Surface treatment method of middle-high-strength carbon fibers
A high-strength carbon fiber, surface treatment technology, applied in fiber treatment, carbon fiber, physical treatment and other directions to avoid damage
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Embodiment 1
[0022] Soak medium and high-strength carbon fibers with a carbon mass ratio higher than 90% in acrylic acid for 30 seconds, and then rinse them with deionized water; introduce the rinsed medium and high-strength carbon fibers into continuous electrochemical treatment equipment, and use graphite plates as cathodes , using a weak alkaline electrolyte for electrochemical oxidation treatment, the treatment temperature is 25°C, and the applied current density is controlled to be 0.4mA / cm 2 , processed for 30s, followed by washing, drying, sizing and winding. Wherein, the formula of weak alkaline electrolyte is: 0.2mol / L ammonium oxalate, 0.06mol / L citric acid and 0.12mol / L sodium citrate, and the solvent is water.
Embodiment 2
[0024] Soak medium-high-strength carbon fibers with a carbon content higher than 90% in acrylic acid for 60 seconds, and then rinse them with deionized water; introduce the rinsed medium-high-strength carbon fibers into continuous electrochemical treatment equipment, and use nickel plates as cathodes , using a weak alkaline electrolyte for electrochemical oxidation treatment, the treatment temperature is 35°C, and the applied current density is controlled to 1.6mA / cm 2 , processed for 80s, followed by washing, drying, sizing and winding. Wherein, the formula of the weak alkaline electrolyte is: 0.4mol / L ammonium oxalate, 0.2mol / L citric acid and 0.4mol / L sodium citrate, and the solvent is water.
Embodiment 3
[0026] Soak medium and high-strength carbon fibers with a carbon mass ratio higher than 90% in acrylic acid for 90s, and then rinse them with deionized water; introduce the rinsed medium and high-strength carbon fibers into continuous electrochemical treatment equipment, and use nickel plates as cathodes , using a weak alkaline electrolyte for electrochemical oxidation treatment, the treatment temperature is 50°C, and the applied current density is controlled to 6mA / cm 2 , processed for 100s, followed by washing, drying, sizing and winding. Wherein, the formula of the weak alkaline electrolyte is: 0.8 mol / L ammonium oxalate, 0.3 mol / L citric acid and 0.6 mol / L sodium citrate, and the solvent is water.
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Abstract
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