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A preparation method of flexible n-type silver telluride nanowire thermoelectric film

A thermoelectric thin film, silver telluride technology, which is applied in the direction of thermoelectric device junction lead wire materials, etc., can solve the problems of complex preparation process, high cost, poor flexibility, etc., and achieves excellent thermoelectric performance, good flexibility, and simple and controllable process. Effect

Active Publication Date: 2018-11-23
GUILIN UNIV OF ELECTRONIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But so far, flexible thermoelectric materials based on silver telluride are prepared from composite materials containing silver telluride nanoparticles, the preparation process is complicated, the cost is high, and the flexibility is poor.

Method used

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  • A preparation method of flexible n-type silver telluride nanowire thermoelectric film
  • A preparation method of flexible n-type silver telluride nanowire thermoelectric film
  • A preparation method of flexible n-type silver telluride nanowire thermoelectric film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] (1) ultrasonically disperse 30 mg of silver telluride nanowires and 1.5 mg of polyvinylpyrrolidone in 5 mL of ethylene glycol to obtain a silver telluride nanowire dispersion;

[0029] (2) With the assistance of vacuum filtration, evenly drop-coat 0.75mL of silver telluride nanowire dispersion on a 2.5cm×0.5cm glass fiber filter membrane, and drain the liquid; The glass fiber filter membrane was vacuum-dried at 75°C to obtain a silver telluride nanowire film adhered to the glass fiber filter membrane. The scanning electron microscope photos are as follows: figure 1 shown;

[0030] (3) the silver telluride nanowire thin film adhered on the glass fiber filter membrane that step (2) obtains is clamped between two copy papers, transfers in the tablet press, under 30MPa pressure extrusion molding, makes The silver telluride nanowire film is transferred to a piece of copy paper, and then the glass fiber filter fragments on the back of the silver telluride nanowire film are s...

Embodiment 2

[0038] (1) ultrasonically disperse 35 mg of silver telluride nanowires and 3.5 mg of polyvinylpyrrolidone in 7 mL of ethylene glycol to obtain a silver telluride nanowire dispersion;

[0039] (2) With the assistance of vacuum filtration, evenly drop-coat 1.0mL of silver telluride nanowire dispersion on a 2.5cm×0.5cm glass fiber filter membrane, and drain the liquid; The glass fiber filter membrane was vacuum-dried at 75° C. to obtain a silver telluride nanowire film adhered to the glass fiber filter membrane;

[0040] (3) the silver telluride nanowire thin film adhered on the glass fiber filter membrane that step (2) obtains is sandwiched between two copy papers, transferred in the tablet press, extruded under 10MPa pressure, then Use a brush to sweep away the glass fiber filter fragments on the back of the silver telluride nanowire film to obtain paper with the silver telluride nanowire film;

[0041] (4) Finally, place the paper with the silver telluride nanowire thin film ...

Embodiment 3

[0043] (1) ultrasonically disperse 40 mg of silver telluride nanowires and 10 mg of polyvinylpyrrolidone in 10 mL of ethylene glycol to obtain a silver telluride nanowire dispersion;

[0044] (2) With the assistance of vacuum filtration, evenly drop-coat 0.90mL of silver telluride nanowire dispersion on a 2.5cm×0.5cm glass fiber filter membrane, and drain the liquid; The glass fiber filter membrane was vacuum-dried at 75° C. to obtain a silver telluride nanowire film adhered to the glass fiber filter membrane;

[0045](3) the silver telluride nanowire film adhered on the glass fiber filter membrane that step (2) obtains is sandwiched between two copy papers, transferred in the tablet press, extruded under 5MPa pressure, then Use a brush to sweep away the glass fiber filter fragments on the back of the silver telluride nanowire film to obtain paper with the silver telluride nanowire film;

[0046] (4) Finally, place the paper with the silver telluride nanowire film obtained in...

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Abstract

The invention discloses a method for preparing a flexible N-type silver telluride nanowire thermoelectric film. The method comprises the following steps: mixing the silver telluride nanowire with polyvinylpyrrolidone, and ultrasonically dispersing in a solvent to obtain the dispersion of the silver telluride nanowire liquid; under the condition of vacuum filtration, evenly drop-coat the silver telluride nanowire dispersion on the glass fiber filter membrane, and dry it in vacuum at 75°C to obtain the silver telluride nanowire thin film adhered to the glass fiber filter membrane sandwich it between two pieces of copy paper, place it in a tablet press, and then use a brush to remove the glass fiber filter membrane fragments on the back of the silver telluride nanowire film, and place it in a vacuum oven for annealing to obtain the target product. The invention is simple and controllable, has short preparation cycle, safety and pollution-free, low energy consumption, and the obtained thin film has excellent thermoelectric performance and good flexibility, and flexible thermoelectric thin films of different sizes and shapes can be flexibly prepared according to the size and shape of the glass fiber membrane. have a broad vision of application.

Description

Technical field: [0001] The invention relates to the technical field of new energy materials, in particular to a method for preparing a flexible N-type silver telluride nanowire thermoelectric film. Background technique: [0002] Thermoelectric materials can directly convert electric energy and heat energy. Thermoelectric power generation devices and refrigeration devices made of thermoelectric materials have the characteristics of compact structure, no noise, no pollution during operation, and waste energy can be recycled. They are used in military, medical, aerospace , microelectronics and even household appliances and other fields have broad application prospects. Compared with commercial bulk thermoelectric materials, flexible thermoelectric materials have unique advantages such as bendability, small weight, simple process, and wide application range. In recent years, they have attracted more and more attention from the scientific research community and the business comm...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L35/16H10N10/852
CPCH10N10/852
Inventor 苗蕾高杰刘呈燕王潇漾彭英
Owner GUILIN UNIV OF ELECTRONIC TECH
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