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Surface treatment method of middle-high-strength carbon fibers

A high-strength carbon fiber, surface treatment technology, applied in fiber treatment, carbon fiber, physical treatment and other directions to avoid damage

Inactive Publication Date: 2017-01-11
郑州峰泰纳米材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, there are very few studies aimed at improving the surface structure of carbon fibers and increasing the tensile strength, and there are few reports on the simultaneous improvement of the intrinsic tensile strength of carbon fibers and the interlaminar shear strength of composite materials by electrochemical oxidation.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Soak medium and high-strength carbon fibers with a carbon mass ratio higher than 90% in acrylic acid for 30 seconds, and then rinse them with deionized water; introduce the rinsed medium and high-strength carbon fibers into continuous electrochemical treatment equipment, and use graphite plates as cathodes , using a weak alkaline electrolyte for electrochemical oxidation treatment, the treatment temperature is 25°C, and the applied current density is controlled to be 0.4mA / cm 2 , processed for 30s, followed by washing, drying, sizing and winding. Wherein, the formula of weak alkaline electrolyte is: 0.2mol / L ammonium oxalate, 0.06mol / L citric acid and 0.12mol / L sodium citrate, and the solvent is water.

Embodiment 2

[0024] Soak medium-high-strength carbon fibers with a carbon content higher than 90% in acrylic acid for 60 seconds, and then rinse them with deionized water; introduce the rinsed medium-high-strength carbon fibers into continuous electrochemical treatment equipment, and use nickel plates as cathodes , using a weak alkaline electrolyte for electrochemical oxidation treatment, the treatment temperature is 35°C, and the applied current density is controlled to 1.6mA / cm 2 , processed for 80s, followed by washing, drying, sizing and winding. Wherein, the formula of the weak alkaline electrolyte is: 0.4mol / L ammonium oxalate, 0.2mol / L citric acid and 0.4mol / L sodium citrate, and the solvent is water.

Embodiment 3

[0026] Soak medium and high-strength carbon fibers with a carbon mass ratio higher than 90% in acrylic acid for 90s, and then rinse them with deionized water; introduce the rinsed medium and high-strength carbon fibers into continuous electrochemical treatment equipment, and use nickel plates as cathodes , using a weak alkaline electrolyte for electrochemical oxidation treatment, the treatment temperature is 50°C, and the applied current density is controlled to 6mA / cm 2 , processed for 100s, followed by washing, drying, sizing and winding. Wherein, the formula of the weak alkaline electrolyte is: 0.8 mol / L ammonium oxalate, 0.3 mol / L citric acid and 0.6 mol / L sodium citrate, and the solvent is water.

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Abstract

The invention provides a surface treatment method of middle-high-strength carbon fibers. The surface treatment method of the middle-high-strength carbon fibers comprises the following steps: (1) soaking the middle-high-strength carbon fibers of which carbonic mass ratio is higher than 90% with acrylic acid, and then washing cleanly with deionized water; (2) introducing the cleanly washed middle-high-strength carbon fibers in the step (1) into continuous electrochemical treatment equipment, taking a graphite plate, a stainless steel plate, a copper plate or a nickel plate as a cathode, carrying out electrochemical oxidation treatment with alkalescent electrolyte at the temperature of 20-60 DEG C, controlling applied current density to be 0.1-10 mA / cm(2), treating for 20-240 s, then washing, drying, sizing and rolling to obtain the middle-high-strength carbon fibers. By the treatment method, drawing strength and shear strength of the carbon fibers can be improved, and further, the tensile strength of carbon fiber bodies cannot be damaged.

Description

technical field [0001] The invention belongs to the technical field of carbon fiber treatment, and in particular relates to a surface treatment method for medium and high-strength carbon fibers. Background technique [0002] Carbon fiber is a fibrous carbon material with a carbon content greater than 90%. It has excellent properties such as high tensile strength, high tensile modulus, low density, high temperature resistance, ablation resistance, corrosion resistance, high electrical and thermal conductivity, low thermal expansion, self-lubrication and good biocompatibility. Ablation, structural and functional composite components. At present, carbon fiber and its composite materials are mainly used in cutting-edge technology industries such as aerospace, aviation, and atomic energy, as well as in the manufacture of sports equipment. As a reinforcement of composite materials, the strength of the carbon fiber body and the interface between it and the matrix material are the...

Claims

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Application Information

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IPC IPC(8): D06M10/08D06M101/40
CPCD06M10/08D06M2101/40
Inventor 李洋洋
Owner 郑州峰泰纳米材料有限公司
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