08K13/06C08K9/04C08K3/04C08K7/06
CPCC08K2201/011C08L7/00C08L2205/035C08L25/06C08L71/02C08L33/26C08K13/06C08K9/04C08K3/04C08K7/06
Inventor 周正红
Owner TONGLING HONGZHENG NETWORK SCI & TECH CO LTD
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