Water-based amino stoving varnish and preparation method thereof
An amino baking varnish, water-based technology, applied in the direction of polyurea/polyurethane coating, epoxy resin coating, polyester coating, etc., can solve the problems of organic solvent emission pollution, endangering the health of operators, and hidden dangers of environmental safety, etc., to solve the problem of easy hydrolysis , Construction is convenient and fast, and the effect of convenient construction
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Embodiment 1
[0033] A water-based amino baking varnish, the water-based amino baking varnish is made of the following raw material ratios, calculated by weight percentage: 25% water-based polyester resin, 5% water-based epoxy resin, 9% water-based amino resin, 35% Deionized water, 2% pH regulator, 0.3% wetting agent, 0.4% defoamer, 0.5% dispersant, 2% co-solvent, 17.1% pigment and filler, 2% nano-alumina , 0.5% lithium magnesium silicate, 0.4% thickener, 0.8% leveling agent.
[0034] The preparation method of the water-based polyester resin is: add the water-based branched-chain polyester resin with an acid value of 50 mgKOH / g, add glycidyl tertiary carbonic acid ester, carry out copolymerization modification at 120 ° C for 0.5 h, until the end point acid value is 40 mgKOH / g, and obtain Waterborne polyester resin. The mass ratio of water-based branched polyester resin to glycidyl tertiary carbonic acid ester is 8.5:1.
[0035] The preparation method of water-based epoxy resin is as follo...
Embodiment 2
[0043]A water-based amino baking varnish, the water-based amino baking varnish is made of the following raw material ratios, calculated as: 30% water-based polyester resin, 4% water-based epoxy resin, 7% water-based amino resin, 28.8% Deionized water, 1.5% pH adjuster, 0.4% wetting agent, 0.2% defoamer, 0.7% dispersant, 1% co-solvent, 20% pigment and filler, 5% nano-alumina , 0.4% lithium magnesium silicate, 0.3% thickener, 0.7% leveling agent.
[0044] The preparation method of the water-based polyester resin is: add the water-based branched-chain polyester resin with an acid value of 60mgKOH / g, add glycidyl tertiary carbonic acid ester, carry out copolymerization modification at 130°C for 0.5h, until the end point acid value is 50mgKOH / g, and obtain Waterborne polyester resin. The mass ratio of water-based branched polyester resin to glycidyl tertiary carbonic acid ester is 9:1.
[0045] The preparation method of water-based epoxy resin is as follows: low-iodine value fatt...
Embodiment 3
[0049] A water-based amino baking varnish, the water-based amino baking varnish is made of the following raw material ratios, calculated as: 35% water-based polyester resin, 4.5% water-based epoxy resin, 10% water-based amino resin, 26% Deionized water, 2.5% pH adjuster, 0.3% wetting agent, 0.5% defoamer, 0.8% dispersant, 5% co-solvent, 11% pigment and filler, 3% nano-alumina , 0.3% lithium magnesium silicate, 0.5% thickener, 0.6% leveling agent.
[0050] The preparation method of the water-based polyester resin is: add the water-based branched-chain polyester resin with an acid value of 55 mgKOH / g, add glycidyl tertiary carbonic acid ester, carry out copolymerization modification at 140 ° C for 0.5 h, until the end point acid value is 45 mgKOH / g, and obtain Waterborne polyester resin. The mass ratio of water-based branched polyester resin to glycidyl tertiary carbonic acid ester is 8.8:1.
[0051] The preparation method of the water-based epoxy resin is as follows: low-iodi...
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