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Method for preparing single-layer 2H-phase tungsten disulfide/graphene composite material

A tungsten disulfide and composite material technology, applied in chemical instruments and methods, tungsten compounds, inorganic chemistry, etc., can solve problems such as single-layer tungsten disulfide nanosheets, and achieve low price, simple process operation, and mild reaction conditions. Effect

Inactive Publication Date: 2016-12-14
HENAN NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are almost no reports on single-layer tungsten disulfide in the published literature, especially the preparation of single-layer tungsten disulfide nanosheets with a single specified phase state.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Weigh 0.004mol of lithium hydroxide and 0.002mol of ammonium thiotungstate respectively, mix and grind them in an agate mortar for 1 hour, put the ground mixture in a corundum crucible, place it in a tube furnace, and protect it with argon. , the temperature was raised to 600 ° C by program, and kept for 1 h, and then continued to pass argon gas to cool down to room temperature naturally to obtain lithium-intercalated 2H phase tungsten sulfide (Li 2 WS 4 ) block; place the lithium-inserted tungsten sulfide block in a container filled with 50mL of deionized water, and disperse it ultrasonically for 10 minutes. Add graphene oxide with a mass ratio of 1:0.005 to the tungsten disulfide content in the suspension, ultrasonically disperse for 10 minutes, add 0.25 mL of hydrazine hydrate with a mass fraction of 80%, and continue ultrasonicating for 0.5 h to obtain a single layer of 2H phase WS 2 / graphene suspension; the resulting monolayer 2H phase WS 2 The / graphene suspen...

Embodiment 2

[0022] Weigh 0.004 mol of lithium acetate and 0.002 mol of ammonium thiotungstate respectively, mix and grind them in an agate mortar for 1 hour, place the ground mixture in a corundum crucible, place it in a tube furnace, and protect it with argon. The temperature was raised to 200°C by program, kept for 10 hours, and then continued to cool down to room temperature naturally with argon gas to obtain lithium-intercalated 2H phase tungsten sulfide (Li 2 WS 4 ) block; place the lithium-inserted tungsten sulfide block in a container filled with 50mL of deionized water, and disperse it ultrasonically for 10 minutes. Add graphene oxide with a mass ratio of 1:0.01 to the content of tungsten disulfide in the suspension, ultrasonically disperse for 10 minutes, add 0.5 mL of hydrazine hydrate with a mass fraction of 80%, and continue ultrasonicating for 0.5 h to obtain a single layer of 2H phase WS 2 / graphene suspension; the resulting monolayer 2H phase WS 2 / Graphene suspension wa...

Embodiment 3

[0024] Weigh 0.004 mol of lithium nitrate and 0.002 mol of ammonium thiotungstate respectively, mix and grind them in an agate mortar for 1 hour, place the ground mixture in a corundum crucible, place it in a tube furnace, and protect it with argon gas. The temperature was raised to 300°C by program, kept for 5 hours, and then continued to flow argon to cool down to room temperature naturally to obtain lithium-intercalated 2H phase tungsten sulfide (Li 2 WS 4 ) block; place the lithium-inserted tungsten sulfide block in a container filled with 50mL of deionized water, and disperse it ultrasonically for 5 minutes. The content of tungsten disulfide in the suspension was added with graphene oxide at a mass ratio of 1:0.10, ultrasonically dispersed for 10 minutes, and then 2.5 mL of hydrazine hydrate with a mass fraction of 80% was added, and ultrasonication was continued for 1 hour to obtain a single layer of 2H phase WS. 2 / graphene suspension; the resulting monolayer 2H phase...

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Abstract

The invention discloses a method for preparing a single-layer 2H-phase tungsten disulfide / graphene composite material. The specific process of the method is as follows: ammonium thiotungstate and a lithium salt compound are taken as raw materials, the ammonium thiotungstate and the lithium salt compound can be synthesized into a lithium-intercalated 2H-phase tungsten sulfide block through simple temperature control, the lithium-intercalated 2H-phase tungsten sulfide block can be automatically peeled into 2H-phase single-layer WS2 nanosheets in water, and then the 2H-phase single-layer WS2 nanosheets are self-assembled with oxidized graphene to form the single-layer 2H-phase tungsten disulfide / graphene composite material. The method is simple in technological operation and mild in reaction conditions, and used reagents are low in cost, green and environmentally-friendly.

Description

technical field [0001] The invention belongs to the technical field of synthesis of tungsten disulfide / graphene composite materials, and in particular relates to a method for preparing single-layer 2H phase tungsten disulfide / graphene composite materials. Background technique [0002] Tungsten disulfide has the same structure as molybdenum disulfide, which is a typical sandwich layered structure. Due to the relatively weak van der Waals force between the layers, it can also be peeled off into single-layer or few-layer nanosheets, which is considered to be another equivalent. Important two-dimensional nanosheet materials with unique physical, chemical and electrical properties. Tungsten disulfide is the same as molybdenum disulfide, and there are three phases, namely 1T, 2H and 3R phases. Among them, the 1T phase is WS 2 One S-W-S monolayer is stacked as the minimum repeating unit, while the 2H and 3R phases are stacked with two and three S-W-S monolayers as the minimum repe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/583H01M4/58H01M4/1393H01M4/1397C01G41/00C01B31/04
CPCC01G41/00H01M4/1393H01M4/1397H01M4/362H01M4/5815H01M4/583Y02E60/10
Inventor 常焜李苞汤宏伟上官恩波李熠辉常照荣
Owner HENAN NORMAL UNIV