A kind of modified pitch for producing anode carbon block and preparation method of modified pitch

A technology for modifying asphalt and anode carbon blocks, which is applied in the chemical field, can solve the problems of increased anode replacement frequency, increased labor intensity of workers, reduced electrolytic cell efficiency, etc., and achieves a simple and easy-to-understand preparation method, improved coking properties, and reduced viscosity. Effect

Active Publication Date: 2019-06-07
GUANGXI QIANGQIANG CARBON CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Moreover, the excessive consumption of the anode will lead to an increase in the frequency of anode replacement, which will not only increase the labor intensity of the workers, but also make it difficult to implement the modern high-efficiency energy-saving process technology characterized by low anode effect, and reduce the efficiency of the electrolytic cell.

Method used

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  • A kind of modified pitch for producing anode carbon block and preparation method of modified pitch

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] 1. Raw material preparation:

[0026] A modified asphalt for the production of anode carbon blocks, comprising 50 parts by weight of asphalt, 5 parts of asphalt modifier A, and 3 parts of asphalt modifier B;

[0027] Among them, the asphalt modifier A includes 1 part of modified diatomite and 2 parts of modified bentonite in parts by weight;

[0028] Among them, the modified diatomaceous earth is calcined at 500° C. for 10 min, and then pulverized with ultrasonic waves to a particle size of 100 mesh after cooling.

[0029] Among them, the modified bentonite is mechanically pulverized to 50 meshes and then thermally cracked in a steam thermal cracking device for 2 seconds; the temperature of the steam thermal cracking device is 350°C, and the steam thermal cracking device is added after being vacuumed Argon.

[0030] Among them, the asphalt modifier B includes 0.5 part of n-decyl stearate, 0.1 part of dibutyl phthalate, 0.1 part of ultrafine graphite powder and 0.5 part of fluori...

Embodiment 2

[0039] 1. Raw material preparation:

[0040] A modified asphalt for the production of anode carbon blocks, comprising 85 parts by weight of asphalt, 15 parts of asphalt modifier A, and 8 parts of asphalt modifier B;

[0041] Among them, the asphalt modifier A includes 5 parts of modified diatomite and 8 parts of modified bentonite in parts by weight;

[0042] Among them, the modified diatomaceous earth is calcined at 600° C. for 30 min, and then pulverized by ultrasonic waves to a particle size of 150 mesh after cooling.

[0043] Among them, the modified bentonite is mechanically pulverized to 100 meshes and then thermally cracked in a steam thermal cracking device for 5 seconds; the temperature of the steam thermal cracking device is 450°C, and the steam thermal cracking device is added after being vacuumed Argon.

[0044] Among them, the asphalt modifier B includes 1.5 parts of n-decyl stearate, 0.8 parts of dibutyl phthalate, 3 parts of ultrafine graphite powder and 2 parts of fluor...

Embodiment 3

[0053] 1. Raw material preparation:

[0054] A modified asphalt for the production of anode carbon blocks, comprising 64 parts by weight of asphalt, 8 parts of asphalt modifier A, and 5 parts of asphalt modifier B;

[0055] Wherein, the asphalt modifier A includes 3 parts of modified diatomite and 4 parts of modified bentonite in parts by weight;

[0056] Among them, the modified diatomaceous earth is calcined at 550° C. for 18 min, and then pulverized with ultrasonic waves to a particle size of 120 mesh after cooling.

[0057] Among them, the modified bentonite is mechanically pulverized to 60 meshes and then thermally cracked in a steam thermal cracking device for 3 seconds; the temperature of the steam thermal cracking device is 380°C, and the steam thermal cracking device is added after vacuuming Argon.

[0058] Among them, the asphalt modifier B includes 0.8 parts of n-decyl stearate, 0.4 parts of dibutyl phthalate, 1.5 parts of ultrafine graphite powder and 1.0 part of fluoride i...

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Abstract

The present invention belongs to the chemical field, and more particularly relates to a modified asphalt for producing an anode carbon block, and a preparation method thereof, wherein the modified asphalt comprises, by mass, 50-85 parts of asphalt, 5-15 parts of an asphalt modifier A, and 3-8 parts of an asphalt modifier B. The preparation method comprises: preparing raw materials, carrying out heating cross-linking fusing modification with the asphalt modifier A, and carrying out cooling modification with the asphalt modifier B so as to obtain the modified asphalt. According to the present invention, the asphalt is adopted as the raw material and the performances of the asphalt are improved, such that the coking property of the asphalt can be improved by adjusting the Coal tar Pitch softening point, the toluene insoluble content and the beta resin content during the application of the modified asphalt to produce the anode carbon block, and the oxidation resistance of the pitch coke can be improved; and the preparation method is simple, and has the generalization.

Description

【Technical Field】 [0001] The invention belongs to the field of chemistry, and particularly relates to a modified pitch used for producing anode carbon blocks and a preparation method of the modified pitch. 【Background technique】 [0002] At present, the production of pure aluminum mainly uses Hall-Heroult's cryolite-alumina molten salt electrolysis method. The anode material is a consumable carbon product, which is the "heart" of electrolytic aluminum. Carbon anode consumption is one of the main costs of electrolytic aluminum production, accounting for about 15% of the total cost. In the process of electrolytic aluminum production, carbon anode consumption includes electrochemical consumption, chemical consumption and mechanical consumption. Among them, carbon anode and CO 2 The chemical consumption caused by the oxidation reaction with air at high temperature is the main reason for the excessive consumption of the anode, accounting for about 7%-20% of the entire carbon consumpt...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L95/00C08K13/06C08K9/00C08K3/34C08K5/101C08K5/12C08K3/04C08K3/16C25C3/12
CPCC08K3/04C08K3/16C08K3/34C08K3/346C08K5/101C08K5/12C08K9/00C08K13/06C08K2003/162C08K2003/166C08L2201/08C08L2312/00C25C3/125C08L95/00
Inventor 赵唯皓杨云坤罗高强黄海燕李永锋周勇农增宏
Owner GUANGXI QIANGQIANG CARBON CO LTD
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