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Polypropylene composition for spray-free bumpers and preparation method thereof

A technology of polypropylene composition and bumper, which is applied in the field of material chemistry, can solve the problems of bumper mechanical performance degradation, difficulty in meeting assembly requirements, and poor antistatic durability, so as to achieve dust absorption, low environmental dependence, and excellent performance. The effect of anti-aging properties

Inactive Publication Date: 2017-02-08
ZHUZHOU TIMES NEW MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] (1) Since the spray-free bumper has no paint film protection, in addition to directly facing the hazards of external acid rain, ultraviolet rays, and oxides, there are also the hazards of metal impurities in the internal metal toner that have a catalytic aging effect, and the bumper is prone to mechanical damage. Serious performance degradation, short service life and other issues
[0006] (2) Since polypropylene is a non-polar material with strong insulation, the surface is easy to accumulate charges, which makes the surface of the bumper body easy to absorb dust; at the same time, excessive static electricity accumulation will also cause some dangerous accidents. Use environment and service life, the low-molecular antistatic agent used in the prior art has poor washing resistance, and the antistatic effect can be greatly reduced by car washing and raining, resulting in poor antistatic durability. The mechanism of action is to absorb air moisture to form a conductive water film, and its antistatic performance is also highly dependent on the ambient humidity
[0007] (3) Since the existing production line of the main engine factory is still mainly assembled after spraying, the bumper in this process has two shrinkages, namely, the cooling shrinkage after injection molding of the material and the shrinkage during the baking and painting process. The latter shrinkage is more difficult to control and fluctuates more Large, while the spray-free bumper only undergoes cooling shrinkage after injection molding, it is difficult to meet the assembly requirements under the same conditions, so the shrinkage rate of the material needs to be controlled

Method used

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  • Polypropylene composition for spray-free bumpers and preparation method thereof
  • Polypropylene composition for spray-free bumpers and preparation method thereof

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Effect test

Embodiment 1

[0037] An embodiment of the polypropylene composition for spray-free bumper of the present invention and its preparation method, the polypropylene composition comprises the following components by weight percentage: 33.3% of copolymerized polypropylene, 32.5% of homopolypropylene, Toughening agent 13%, anti-aging system additive 1.2%, scratch resistance agent 2%, nucleating agent 0.2%, lubricant 0.5%, coupling agent 0.3%, polymer antistatic agent 5%, masterbatch 2 %, mineral filler 10%.

[0038] The preparation method of above-mentioned polypropylene composition, comprises the following steps:

[0039] (1) Weigh the following raw materials: melt index 20-40g / 10min, notched impact strength greater than 10KJ / m 2 33.3kg of copolymerized polypropylene resin, 32.5kg of homopolypropylene resin with a melt index greater than 10g / 10min, 10kg of ethylene-octene copolymer, 3kg of linear low-density polyethylene, 0.4kg of hindered amine light stabilizers, hindered phenols Heat stabiliz...

Embodiment 2

[0045] An embodiment of the polypropylene composition for spray-free bumper of the present invention and its preparation method, the raw materials of the polypropylene composition are calculated by weight percentage, including the following components: 28.3% of copolymerized polypropylene resin, 28.3% of homopolymerized polypropylene resin, Acrylic resin 22.5%, toughening agent 18%, anti-aging system additive 1.2%, scratch resistance agent 2%, nucleating agent 0.2%, lubricant 0.5%, coupling agent 0.3%, polymer antistatic agent 5 %, masterbatch 2%, mineral filler 20%.

[0046] The preparation method of above-mentioned polypropylene composition, comprises the following steps:

[0047] (1) Weigh the following raw materials: melt index 70-120g / 10min, notched impact strength greater than 5KJ / m 2 28.3kg of copolymerized polypropylene resin, 22.5kg of high crystalline homopolypropylene resin, 15kg of ethylene-butylene copolymer, 3kg of low-density polyethylene, 0.4kg of phenylacryli...

Embodiment 3

[0053] An embodiment of the polypropylene composition for spray-free bumpers of the present invention and its preparation method, the raw materials of the polypropylene composition are calculated by weight percentage, including the following components: 23.3% of copolymerized polypropylene resin, 23.3% of homopolymerized polypropylene resin, Acrylic resin 15.5%, toughening agent 20%, anti-aging system additive 1.2%, scratch resistance agent 2%, nucleating agent 0.2%, lubricant 0.5%, coupling agent 0.3%, polymer antistatic agent 5 %, masterbatch 2%, mineral filler 30%.

[0054] The preparation method of above-mentioned polypropylene composition, comprises the following steps:

[0055] (1) Weigh the following raw materials: melt index 20-40g / 10min, notched impact strength greater than 10KJ / m 2 Copolymerized polypropylene resin 3.3kg, melt index 70-120g / 10min, notched impact strength greater than 5KJ / m 2 20kg of copolymerized polypropylene resin, 5.5kg of homopolypropylene resi...

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Abstract

The invention discloses a polypropylene composition for spray-free bumpers and a preparation method thereof. The polypropylene composition comprises the following components in percentage by weight: 20-60% of copolymer polypropylene resin, 10-40% of homopolymer polypropylene resin, 10-20% of toughener, 1-4% of antiaging system aid, 1-5% of scratch-resistant agent, 0.1-0.5% of nucleator, 0.5-3% of lubricant, 0.2-0.5% of coupling agent, 1-15% of high-polymer antistatic agent and 1-3% of master batch. The spray-free bumper prepared from the composition has the advantages of favorable washability, favorable permanent antistatic property, favorable long-term aging resistance and low dependence on the environment. The preparation method comprises the following steps: (1) weighing the materials in percentage by weight; (2) stirring and mixing the raw materials to obtain a premix; and (3) carrying out extrusion granulation on the premix to obtain the polypropylene composition. The method has the advantages of simple production technique and low cost.

Description

technical field [0001] The invention relates to the technical field of material chemistry, in particular to a polypropylene composition for a spray-free bumper and a preparation method thereof. Background technique [0002] With the continuous development of automobile lightweight requirements, polypropylene composite materials with many advantages such as low cost, good comprehensive mechanical properties, non-toxic, light weight, corrosion resistance, good electrical properties, easy processing, and easy recycling are widely used in Production of auto parts, among which auto bumpers are the most representative parts. Nowadays, the development trend of bumper requires not only protective function, but also decorative function, which should be harmonious and unified with the shape of the car body. The spraying of automobile bumpers can meet the increasingly colorful decorative needs of the automobile industry for bumpers. At the same time, the paint can protect the bumper b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/14C08L23/12C08L101/00C08L23/08C08L23/06C08K13/02C08K5/098C08K5/20C08K3/34
CPCC08L23/14C08K2201/003C08L2201/04C08L2205/025C08L2205/035C08L2205/24C08L2207/062C08L2207/066C08L2310/00C08L23/12C08L101/00C08L23/0815C08K13/02C08K5/098C08K5/20C08K3/34C08L23/06
Inventor 孟凡地王雄刚韩领吴承然黎敏宋克东黄安民
Owner ZHUZHOU TIMES NEW MATERIALS TECH
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