A kind of heterojunction solar cell with core-shell structure based on chalcogenide cuprous compound and its preparation method

A technology of solar cells and chalcogenides, applied in circuits, electrical components, photovoltaic power generation, etc., can solve the problems of increasing the preparation cost and process complexity of nanowire solar cells, hindering promotion, etc., and achieves remarkable universality and simple preparation. , good compatibility

Inactive Publication Date: 2017-12-01
HEFEI UNIV OF TECH
View PDF2 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In the preparation process of the above nanowire solar cells, the use of high operating costs and complex processes of high-vacuum evaporation equipment such as atomic layer deposition and pulsed laser deposition has increased the preparation cost and process complexity of nanowire solar cells and hindered their development. further promotion

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of heterojunction solar cell with core-shell structure based on chalcogenide cuprous compound and its preparation method
  • A kind of heterojunction solar cell with core-shell structure based on chalcogenide cuprous compound and its preparation method
  • A kind of heterojunction solar cell with core-shell structure based on chalcogenide cuprous compound and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] The heterojunction solar cell of this embodiment is based on a silicon-based substrate 1 covered with an insulating layer 2 on the surface, and a chalcogenide cuprous compound quasi-one-dimensional nanostructure 3 is dispersed on the insulating layer 2. The first metal thin film electrode 4 is deposited on one end of the quasi-one-dimensional nanostructure 3 to form an ohmic contact; a photoresist barrier layer 5 is covered on the first metal thin film electrode 4 through ultraviolet exposure technology; The surface of the quasi-one-dimensional nanostructure of the chalcogenide compound that is not covered by the photoresist barrier layer is replaced with the chalcogenide compound of indium 6, forming a core-shell with the chalcogenide compound as the core and the chalcogenide compound of indium as the shell Structural heterojunction; the photoresist barrier layer 5 is removed, and the second metal film electrode 7 is deposited on the chalcogenide compound of indium by ul...

Embodiment 2

[0051] The preparation method of the core-shell structure heterojunction solar cell of this embodiment is the same as that of embodiment 1, except that the chalcogenide cuprous compound used in this embodiment is Cu 2 S nanowires, through the liquid phase cation replacement method, constructed Cu 2 S-In 2 S 3 Core-shell structure heterojunction solar cell.

[0052] The core-shell structure heterojunction solar cell prepared in this example has a light intensity of 30 mW cm -2 , Under the irradiation of monochromatic light with a wavelength of 532nm, it exhibits significant photovoltaic characteristics, such as Figure 5 As shown, the open circuit voltage is 0.12V, the short-circuit current is 1.29nA, the fill factor is 28.9%, and the conversion efficiency is about 2.0%.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
lengthaaaaaaaaaa
lengthaaaaaaaaaa
electrical resistivityaaaaaaaaaa
Login to view more

Abstract

The invention discloses a heterojunction solar cell with a core-shell structure based on a chalcogen cuprous compound and a preparing method thereof, characterizedin that silicon substrate on the upper surface is covered with an insulation layer is taken as the substrate, the quasi-one-dimensional nano-structure of the chalcogencuprous compound is dispersed on the insulation layer, a first metal membrane electrode is deposited at one end of the nano-structure to form ohmic contact, a layer of photoresist barrier layer is covered on the first metal membrane electrode, the surface of the quasi-one-dimensional nano-structure not covered by the photoresist barrier layer is replaced to indium chalcogenide by liquid-phase cation replacement, the heterojunction with core-cell structure is formed, and the photoresist is removed. A second metal membrane electrode is deposited above the indium chalcogenide to form the ohmic contact, namely, forming solar cell. The formation of heterojunction with core-cell structure can be realized by liquid-phase cation replacement in this invention, the formation process of heterojunctionis combined with the preparing process of the solar cell, the process has excellent compatibility and the process is simple and easy.

Description

Technical field [0001] The invention relates to a radial heterojunction solar cell and a preparation method thereof, in particular to a core-shell structure heterojunction solar cell based on a chalcogenide cuprous compound and a preparation method thereof. Background technique [0002] With the development of miniaturization and miniaturization of integrated circuits, the preparation of high-performance, low-power micro-nano devices has become a research focus. The well-crystallized quasi-one-dimensional nanostructures have received great attention in the field of new micro-nano devices due to their significantly lower production cost than bulk materials and better electrical transport characteristics than thin-film materials. Taking nanowire solar cells as an example, compared with bulk solar cells and thin-film solar cells, nanowire solar cells are expected to reduce the device size while significantly reducing material costs and manufacturing costs, and obtain comparable devi...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): H01L31/072H01L31/032H01L31/18
CPCH01L31/032H01L31/072H01L31/18Y02E10/50Y02P70/50
Inventor 吴春艳王友义彭伟叶斌罗林保
Owner HEFEI UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products